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eT Pe ee 


The Automobile 


Storage Battery. 


Its Care and Repair 


Cee ee 98 eee 8h © 1 = Boe 


American Bureau of Engineering, Inc. 
1018-1024 So. Wabash Avenue, Chicago, Iil., U. S. A. 


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Copyright, 1918, by the 


American Bureau of Engineering, Ine. 


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PREFIX. 


Many books have been written on Storage Batteries used in 
stationary work, as in electric power stations. These books 
cover the subject thoroughly. The storage battery, as used on the 
modern gasoline car, however, is subjected to service which is 
radically different from that of the battery in stationary work. 
It is true that the chemical actions are the same in all lead-acid 
storage batteries, but the design, construction, and operation of 
the starting and lighting battery aré unique, and require a special 
description. 

This book therefore refers only to the lead-acid type of starting 
and lighting battery used on the modern gasoline automobile. It 
is divided into two sections. The first section covers the, théory, 
design, operating conditions, and care of the battery. The Wil- 
lard Battery Company, the Electric Storage Battery Company, 
and the U. S. Light and Heat Corporation kindly contributed 
most of the illustrations for this section. 

The second section deals with the actual work of repairing and 
rebuilding the storage battery. Much of the material for the 
text in this section was furnished by Mr. H. E. Peers of Topeka, 
Kansas, who also supplied: most of the photographs from which 
the illustrations were made for this section. Mr. Peers is a 
practical battery man, and has been engaged in actually repair- 
ing and rebuilding batteries for many years. 

The second section will be especially valuable to the battery 
repairman. All the instructions given have been in actual use 
for years, and represent the accumulated experiences of one of 
the most up-to-date battery repair shops in the United States. 

Information concerning any of the tools and appliances may be 
obtained from the American Bureau of Engineering. 


O. A. WITTE, 
Chief Engineer, American Bureau of Engineering. 


CONTENTS | 


SECTION 1. 


Chapter Page 
1. INTRODUCTORY 2.2... .. cece ec cee cee ee cece eee neee. 1 
2. BATTERIES IN GENERAL........ 0... cL ec ccc cece eee 5 
3. CHEMICAL ACTIONS WHICH PRCDUCE ELECTRICITY......... 11 
4. HOW CHEMICAL ACTIONS PRODUCE ELECTRICITY......... 17 
5. LOSS OF CHARGE IN AN IDLE BATTERY..................... 26 
6. THE DISCHARGE PHENOMENA................ 20 cece ee eee 2G 
7. THE CHARGE PHENOMENA.......... 0... ccc cece ee ee eens 37 
8. CAPACITY OF STORAGE BATTERIUS....................085.. 40 
9. INTERNAL RESISTANCE .............. 0. cece ee eee 48 

10. BATTERY DISEASES ........ 06. ccc ccc eee ee tenes 51 

11. CONDITIONS OF OPERATION............. 0... cece eee ee eee 61 

12. HOW TO TAKE CARE OF BATTERY ON THE CAR............ 68 

13. MANUFACTURE OF STORAGE BATTERIES.................... 89 

SECTION 2. 
14, THE WORK SHOP. GENERAL INSTRUCTIONS............... 102 


15. 


16. 


The Workshop. Shop Equipment. Special Work Bench. Shelving. 
Concerning Light. Charging Methods. Charging Equipment. 
Double Charging Bench. Motor-Generator Sets. Mercury Arc 
Rectifier. Electrolytic Rectifier. Discharge Board. Tools and 
Equipment. The Battery Steamer. The Battery Plate Press. 
Battery Turntable. The Burning Lead Mold. Tagging Bat- 
teries. Precautions to Be Taken by the Repairman. Lead Burn- 
ing. Saving the Sediment. Mixing Electrolyte. 

ANALYSIS OF THE CONDITION OF THE BATTERY........... 162 

What Is the Trouble? Cutout Adjustments. Battery Trouble 
Charts. Summary of Work to Be Done on the Battery. When 
May a Battery Be Left on the Car? When Should a Battery 
Be Removed from the Car? When Is It Unnecessary to Open 
the Battery? When Must a Battery Be Opened? 

WORK ON THE BATTERY.......... 0... ccc cece ce ee ce ene ee eess 182 

Charging Batteries Before Rebuilding. How to Open a Battery. 
What Must Be Done with the Opened Battery? When to Put 
in New Plates. When the Old Plates May Be Used Again. 
Separators. Freeing Shorts. Charging, Washing and Pressing. 


Chapter 


CONTENTS 


Page 


Burning on Plates. Reassembling the Elements. Repairing the 
Case. Putting in New Jars. Putting Elements in Jars. Fill- 
ing Jars with Electrolyte. Putting on the Covers. Sealing 
Compounds. Sealing the Battery. Burning in the Connecting 
Straps with Hydrogen and Oxygen Flame. Burning in the Con- 
necting Straps with Soldering Irons. Cleaning and Painting the 


Case. Charging the Rebuilt Battery. Discharging and Testing. 


17. SPECIAL INSTRUCTIONS ......... cee cee eee eeee 


Willard Type S Batteries. Ex‘de Batteries. 


U. S. L. Batteries. 


18. CADMIUM TEST. STORING BATTERIES..... eccecceceeeeues 


Prestolite Batteries. 


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Section I 


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BL BUBUE BRIBE 


Theory and Practice 


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NBS MS i Oe RR 


ae NOSONSGIBE” PTT ECON Oe UOC He OCG GOT UG OIE EC Le Eb Leib a 


The Automobile Storage 
Battery 


CHAPTER i. 
INTRODUCTORY. 


Gasoline and electricity have made possible the modern auto- 
mobile. Each has its work to do in the operation of the ear, 
and if either fails to perform its duties, the car cannot move. 
The action of the gasoline, and the mechanisms that control it 
are comparatively simple, and easily understood, because gasoline 
is something definite which we can see and feel, and which can 
be weighed, or measured in gallons. Electricity, on the other 
hand, is invisible, cannot be poured into cans or tanks, has no 
odor, and, therefore, nobody knows just what it is. We can 
only study the effects of electricity, and the wires, coils, and 
similar apparatus in which it is present. It is for ‘this reason 
that an air of mystery surrounds electrical things, especially to 
the man who has not made a special study of the subject. 

Without electricity, there would be no gasoline engine, be- 
cause gasoline itself cannot cause the engine to operate. It is 
only when the electrical spark explodes or ‘‘ignites*’ the mix- 
ture of gasoline and air which has been drawn into the engine 
cylinders that the engine develops power. Thus an elec- 
trical ignition system has always been an essential part of every 
gasoline automobile. 

The next step in the use of electricity on the automobile con- 
sisted in the substitution of an electric lighting system for the . 
inconvenient oil or gas Jamps which were satisfactory as far 
as the light they gave was concerned, but which had the dis- 
advantage of requiring whe driver to leave his seat, and bring 


1 


2 THE AUTOMOBILE STORAGE BATTERY 


each lamy" inte lyfe. separately, vften in a strong wind or rain 
which cohstinied* many ~*matchés,-time, and frequently spoiled | 
his temper for the remainder of the evening. Electric lamps 
have none of these disadvantages. They can be controlled from 
the driver’s seat, can be turned on or off by merely turning or 
pushing a switch-button, are not affected by wind or rain, do not 
smoke up the lenses, and do not send a stream of unpleasant 
odors back to the passengers. 

The apparatus used to supply the electricity for the lamps con- 
sisted of a generator, or a ‘‘storage’’ battery, or both. The gen- 
erator alone had the disadvantage that the lamps could be used 
only while the engine was running. The battery, on the other 
hand, furnished light at all times, but had to be removed from 
the car frequently, and ‘‘charged.’’ With both the generator 
and battery, the lights could be turned on whether the engine 
was running or not, and, furthermore, it was no longer necessary 
to remove the battery to ‘‘charge,’’ or put new life into it. With 
a generator and storage battery, moreover, a reliable source of 
electricity for ignition was provided, and so we find dry batteries 
and magnetos being discarded in a great many automobiles and 
‘battery ignition’’ systems substituted. 

The development of electric lighting systems increased the pop- 
ularity of the automobile, but the mbtor car still] had a great 
drawback—cranking. Owing to the peculiar features of a gaso- 
line engine, it must first be put in motion by some external power 
before it will begin to operate under its own power. This made 
it necessary for the driver to ‘‘crank’’ the engine, or start it 
moving, by means of a handle attached to the engine shaft. 
' Cranking a large engine is difficult, especially if it is cold, and 
often results in tired muscles, and soiled clothes and tempers. 
It also made it impossible for the average woman to drive a car 
because she did not have the strength necessary to ‘‘crank”’ 
an engine. 

The next step in the perfection of the automobile was naturally 
the development of an automatic device to crank the engine, 
and thus make the driving of a car a pleasure rather than a task. 


We find, therefore, that in 1912, ‘‘self-starters’’ began to be — 


used. These were not all electrical, some used tanks of com- 


INTRODUCTORY 3 


pressed air, others acetylene, and various mechanical devices, 
such as the spring starters. The electrical starters, however, 
proved their superiority immediately, and filled such a long felt 
want that fully 98% of the various makes of automobiles now 
have electric starters. The present day motor car, therefore, 
uses gasoline for the engine only, but uses electricity for igni- 
tion, starting, lighting, for the horn, cigar lighters, hand warmers 
on the steering wheel, gasoline vaporizers, and even for shifting 
speed changing gears, and for the brakes. 


Fig. 1. The Battery 


On any car that uses an electric lighting and starting system, 
there are two sources of electricity, the generator and the bat- 
tery. These must furnish the power for the starting, or ‘‘crank- 
ing’’ motor, the ignition, the lights, the horn, and the other 
devices. The demands made upon the generator are compara- 
tively light and simple, and no severe work is done by it. The 
battery, on the other hand is called upon to give a much more 
severe service, that of furnishing the power to crank the engine. 
It must also perform all the duties of the generator when the 
engine is not running, since a generator must be in motion in 
order to produce electricity. 


4 THE AUTOMOBILE STORAGE BATTERY 


A generator is made of iron, copper, carbon, and insulation. 
These are all solid substances which can easily be built in any 
size or Shape, and which undergo very little change as parts of 
the generator. The battery is made mainly of lead, lead com- 
pounds, water and sulphuric acid. Here we have liquids as well 
as solids, which produce electricity by changes in their com- 
position, resulting in complicated chemical as well as electrical 
actions. 

The battery is, because of its construction and performance, a 
much abused, neglected piece of apparatus which is but partly 
understood, even by many electrical experts, for to understand 
it thoroughly requires a study of chemistry as well as of elec- 
tricity. Knowledge of the construction and action of a storage 
battery is not enough to make anyone an expert battery man. 
He must also know how to regulate the operating conditions 
so as to obtain the best service from the battery, and he must 
be able to make complete repairs on any battery no matter what 
its condition may be. 

In the following chapters we shall treat in detail the subjects 
of electrical and chemical reactions, construction, operation, 
maintenance, and repair, with the object of making the reader 
familiar with all phases of battery work, and to lift the veil of 
mystery from the ‘‘giant who lives in a box.’’ 


—_$— ie, memento, Di. oP a: cian 


. 
ST OGG |e oe 


CHAPTER 2. 
BATTERIES IN GENERAL. 


There are three ways of ‘‘generating”’ electricity; 1. Magnet- 
ically, 2. Chemically, 3. Thermally. The first method is that used 
in a generator, in which wires are rotated in a ‘‘field’’ in which 
magnetic forces act. The second method is that of the battery, 
and the one in which we are now interested. The third method 
consists of heating a joint of two different metals and is of no 
practical importance. 

If two unlike metals or conducting substances are placed in 
a liquid which acts chemically upon one of the substances more 
than upon the other, an electrical pressure, or ‘‘electromotive’’ 
force is caused to exist between the two metals or conducting 
substances. The greater the difference in the chemical activity 
on the substances, the greater will be the electrical pressure, 
and if the substances are connected together outside of the liquid 
by a wire‘or other conductor of electricity, an electric current 
will flow through the path or ‘‘cireuit’’ consisting of the liquid, 
the two substances which are immersed in the liquid, and the 
external wire or conductor. | 

As the current flows through the combination of the liquid, 
and the substances immersed in it, which is called a voltaic ‘‘cell,”’ 
one or both of the substances undergo chemical changes which con- 
tinue until one of the substances is entirely changed. These 
chemical changes produce the electrical pressure which causes 
the eurrent to flow, and the flow will continue until one or both 
of the substances are changed entirely. This change due to the 
chemical action may result in the formation of gases, or of 
solid compounds. If gases are formed they escape and are lost. 
If solids are formed, no material is actually lost. 

Assuming that one of the conducting substances, or ‘‘elec- 
trodes,’’ which are immersed in the liquid has been acted upon 

5 


6 THE AUTOMOBILE STORAGE BATTERY 


by the liquid, or ‘‘electrolyte,’’ until no further chemical action 
can take place, our voltaic cell will no longer be capable of 
causing a flow of electricity. If none of the substances result- 
ing from the original chemical action have been lost as gases, it 
may be possible to reverse the entire set of operations which 
have taken place. “That is, Suppose we now send a current 
through the cell from an outside source of electricity, in a. direc- 
tion which is opposite to that in which the currerit, which was 
produced by the chemical action between the electrodes and 
electrolyte, flowed.’ If this current now produces chemical ac- 
tions between electrodes and electrolyte which are the reverse 
of those which occurred originally, so that finally we have the 
electrodes and electrolyte brought back to their original compo- 
sition and condition, we have the cell just as it was before we 
used it for the production of an electrical pressuree The cell 
can now again be used as a source of electricity as long as 
the electrolyte acts tipon the electrodes, or until it is ‘‘dis- 
charged’’ and incapable of any further production of electrical 
pressure. Sending a current through a discharged eell, so 
as to reverse the chemical actions which brought about the dis- 
charged condition, is called ‘‘charging’’ the cell. 

Cells in which an electrical pressure is produced as soon as-the 
electrodes are immersed in the electrolyte are called ‘‘primary’’ 
cells. In these cells it is often impossible, and always unsatis- 
factory to reverse the chemical action as explained above. Cells 
whose chemical actions are reversible are called ‘‘storage’’ or 
‘‘secondary’’ cells. In the ‘‘storage’’ cells used today, a current 
must first be sent through the cell in order. to cause the chem- 
ical changes which result in putting the electrodes and elec- 
trolyte, in such a condition that they will be capable of pro- 
ducing an electrical pressure when the chemical changes caused 
by the current are complete. The cell now possesses all the 
characteristics of a primary cell, and may be used as a.source 
of electricity until ‘‘discharged.’’ It may then be ‘‘charged’’ 
again, and so on, the chemical action in one case causing a flow 
of current, and a reversed flow of current causing reversed chem- 
ical actions. . 

We see from the above that the ‘‘storage’’ battery does not 


BATTERIES IN GENERAL 7 


“‘store’’ electricity at all, but changes chemical into electrical 
energy when ‘‘discharging,’’ and changes electrical into chem- 
ieal energy when ‘‘charging,’’ the two actions being entirely 
reversible. The idea of ‘‘storing’’ electricity comes from the 
fact that if we send a current of electricity through the cell 
for a certain length of time, we can at a later time draw a current 
from the cell for almost the same length of time. 

Three things are therefore required in a storage cell, the liquid 
or ‘‘electrolyte’’ and two unlike substances or electrodes, through 


4 Complete Cell 
Fig. 2 


which a current of electricity can pass and which are acted upon 
by the electrolyte with a chemical action that is greater for one 
substance than the other. In the storage cell used on the auto- 
mobile to-day for starting and lighting, the electrodes are lead 
and peroxide of lead, and the electrolyte is a mixture of sulphuric 
aeid and water. The peroxide of lead electrode is the one upon 
which the electrolyte has the greater chemical effect, and it is 
called the positive or ‘‘-++’’ electrode, because when the battery 
is sending a current through an external circuit, the current 


8 THE AUTOMOBILE STORAGE BATTERY 


flows from this electrode through the external circuit, and back 
to the lead electrode, which is called the negative, or ‘‘—” 
electrode. 

When starting and lighting systems were adopted in 1912, 
storage batteries had been used for many years in electrie power 
stations. These were, however, large and heavy, and many dif- 
ficult problems of design had to be solved in order to produce 
a battery capable of performing the work of cranking the engine, 
and yet be portable, light, and small enough to occupy only a 


Fig. 8. A complete element, consisting of a positive and negative group of plates, 

hold-down blocks and separators ready for placing in the hard rubber jars 
very limited space on the automobile. As a result these condi- 
tions governing the design, the starting and lighting battery of 
to-day is in reality ‘‘the giant that lives in a box.’’ The Elec- 
trie Storage Battery Company estimates that one of its types of 
batteries, which measures only 125 inches long, 73g wide, and 
91% high, and weighs only 6312 pounds, can deliver enough 
energy to raise itself to a height of 6 miles straight up in the 
air. It must be able to do its work quickly at all times, and in 
all sorts of weather, with temperatures ranging from below 0° 
to 100° Fahrenheit. 


BATTERIES IN GENERAL 9 


The starting and lighting battery has therefore been designed 
to withstand severe operating conditions. Looking at such a bat- 
tery on a car we see a small wooden box in which are placed three 
or more ‘‘cells,’’ see Fig. 1. Each ‘‘cell’’ has a hard, black rubber 
top through which two posts of lead project. Bars of lead connect 
the posts of one cell to those of the next. To one of the posts of each 
end cell is connected a cable which leads into the car, and through 
which the current leaves or enters the battery. At the center of 
each cell is a removable rubber plug covering an opening through 
which communication is established with the inside of the cell 
for the purpose of pouring in water, removing some of the elec- 
trolyte to determine the condition of the battery, or to allow gases 
formed within the cell to escape. Looking down through this 
opening we can see the things needed to form a storage battery: 
the electrolyte, and the electrodes or ‘‘plates’’ as they are called. 
J£ we should remove the lead bars connecting one cell to another, 
and take off the black cover, we shall find that the posts which 
project out of the cells are attached to the plates which are 
broad and flat, and separated by thin pieces of wood or rubber. If 
we lift the plates out of the jar we find that they are connected 
alternately to the two lead posts, and that the two outside ones 
have a gray color. If we pull the plates out from each other, we 
find that the plates next to the two outside ones, and all other 
plates connected to the same lead post as these have a chocolate- 
_ brown color. If we remove the jar of the cell, we find that it is 
made of hard rubber. Pouring out the electrolyte we find several 
ridges which hold the plates off the bottom of the jar. The pock- 
ets formed by these ridges may contain some soft, muddy sub- 
stance. Thus we have exposed all the elements of a cell,—posts, 
plates, ‘‘separators,’’ and electrolyte. The gray colored plates 
are attached to the ‘‘negative’’ battery post, while the chocolate- 
brown colored ones are connected to the ‘‘positive’’ battery post. 
Examination will show that each of the plates consists of a skele- 
ton metallic framework which is filled with the brown or gray sub- 
stances. This construction is used to decrease the weight of the 
battery. The gray filler material is pure lead in a condition called 
‘‘spongy lead.’’ The chocolate-brown filler substance is peroxide 
of lead. a” | | 


10 THE AUTOMOBILE STORAGE BATTERY 


We have found nothing but two sets of plates,—one of pure 
lead, the other of peroxide of lead, and the electrolyte of sulphuric 
acid and water. These produce the heavy current necessary to 
crank the engine. How this is done,.and what the chemical. ac- 
tions within the cell are, are described in the next chapter. 


CHAPTER 3. 


CHEMICAL ACTIONS WHICH PRODUCE ELECTRICITY. 


Before explaining what happens within one storage cell, let 
us look into the early history of the storage battery, and see what 
a modest beginning the modern heavy duty battery had. Between 
1850 and 1860 a man named Plante began his work on the storage 
battery. His original cell consisted of two plates of metallic lead 
immersed in dilute sulphuric acid. The acid formed a thin layer 
of lead sulphate on each plate which soon stopped further action 
on the lead. If a current was passed through the cell, the lead 
sulphate on the ‘‘anode’’ or lead plate at which the current 
entered the cell was changed into peroxide of lead, while the sul- 
phate on the other lead plate or ‘‘cathode’’ was changed into pure 
lead in a spongy form. This cell-was allowed to stand for a 
couple of days and was then ‘‘discharged,’’ lead sulphate being 
again formed on each plate. Each time this cell was charged, more 
‘‘spongy’’ lead and peroxide of lead were formed. These are 
called the ‘‘active’’ materials, because it is by the chemical action 
between them and the sulphuric acid that the electricity is pro- 
duced. Evidently, the more active materials the plates contained, 
the longer the chemical action between, the acid and active ma- 
terials could take place, and hence the greater the ‘‘capacity,’’ 
or amount of electricity furnished by the cell. The process of 
charging and discharging the battery so as to increase the amount 
of active material, is called ‘‘forming’’ the plates. 

Plante’s method of forming plates was very slow, tedious, and 
expensive. If the spongy lead, and peroxide of lead could be 
made quickly from materials which could be spread over the 
plates, much time and expense could be saved. It was Faure who 
first suggested such a plan, and gave us the ‘“‘pasted’’ plate of 
to-day, which consists of a skeleton framework of lead, with the 
sponge lead and peroxide of lead filling the spaces between the 

11 


12 THE AUTOMOBILE STORAGE BATTERY 


‘‘ribs’’ of the framework. Such plates are known as ‘‘pasted” | 
plates, and are much lighter and satisfactory than the heavy solid | 
lead plates of Plante’s. Chapter 13 will describe more fully the 
processes of manufacturing and pasting the plates. 

We know now what constitutes a storage battery, and what the 
parts are that ‘‘generate’’ the electricity. How is the electricity 
produced? If we take a battery which has been entirely 
discharged, so that it is no longer able to cause a flow of current, 
and examine and test the electrolyte and the materials on the 
plates, we shall find that the electrolyte is pure water, and both 
sets of plates composed of white lead sulphate. On the other 
hand, if we make a similar test and examination of the plates and 
electrolyte of a battery through which a current has been sent 
from some outside source, such as a generator, until the current 
can no longer cause chemical reactions between the plates and 
electrolyte, we will find that the electrolyte is now eomposed of 
water and sulphuric acid, the acid comprising about 30%, and 
the water 70% of the electrolyte. The negative set of plates will 
be composed of pure lead in a spongy form, while the positive will 
consist: of peroxide of lead. 

It is evident that the chemical changes which have taken place 
in totally discharging the battery consisted in taking all the acid 
out of the electrolyte, changing the material of the positive plates 
from lead peroxide to lead sulphate, and changing the material of 
the negative plates from pure spongy lead to lead sulphate. Both 
plates are now composed of the same material, and they are im- 
mersed in pure water, which has no chemical action upon either 
plate. Such a combination cannot produce electricity, as ex- 
plained previously. | 

The foregoing description gives the final products of the chem- 
ical changes that take place in the storage battery. To under- 
stand the changes themselves requires a more detailed investiga- 
tion. The substances to be considered in the chemical actions 
are sulphuric acid, water, pure lead, lead sulphate, and lead © 
peroxide. With the exception of the pure lead, each of these sub- | 
stances is a chemical compound, or composed of several elements. 
Thus sulphuric acid is made up of two parts of hydrogen, which 
is a gas; one part of sulphur, a solid, and four parts of oxygen, 


ee a. 


a 


CHEMICAL ACTIONS WHICH PRODUCE ELECTRICITY 13 


which is also a gas; these combine to form the acid, which is a 
liquid, and which is for convenience written as H,SO,, H., rep- 
resenting two parts of hydrogen, S one part of sulphur, and O, 
four parts of oxygen. Similarly, water a liquid, is made up of 
two parts of hydrogen and one part of oxygen, represented by 
the symbol H,0. Lead is not a compound, but an element whose 
chemical symbol is Pb, taken from the Latin name for lead. Lead 
sulphate is a solid, and consists of one part of lead, a solid sub- 
stance, one part of sulphur, another solid substance, and four 


' WA ASANO NSS SWANS AANA 
¢ ~~ 


Chemical Action in aStorage Cell During 
Charge 


g 


Fig. 4 


parts of oxygen, a gas. It is represented chemically by Pb SQ,. 
Lead peroxide is also a solid, and is made up of one part of lead, 
and two parts of oxygen. In the chemical changes that take place, 
the compounds just described are to a certain extent split up into 
the substances of which they are composed. We thus have lead 
(Pb), hydrogen (H), oxygen (QO), and sulphur (S), four ele- 
mentary substances, two of which are solids, and two gases. The 
sulphur does not separate itself entirely from the substances with 
which it forms combination of H,SO, and Pb SO,. These com- 
pounds are split into H, and SO, and Pb and SO, respectively. 


14 THE AUTOMOBILE STORAGE BATTERY 


That is, the sulphur always remains combined with four parts of 
oxygen. | 

Let us now consider a single storage cell made up of electrolyte, 
one positive plate, and one negative plate. When this cell is fully 
charged, or in a condition to produce a current of electricity, the 
positive plate is made up of peroxide of lead (PbO,), the negative 
plate of pure lead (Pb), and the electrolyte of sulphuric acid 
(H,SO,). This is shown diagrammatically in figure 4. The chem- 
ical changes that take place when the cell is discharging and the 
final result of the changes are as follows: 

(a). At the positive plate: Lead peroxide (PbO,) and sulphuric 
acid (H,SO,) and two parts of hydrogen (H,) produce two parts 
of water (2H,O) and one part of lead sulphate (PbSO,). This 
may also be represented in this way: PbO,+H,S0,+H, = 
PbSO,-+2H,0. 

(b). At the negative plate: Lead (Pb) and Sulphate (SO,) 
produce lead sulphate PbSO,. This may again be represented by 
Pb-++SO, — PbSQ,. 

From (a) and (b), above, we see 
that at the positive plate the chemical 


water and lead sulphate, whereas only 
lead sulphate is produced at the nega- 
tive plate, showing that the positive 
plate is acted upon to a greater extent 
by the acid than the negative plate is. 
The storage cell therefore fulfills the 
condition necessary to have a current 
produced, namely, that we must have 
two unlike substances immersed in a 
liquid, the chemical action of which 
is greater upon one substance than 
upon the other. 


Chemical Action ina Storage Cell Durin ; . . 
Discharge The chemical changes described in 
Fig. 5 (a) and (b) are not instantaneous. 


That is, the lead, lead peroxide, and 
sulphuric acid of the fully charged cell are not changed into lead 
sulphate and water as soon as a current begins to pass through the 


changes during discharge produce | 


a cae tl ——— 


CHEMICAL ACTIONS WHICH PRODUCE ELECTRICITY 15 


cell. This action is a gradual one, small portions of these substances 
being changed ata time. The greater the current that flows through 
the cell, the faster will the changes occur. The changes will continue 
to take place as long as any lead, lead peroxide, and sulphuric acid 
remain. The faster these are changed into lead sulphate and water, 
the shorter will be the time that the storage cell can furnish a cur- 
rent, or the sooner it will be discharged. When the cell is completely 
discharged, we will have the conditions shown in the lower part of 
the cell of figure 5. 

Taking the cell in its discharged condition, let us now connect 
the cell to a dynamo and send current through the cell from the 
positive to the negative plates. This is called ‘‘charging’’ the cell. 
The lead sulphate and water will now gradually be changed back 
into lead, lead peroxide, and sulphuric acid. The lead sulphate 
which is on the negative plate is changed to pure lead; the lead 
sulphate on the positive plate is changed to lead peroxide, and sul-° 
phuric acid will be added to the water. The changes at the positive 
plate may be represented as follows: 

Lead sulphate (PbSO,) and water (2H,O) and sulphate (SO,) 
produce sulphuric acid (2H,SO,) and lead peroxide (PbO,), or 

PbSO, + 2H,0 + SO, = 2H,SO, + PbO, 
Pb + SO, + 2H, + 20 + SO, = 2H,SO, + PbO, 
(Pb + 20) + (2H, + S80,-+ S0,) = 2H,S0O, + PbO, 

The changes at the negative plate may be expressed as follows: 

Lead sulphate (PbSO,) and hydrogen (H,) produce sulphuric 
acid (H,SO,) and lead (Pb), or 


PbSO, -+ H, = H,S0, -+ Pb 
Pb -+ SO, + H, = H,80, + Pb 
Pb + (SO,-+-H.) = H,80, -+ Pb 


These changes produced by sending a eurrent through the cell 
are also gradual, and will take place faster as the current is made 
greater. When all the lead sulphate has been used up by the 
ehemical changes caused by the current, no further charging can 
_ take place. If we continue to send a current through the cell 
after it is fully charged, the water will continue to be split up into 
_hydrogen and oxygen. Since, however, there is no more lead 


16 THE AUTOMOBILE STORAGE BATTERY 


sulphate left with which the hydrogen and oxygen can combine 
to form lead, lead peroxide, and sulphuric acid, the hydrogen and 
oxygen rise to the surface of the electrolyte and escape from the 
cell. This is known as ‘‘gassing,’’ and is an indication that the 
eell is fully charged. 


CHAPTER 4. 


HOW CHEMICAL ACTIONS PRODUCE ELECTRICITY. 


In Chapter 3 we studied the chemical changes that occurred in 
the cell both when the cell was producing a current, and when a 
current was sent through the cell from a dynamo. But we have 
not as yet learned how these chemical actions preduce electricity. 
The fact that the chemical actions produce electricity, and 
that, on the other hand, electricity produces chemical changes 
shows that electricity and chemical changes are closely asso- 


ciated. 


A complete study of the electricity which chemical changes 
make available would furnish material for a book many times 


“" te Cell During Discharge 


thicker than this one, as it 
forms a distinct branch of 
science known as Electro- 
Chemistry. A general in- 
vestigation will be made, 
however. No chemical 
change, or chemical reac- 
tion is supposed to produce 
electricity, but merely to 
make it available for use. 
Thus the storage battery 
contains the electricity be- 
fore any chemical change 
takes place. As soon as the 
battery circuit is closed 
through the lamps or 
starting motor, however, 
the electric current flows 
out of the battery at the 


positive terminal, and back into the battery at the negative terminal. 
Where is the electricity, and in what form, and how does the mere 
closing of the battery circuit cause it to appear? 


17 


18 THE AUTOMOBILE STORAGE BATTERY 


‘When we think of an electric current flowing through a wire, 
we take it for granted that at any point in the wire the cur- 
rent is flowing in one direction only, just lke water flowing 
through a pipe. When, however, a current flows through a 


liquid, like the battery electrolyte, it is supposed to be | 


flowing both from the positive to the negative, and from 
the negative to the positive. These currents are carried 
by the sulphuric acid. As long as this acid is not mixed with 
water, it cannot carry any current. -When the acid is poured 


into the water, it is partly divided into hydrogen (H,) and 
sulphate (SO,). This happens as soon as the acid and water are _ 
mixed. The hydrogen has a certain amount of positive elec- 


tricity attached to it, and the sulphate a certain amount of neg- 
ative electricity. Where did the electricity come from? It 
was in the acid in the first place, but as long as the acid was not 
separated into hydrogen and sulphate, the positive electricity 
of the hydrogen neutralized that of the sulphate. The particles 
which have the electricity attached to them are called ‘‘ions.”’ 
They are extremely small, and the electricity they carry is spoken 
of as a positive or a negative ‘‘charge’’ of electricity, or simply 
‘‘eharge.’’ We then have a quantity of hydrogen ions which 


are carrying positive electricity or have a positive ‘‘charge.”’ 


Similarly the sulphate ions carry a certain amount of negative 
electricity, or have a negative ‘‘charge.’’ The ions are entirely 
unlike the substances as we see them and have different char- 
acteristics. 

Leaving the acid with its ‘‘charges’’ of electricity, let us con- 
sider the electrodes or plates. Like the acid, the lead and lead 
peroxide contain certain amounts of electricity, both positive 
and negative. When the electrodes are immersed in the elec- 


trolyte these amounts of positive and negative charges are made © 


available. 


At the negative plate, which is composed of pure lead, some of | 


the lead separates from the plate, and mixes with the acid in 
the form of ‘‘ions,”’ each ion carrying a small amount, or charge 
of electricity. The lead ion leaves a similar and equal amount 
negative electricity on the lead plate. Only a very few of these 
lead ions are formed as long as no current passes through the 


HOW CHEMICAL ACTIONS PRODUCE ELECTRICITY 19 


battery. This is due to the fact that the positive charge on the 
lead ion and the negative charge on the lead plate have a strong 
attraction for each other. After a few ions have been formed, 
the attraction is so strong that no more are formed. Similarly, 
for the positive plate, small particles of the lead peroxide enter 


CHARGED CELL ON OPEN CIRCUIT 


Ww 
ae 
< 
y 
a 
QO 
{ 
w 
a 


LEAD PEROXIDE PLATE 


Fig. 7 


the electrolyte, and take with them certain quantities of nega- 
tive electricity, or negative charges, leaving the plate with an 
equal positive charge. As long as the circuit outside the battery 
is Open, no current can flow, because the negative and positive 
quantities of electricity, or ‘‘charges’’ on the plates are kept 
there by the opposite charges on the ions that have entered the 


20 THE AUTOMOBILE STORAGE BATTERY 


acid. The fact that the minute particles called ‘‘ions”’ carry 
with them certain quantities of electricity is indicated by writing 
the signs ‘‘+-’’ and ‘‘—”’ after them. Thus, a lead ion is written 
(Pb*t), and a lead peroxide ion PbO,”). 

Figure 7 shows the conditions described above. At the nega- 
tive plate is a layer of lead ions which have gone into the acid, 
carrying positive charges and leaving an equal number of nega- 


CELL DISCHARGING 


LEAD PLATE 


LEAD PEROXIDE PLATE 


NPI LPI PI I SIL LI I 


+t het ttttettte te ttet 


tive charges on the lead plate. Similarly, at the positive plate 
is a layer of lead peroxide ions which have entered the acid, 
carrying negative charges, and leaving an equal number of posi- 
tive charges on the positive plate. The acid itself has been split 
by the water, into hydrogen ions and sulphate ions, the hydrogen 
ions carrying positive charges, and the sulphate ions carrying 
negative charges. The ions of the acid are distributed through- 
out the electrolyte. As the figure shows, the number of positive 


HOW CHEMICAL ACTIONS PRODUCE ELECTRICITY 21 


and negative ions are equal, and as they attract each other 
strongly, they cannot move away from each other, and hence no 
current can flow. 

If we now connect the positive and negative plates together 
through a starting motor, as shown in figure 8, conditions will 
be changed. The positive charges on the positive plate will move 


0 
) 
0 
a 
> 
A 
0) 
m 
U 
-) 
m 
- 


2) 


U U U0 Uv U\/ 7 0 v 
gicgiicic\lelr\lc\loels 
HTolololol ol] of of o 
ollollololollollol_ojio 
KNSNENENAE ADEN ENON 


LEAD SULPHATE PLATE 
LEAD SULPHATE PLATE 


: v v 
v J 
W) i) 

a O \ Ny O w 


Fig. 9 


along the wire and through the motor to the negative plate. 
There they will meet the negative charges. In order that the 
positive and negative charges on the plates may send a current 
through the starting motor, the lead ions and the lead peroxide 
ions must be removed from the surfaces of the plates. Otherwise 
the attraction of the lead and lead peroxide ions for the charges 


22 THE AUTOMOBILE STORAGE BATTERY 


on the plate will hold the latter on the plate. Now, each ion has 
a tendency to move through the acid. As soon as some of the 
negative charges start to leave the lead plate to go through the 
motor, the lead ions start to move toward the lead peroxide plate. 
They have hardly started to move, however, before they meet sul- 
phate ions from the acid. The sulphate ions and the lead ions 
combine and form lead sulphate. Similarly, the lead peroxide 
ions begin to leave the positive plate. They are then split up into 
lead ions (Pb**) and oxygen ions (20°). This leaves hydrogen 
ions from the acid, and oxygen ions from the lead peroxide un- 
accounted for. The two have opposite charges, and hence attract 
each other, uniting to form water. This gives us lead sulphate 
and water as the final products of discharging a battery, which 
agrees with, the equation on page 14. 

The lead of a negative plate, and the lead peroxide of the 
positive plate are called ‘‘active’’ materials. They are not the 
only substances which ean be used for storage batteries. Many 
combinations for electrolyte and plates have been tried, but the 
lead, lead peroxide, and sulphuric acid combination has worked 
out to be the best combination for practical use. They do not 
ereate electricity, as was explained above, but the chemical 
ehanges that take place in the battery readjust the small quanti- 
ties of electricity or ‘‘charges’’ which are carried by the ‘‘ions”’ 
so that we are able to force the charges to move through the 
starting motor, lamps, or other apparatus. The water in the bat- 
tery causes the ‘‘ions’’ to form as separate particles carrying 
‘‘charges.’’ Without water we could not have a battery, as the 
electricity bound up in the active materials would never be avail- 
able, because the negative and positive charges neutralize each 
other ordinarily, and must be separated from each other long 
enough to be forced to run the starting motor, light the lamps, and 
furnish current for the ignition. Once the charges are separated, 
they have a tendency to unite with those of opposite sign. The 
water prevents a complete reunion of the ions carrying the 
charges, but the tendency they have to unite gives the voltage, or 
electromotive force of the battery. When a current is made to 
flow through the motor, charges are uniting, and a current will 
continue to flow as long as there are charges available. As soon 


q 


ee, I ee. 


HOW CHEMICAL ACTIONS PRODUCE ELECTRICITY 23 


as charges unite through the motor, more are formed in the elec- 
trolyte from the lead, lead peroxide, and sulphuric acid. When 
these materials have all been used so that we have only lead sul- 
phate and water in the battery, no more charges are available, 
and the battery can no longer produce a current. 

In practice, a battery is never discharged until all the lead, 
lead peroxide, and sulphurie acid are changed into lead sulphate 
and water. As lead sulphate is formed, it fills up the pores in 
the plates, and covers the remaining lead and lead peroxide so 
that they are practically sealed in and made useless. The removal 
of the sulphate becomes increasingly difficult as more is formed, 
and, therefore, a battery should not be discharged entirely. This 
subject will be treated. more completely later. 


Charging Discharging 


Fig. 10 


The battery is now completely discharged. We now send a 
continuous current through it so that the current enters through 
the positive terminal, and leaves through the negative terminal, 
. Fig. 10. This direction of flow is just the reverse of the current 
produced by the battery in discharging. The current we are send- 
ing through the battery gradually puts it in a condition in which 
it can again furnish a current. We saw how the battery produces 
a current when it is fully charged, that is, when we had a plate 
of pure lead, a plate of lead peroxide and an electrolyte of acid 
and water. Now we are starting with two plates of lead sul- 
phate immersed in water. How does a current charge the bat- 
tery? . 

When a battery is completely discharged, we have lead sul- 


24 THE AUTOMOBILE STORAGE BATTERY 


phate at each plate,.and water. The water has the power to 
split the lead sulphate into lead (Pb), and sulphate (SO,). The 
water itself is separated, to a slight extent, into hydrogen (H,), 
and oxygen (QO). These parts into which the lead sulphate and 
water separate each carry a ‘‘charge’’ of electricity, some posi- 
tive, and some negative. The lead and hydrogen are positive, and 
the sulphate and oxygen negative. We thus have lead ‘‘ions’’ 
(Pb*t), sulphate ions (SO, -), hydrogen ions (H,*), and oxygen 
ions (O°). , As long as the battery is not being charged, the + 
and — charges attract each other, and no chemical changes occur. 
When the battery is connected to a generator for charging, the 
generator produces positive charges on the positive plate, and 
negative charges on the negative plate. The positive charges 
on the positive plate will attract all the negatively charged ions, 
while the negative charges on negative plate will attract all 
the positively charged ions. As a result, the lead and hydrogen 
ions start to move toward the negative plate, and the sulphate 
and oxygen ions toward the positive plate. The Pb** which be- 
gins to move from the positive to the negative plate meets imme- 
diately with the 20° and PbO, is formed. This seems to then 
become PbO,”*. The positive charges on the positive plates 
attract the PbO, ~, and the latter is deposited on the plate as 
ordinary lead peroxide. The Pb** at the negative plate, is at- 
tracted by the negative charges on the negative plate, and since 
the Pb*t is on the negative plate it is immediately deposited 
as metallic lead, since the negative and positive charges neutralize 
one another and take the charge away from the lead. This 
gives us the changes which occur at the plates so as to give us 
the lead and lead peroxide of a charged battery. We still need 
sulphuric acid however. At the positive plate, the sulphate ion 
meets the hydrogen ion, which is free to travel toward the nega- 
tive plate, and sulphuric acid is formed. At the negative plate, 
the sulphate ion starts to move toward the positive plate, but 
meets the hydrogen ion which is moving toward the negative 
plate, and sulphurie acid is formed, although half of the acid is 
always separated into hydrogen and sulphate. This accounts 
for all the materials. 


HOW CHEMICAL ACTIONS PRODUCE ELECTRICITY 25 


We have thus taken the battery through a charge and dis- 
charge, both chemically, and electrically. The actions described 
for discharge take place faster when a heavy current is drawn 
from the battery. The speed of the charge actions depends 
upon the voltage of the generator, the motions of the ions being 
increased in speed as the voltage is increased. As far as current 
flow in and out of the battery is concerned, this depends upon 
the positive and negative charges on the positive and negative 
plates. When the battery is discharging, these charges will pass 
into the external circuit with increasing speed as the resistance 
of the circuit decreases. When the battery is being charged, the 
charges on the plate attract the charges on the ions, and when 
the charges reach the plates, the opposite charges on lon and 
plate neutralize one another. The result of the ions travelling in 
opposite directions in the electrolyte is to produce a current 
which seems to flow in only one direction in the external circuit. 
The ions of the lead, lead peroxide, and lead sulphate all tend 
to move toward one or the other battery plate, but because they 
are so few in number, and because there are so many hydrogen 
and sulphate ions in the electrolyte, they have hardly begun 
to move before they combine with the ions of the acid to form 
lead sulphate and water. Hence, the ions of the active plate 
materials move exceedingly minute distances. Those of the acid, 
especially the hydrogen ion, move through all parts of the elec- 
trolyte. The chemical actions take place not only at the out- 
side surfaces of the plates, but wherever acid, lead or lead perox- 
ide, or lead sulphate come in contact with each other. We know 
that the acid soaks in to all parts of the plates, and therefore 
the actions take place throughout the entire plate. The materials 
on the plates must therefore be porous in order to allow the acid 
to soak into them easily. 

The “pasted” plate is used almost entirely for starting and 
lighting service. The plates are not made entirely of the spongy 
lead and lead peroxide. Neither of these substances are tough 
enough to be made into plates. They must, therefore, be held 
in place. We thus find that each plate consists of a skeleton 
framework of lead, the pastes filling up the spaces between the 
ribs. 


CHAPTER 5. 
LOSS OF CHARGE IN AN IDLE BATTERY. 


Before taking up the study of discharge by drawing a current 


from the battery, let us see what happens if a fully charged — 


battery is allowed to stand idle on open circuit, that is, with no 


wires or cabes attached to its terminals. It has been found that : 
such a battery will gradually become discharged and that it | 


must be given an ocasional ‘‘freshening’’ charge. 

Now, as we have learned, when a battery discharges lead sul- 
phate forms on each plate, and acid is taken from the electro- 
lyte as the sulphate forms. In our idle battery, therefore, such 
actions must be taking place. The only difference in this case is 
that the sulphate forms without any current passing through the 
battery. The actions at the lead and lead peroxide must, there- 
fore, be independent of each other. At the lead peroxide plate we 
have lead peroxide paste, lead grid, and sulphuric acid. These 
are all the elements needed to produce a storage battery, and 
as the lead peroxide and the lead are touching each other, each 
lead peroxide plate really forms a short circuited cell. Why 
does this plate not discharge itself completely? A certain amount 
of discharge does take place, and results in a layer of lead sul- 
phate forming between the lead peroxide and the grid. The sul- 
phate, having high resistance then protects the lead grid and 
prevents any further action. This discharge action therefore does 
not continue, but causes a loss of a certain part of the charge. 

At the negative plate, we have pure spongy lead, and the grid. 
This grid is not composed entirely of lead, but contains a per- 
eentage of antimony, a metal which makes the grid harder and 
stronger. There is but very little difference of potential between 
the spongy lead and the grid. A small amount of lead sulphate 
does form, however, on the surface of the negative plate. This 
is due to the action between the spongy lead and the electrolyte. 

26 


a 


LOSS OF CHARGE IN AN IDLE BATTERY 27 


Some of the lead combines with the acid to form lead sulphate, 
but after a small amount has been formed the action is stopped 
because a balanced chemical condition is soon obtained. 

Thus only a small amount of lead sulphate is formed at each 
plate, and the cell thereby loses only a small part of its charge. 
In a perfectly constructed battery the discharge would then stop. 
The only further action which would take place would be the 
slow evaporation of the water of the electrolyte. As the level 
of the electrolyte dropped below the tops of the plates, crystalliza- 
tion and sulphation would take place on the part of the negative 
plate above the electrolyte. The loss of charge which actually 
occurs in an idle charged battery is greater than that due to the 
formation of the small amounts of sulphate on the plates, and the 
evaporation of the water from the electrolyte. 

Does an idle cell discharge itself by decomposing its electro- 
lyte? We have a difference of potential of about two volts 
between the lead and lead peroxide plate. Why is the electro- 
lyte not decomposed by this difference? At first it might seem 
that the water and acid should be separated into its parts, and 
hydrogen liberated at the negative plate. As a matter of fact, 
very little hydrogen gas is set free in an idle charged cell be- 
eause to do so would require a voltage of about 2.5. At two 
volts, so little gas is formed that the loss of charge due to it 
may be neglected entirely. 

The greatest loss of charge in an idle battery results from con- 
ditions arising from the processes of manufacture, internal 
troubles, and leakage between terminals. The grids of a cell 
are an alloy of lead and antimony. These are mixed while in a 
molten condition, and are then allowed to cool. If the cooling is 
not done properly, or if a poor grade of antimony is used, the 
resulting grid is not a uniform mixture of antimony and lead. 
There will be areas of pure lead, with an air hole here and there. 
The lack of uniformity in the grid material results in a local dis- 
charge in the grid. This causes-some loss of charge. 

If the active material completely fills the spaces between the 
grids, the acid formed as the cell is charged may not be able to 
diffuse into the main body of the electrolyte, but forms a small 
pocket of acid in the plate. This acid will cause a discharge between 


28 THE AUTOMOBILE STORAGE BATTERY 


paste and grid and a coating of lead sulphate forms on the grid, 
resulting in a certain loss of charge. 

In the process of manufacturing and ‘‘forming’’ plates, graph- 
ite 1s sometimes used to give porosity to the paste, resulting 
in local action which causes a loss of charge. In general 
any metallic impurity in a cell will cause a loss at the lead 
plate. When a cell is charged, the current causes the metals 
to deposit on the lead plate. Local cells are formed by the metal- 
lic impurity, the lead plate, and the acid, and these tiny cells will 
discharge completely, causing a loss of charge. Such metals 
include iron, copper, tin, arsenic, antimony, and platmum. Of 
these, iron is perhaps the most destructive, as it travels back 
and forth from plate to plate, causing a loss of charge. The 
ions of this metal absorb an additional amount of electricity at 
the peroxide plate which they carry to the lead plate and there 


lose it. This action is continuous, and even a small amount of | 


iron in an idle cell can cause an appreciable loss of charge in 
one day. 


Incomplete removal of forming agents causes some local ac- | 


tion in an idle cell which results in a loss of charge. Such sub- 
stances are supposed to have been removed automatically as 
the forming process is completed, but some may remain and 
cause trouble. 

Another cause of loss of charge in an idle cell is leakage of 
current between the terminals on the outside of the battery. Dur- 
ing charge, the bubbles of gas which escape from the electrolyte 
carry with them minute quantities of acid which may deposit on 


—— 


the top of the battery and gradually form a thin conducting | 


layer of electrolyte through which a current will flow from the 
positive to the negative terminals. This danger may be avoided 
by carefully wiping any moisture from the battery. Condensation 
of moisture from the air, on the top or sides and bottom of a 
battery will cause the same condition. This will be especially 
noticeable if a battery is kept in a damp place. 

Impurities in any form are therefore to be guarded against. 
The use of impure acid or water will introduce objectionable 
substances. Every impurity causes local actions which cause 
a loss of charge and shorten the life of the battery. 


a 


—__ er 


f- 


CHAPTER 6. 
THE DISCHARGE PHENOMENA. 


Considered chemically, the discharge of a storage battery con- 
sists of the changing of the spongy lead and lead peroxide into 
lead sulphate, and the abstraction of the acid from the electro- 
lyte. Considered electrically, the changes are more complex, and 
require further investigation. The voltage, internal resistance, 
rate of discharge, capacity, and other features must be considered, 


CELL VOLTAGE 


IZ 14 15 16 17 18 19 20 3 2 3 
TIME OF CHARGE —-MINUTE S&S 


Fig. 11 


and the effects of changes in one upon the others must be studied. 
This proceeding is simplified considerably if we consider each 
point separately. The abstraction of the acid from the electro- 
lyte gives us the most reliable method of determining the con- 
dition of charge or discharge in the battery, and must also be 
studied. 


29 


30 THE AUTOMOBILE STORAGE BATTERY 


Voltage Changes During Discharge. At the end of a charge. 
and before opening the charging circuit, the voltage of each cell 
is about 2.6 to 2.7 volts. As soon as the charging circuit is opened, 
the cell voltage drops rapidly to about 2.1 volts, within three or 
four minutes. This is due to the formation of a thin layer of 
lead sulphate on the surface of the negative plate and between 
the lead peroxide and the metal of the positive plate. Figure 11 
shows how the voltage changes during the last eight minutes of 
charge, and how it drops rapidly as soon as the charging circuit is 
opened. The final value of the voltage after the charging circuit 
is opened is about 2.15-2.18 volts. This is more fully explained in 


Chapter 7. If a current is drawn from the battery at the instant — 


VOLTS 
2.2 


the charge is stopped, this drop is more rapid. At the beginning , 


of the discharge the voltage has already had a rapid drop from 
the final voltage on charge, due to the formation of sulphate as 
explained above. When a current is being drawn from the bat- 


tery, the sudden drop is due to the internal resistance of the | 


cell, the formation of more sulphate, and the abstracting of the 


acid from the electrolyte which fills the pores of the plate. The © 


density of this acid is high just before the discharge is begun. 
It is diluted rapidly at first, but a balanced condition is reached 
between the density of the acid in the plates and in the main 
body of the electrolyte, the acid supply in the plates being main- 
tained at a lowered density by fresh acid flowing into them from 
the main body of electrolyte. After the initial drop, the voltage 
decreases more slowly, the rate of decrease depending on the 


THE DISCHARGE PHENOMENA 31 


amount of curfent drawn from the battery. The entire process 
is shown in figure 12. Lead sulphate is being formed on the sur- 
faces, and in the body of the plates. This sulphate has a higher 
resistance than the lead or lead peroxide, and the internal resis- 
tance of the cell rises, and contributes to the drop in voltage. As 
this sulphate forms in the body of the plates, the acid is used 
up. At first this acid is easily replaced from the main body of 
the electrolyte by diffusion. The acid in the main body of the 
electrolyte is at first comparatively strong, or concentrated, caus- 
ing a fresh supply of acid to flow into the plates as fast as it 
is used up in the plates. This results in the acid in the electro- 
lyte growing weaker, and this, in turn, leads to a constant de- 
crease in the rate at which the fresh acid flows, or diffuses into 
the plates. Furthermore, the sulphate, which is more bulky than 
the lead or lead peroxide fills the pores in the plate, making it 
more and more difficult for acid to reach the interior of the plate. 
This increases the rate at which the voltage drops. 

The sulphate has another effect. It forms a cover over the 
paste which has not been acted upon, and makes it practically 
useless, since the acid is almost unable to penetrate the coating 
of sulphate. We thus have quantities of active material which 
are entirely enclosed in sulphate, thereby cutting down the 
amount of energy which can be taken from the battery. Thus the 
formation of sulphate throughout each plate and the abstraction 
of acid from the electrolyte cause the voltage to drop at a con- 
stantly increasing rate. 

Theoretically, the discharge may be continued until the voltage 
drops to zero, but practically, the discharge should be stopped 
when the voltage of each cell has dropped to 1.7. If the dis- 
charge is carried on beyond this point all the spongy lead and 
lead peroxide have either been changed into lead sulphate, or 
have been covered up by the sulphate so effectively that they 
are almost useless. Plates in this condition require a very long 
charge in order to remove all the sulphate. Another danger 
arises if the discharge is continued. The lead of the grid is grad- 
ually changed to lead sulphate, and when the cell is recharged, 
the sulphate will be changed to spongy lead and lead | peroxide, 
and the grid is consequently weakened. 


32 THE AUTOMOBILE STORAGE BATTERY 


The cell voltage will rise somewhat every time the discharge 
is stopped. This is due to the diffusion of the acid from the 
main body of electrolyte into the plates, resulting in an increased 
concentration in the plates. If the discharge is continuous, es- 
pecially if at a high rate, this rise in voltage will bring the cell 
up to its normal voltage very quicky on account of the more rapid 
diffusion of acid which will then take place. 

The voltage does not depend upon the area of the plate surface 
but upon the nature of the active materials and the electrolyte. 
Hence, although the plates of a cell are gradually being covered 
with sulphate, the voltage measured when no current is flowing, 
will fall slowly, and not in proportion to the amount of energy 
taken out of the cell. It is not until the plates are pretty 
thoroughly covered with sulphate, thus making it difficult for 
the acid to reach the active material, that the voltage begins to 
drop rapidly. This is shown clearly in figure 12, which shows 
that the cell voltage has dropped only a very small amount when 
the cell is 50% discharged. With current flowing through the 
cell, however, the increased internal resistance causes a marked 
drop in the voltage. Open circuit voltage is not useful, therefore 
to determine how much energy has been taken from the battery. 

Acid Density. The electrolyte of a lead storage battery is a 
mixture of chemically pure sulphuric acid, and chemically pure 
water, the acid forming about 30 per cent of the volume of elec- 
trolyte when the battery is fully discharged. The pure acid 


has a ‘‘specific gravity’’ of 1.835, that is, it is 1.835 ag heavy | 


as an equal volume of water. The mixture of acid and water 
has a specific gravity of about 1.300. As the cell discharges, acid 
is abstracted from the electrolyte, and the weight of the latter 
must therefore grow less, since there will be less acid in it. The 
ehange in the weight, or specific gravity of the electrolyte is 
the best means of determining the state of discharge of a cell, pro- 
vided that the cell has been used properly. In order that the 
value of the specific gravity may be used as an indication of 
the amount of energy in a battery, the history of the battery 
must be known. Suppose, for instance, that in refilling the bat- 
tery to replace the water lost by the natural evaporation which 
occurs in the use of a battery, acid, or a mixture of acid and 


- | 


THE DISCHARGE PHENOMENA 33 


water has been used. This will result in the specific gravity 
being too high, and the amount of energy in the battery will be 
less than that indicated by the specific gravity. Again, if pure 
water is used to replace electrolyte which has been spilled, 
the specific gravity will be lower than it should be. In a bat- 
tery which has been discharged to such an extent that much of 
the paste has been covered by a layer of tough sulphate, or if 
a@ considerable amount of sulphate and active material has been 
loosened from the plates and has dropped to the bottom of the 


“SEI —|----}— 


> 


CIFIC GRAVITY 


91100 


LEAT 
LEE YET TET 


|. 


= 


TL cette 
‘TCE EAE 


70 60 5 
RCENT CAPACITY IN BATTERY. 


Fig. 183 


eells, it will be impossible to bring the specific gravity of the elec- 
trolyte up to 1.300, even though a long charge is given. There 
must, therefore, be a reasonable degree of certainty that a bat- 
tery has been properly handled if the specific gravity readings are 
to be taken as a true indication of the condition of a battery. 
Where a battery does not give satisfactory service even though 
the specific gravity readings are satisfactory, the latter are 
not reliable as indicating the amount of charge in the battery. 
As long as a discharge current is flowing from the battery, the 


34 THE AUTOMOBILE STORAGE BATTERY | 


acid within the plates is used up and becomes very much diluted. | 
Diffusion between the surrounding electrolyte and the acid in 


the plates keeps up the supply needed in the plates in order to 
carry on the chemical changes. When the discharge is first begun, 
the diffusion of acid into the plates takes place rapidly because 
there is little sulphate clogging the pores in the paste, and because 
there is a greater difference betwéen the concentration of acid in 
the electrolyte and in the plates than will exist as the discharge 
progresses. As the sulphate begins to form and fill up the pores of 
the plates, and as more and more acid is abstracted from the elec- 
trolyte, diffusion takes place more slowly. 

If a battery is allowed to stand idle for a short time after a 
partial discharge, the specific gravity of the electrolyte will de- 
crease because some of the acid in the electrolyte will gradually 
flow into the pores of the plates to replace the acid used up while 
the battery was discharging. Theoretically the discharge can be 
continued until all the acid has been used up, and the electro- 
lyte is composed of pure water. Experience has shown, how- 
ever, that the discharge of the battery should not be continued after 
the specific gravity of the electrolyte has fallen to 1.150. As far 
as the electrolyte is concerned, the discharge may be carried farther 
with safety. The plates determine the point at which the discharge 
should be stopped. When the specific gravity has dropped from 
1.300 to 1.150, so much sulphate has been formed that it fills all 
the pores in the active material on the plates, and is beginning to 
form a tough covering over the paste. Figure 13 shows the change 
in the density of the acid during discharge. 

Changes at the Negative Plate. Chemically, the action at the 
negative plate consists only of the formation of lead sulphate 
from the spongy lead. The lead sulphate is only slightly soluble 
in the electrolyte and is precipitated as soon as it 1s formed, 
leaving hydrogen ions, which then go to the lead peroxide plate to 
form water with other hydrogen ions and oxygen ions released 
at the peroxide plate. The sulphate forms more quickly on the 
surface of the plate than in the inner portions because there is a 
constant supply of acid available at the surface, whereas the 
formation of sulphate in the interior of the plate requires that acid 
diffuse into the pores of the spongy lead to replace that already used 


———— 


THE DISCHARGE PHENOMENA 30 


up in the formation of sulphate. In the negative plate, however, the 
sulphate tends to form more uniformly throughout the mass of 
the lead, because the spongy lead is more porous than the lead. 
peroxide, and because the acid is not diluted by the formation 
of water as in the positive plate. When the discharge has pro- 
ceeded until the specific gravity of the electrolyte has decreased 
to 1.150, the sulphate has formed a tough coating over the surface 
of the plate and has filled the pores of the lead to such an extent 
that most of the spongy lead that remains is prevented from re- 
acting with the acid because of the high resistance of the sul- 
phate covering it. If the discharge is continued beyond this 
point, the acid begins to attack the grids and form a layer of 
sulphate on them. Subsequent charge will change this sulphate to 
spongy lead, thus making the grids weaker by the amount of the 
lead which formed the sulphate. , 

The sulphate has a greater volume than the lead from which 
it is formed and there is, therefore, an actual increase in the 
volume of the paste during discharge. The spongy lead being 
tough and coherent, this expansion does not cause the paste to 
fall from the plate, but simply results in a bulging out of mate- 
rial between the grid bars. 

Changes at the Positive Plate. In a fully charged positive plate 
we have lead peroxide as the active material. This is composed 
of lead and oxygen. From this fact it is plainly evident that 
during discharge there is a greater chemical activity at this plate 
than at the negative plate, since we must find something to com- 
bine with the oxygen in order that the lead may form lead sul- 
phate with the acid. In an ideal cell, therefore, the material 
which undergoes the greater change should be more porous than 
the material which does not involve as great a chemical reaction. 
In reality, however, the peroxide is not as porous as the spongy 
lead, and does not hold together as well. 

The final products of the discharge of a positive plate are lead 
sulphate and water. The lead peroxide must first be reduced to 
lead, which then combines with the sulphate from the acid to form 
lead sulphate, while the oxygen from the peroxide combines with 
the hydrogen of the acid to form water. There is, therefore, a 
greater activity at this plate than at the lead plate, and the forma- 


36 THE AUTOMOBILE STORAGE BATTERY 


tion of the water dilutes the acid in and around the plate so that 
the tendency is for the chemical actions to be retarded. When 
.the discharge has just begun, the positive plate grows darker in 
color, showing that the lead sulphate at first forms a definite 
compound with the lead peroxide. As the discharge progresses, 
the sulphate begins to form in white scales on the surface of the 
plate. 

The sulphate causes the active material to bulge out because 
it occupies more space than the peroxide. This causes the lead 
peroxide at the surface to begin falling to the bottom of the jar 
in fine dust-like particles, since the peroxide here holds together 
very poorly. 

The abstraction of acid from the electrolyte takes place at both 
plates, of course, but the positive has an additional handicap on 
account of the water formed in its pores. Experiments have 
shown that in order to have the peroxide plate working at its 
greatest capacity, the density of the electrolyte should be more 
than 1.300, while the negative has the greatest capacity when 
the electrolyte has a density of 1.220. The discharge of the bat- 
tery, therefore, tends to have the negative operating at its great- 
est capacity, while the conditions at the positive are just oppo- 
site from what they should be in order to obtain the greatest | 
eapacity from this plate. 


CHAPTER 7. 
THE CHARGE PHENOMENA. 


Voltage. Starting with a battery which has been discharged 
until its voltage has decreased to 1.7 per cell, we pass a current 
through it and cause the voltage to rise steadily. Figure 14 shows 
the changes in voltage during charge. Ordinarily the voltage 
begins to rise immediately and uniformly. If, however, the bat- 
tery has been left in a discharged condition for some time, or has 
been ‘‘over discharged,’’ the voltage rises very rapidly for a 
fraction of the first minute of charge and then drops rapidly to 


j z BS 4 5 
HOURS ON CHARGE 
Fig. 14 


the normal value and thereafter begins to rise steadily to the end 
of the charge. This rise at the beginning of the charge is due 
to the fact that the density of the acid in the pores of the plates 
rises rapidly at first, the acid thus formed being prevented from 
diffusing into the surrounding electrolyte by the coating of 
sulphate. As soon as this sulphate is broken through, diffusion 
takes place and the voltage drops. 

As shown in Figure 14 the voltage remains almost constant 
between the points M and N. At N the voltage begins to rise 
because the charging chemical reactions are taking place farther 
and farther in the inside parts of the plate, and the concentrated 
acid formed by the chemical actions in the plates is diffusing 


37 


38 THE AUTOMOBILE STORAGE BATTERY | 


into the main electrolyte. This increases the battery voltage 
and requires a higher charging voltage. 

- At the point marked O, the voltage begins to rise very rapidly. 
This is due to the fact that the amount of lead sulphate in the | 
plates is decreasing very rapidly, allowing the battery voltage 
to rise and thus increasing the charging voltage. Bubbles of 
gas are now rising through the electrolyte. 

At P, the last portions of lead sulphate are removed, acid is 
no longer being formed, and hydrogen and oxygen gas are formed | 
rapidly. The gas forces the last of the concentrated acid out 
of the plates and in fact, equalizes the acid concentration through- 
out the whole cell, Thus no further changes can take place, and | 
the voltage becomes constant at R. 

Density of Electrolyte. Discharge should be stopped when the 
density of the electrolyte, as measured with a hydrometer, is 
1.150. When we pass a charging current through the battery, 
acid is produced by the chemical actions which take place in the 
plates. This gradually diffuses with the main electrolyte and 
causes the hydrometer to show a higher density than before. This 
increase in density continues steadily until the battery begins to | 
‘‘ovas’’ freely. ‘‘Gassing’’ causes the electrolyte in the plates to 
mix thoroughly with that surrounding the plates and also in- | 
creases the volume of the electrolyte and consequently decreases 
its density. 

The progress of the charge is always determined by the density 
of the electrolyte. For this purpose in automobile batteries, a 
hydrometer is placed in a glass syringe having a short length of 
rubber tubing at one end, and a large rubber bulb at the other. 
The rubber tube is inserted in the cell and enough electrolyte © 
drawn up into the syringe to float the hydrometer so as to be 
able to obtain a reading. This subject will be treated more fully 
in a later chapter. 

Changes at Negative Plate. The charging current changes lead 
sulphate into spongy lead, and acid is formed. The acid is mixed 
with the diluted electrolyte outside of the plates, resulting in a 
rise in temperature. This is not objectionable unless the tem- , 
perature rises to more than 105° F., since the concentrated acid 
formed in the plates diffuses into the electrolyte more rapidly 


THE CHARGE PHENOMENA 39 


as the temperature is increased, thus hastening the charging 
actions. As the charging proceeds the active material shrinks or 
contracts, and the weight of the plate actually decreases on 
account of the difference between the weight and volume of the 
lead sulphate and spongy lead. If the cell has had only a normal 
discharge and the charge is begun soon after the discharge ended, 
the charge will proceed quickly and without an excessive rise in 
temperature. If, however, the cell has been discharged too far, 
or has been in a discharged condition for some time, the lead sul- 
phate will not be in a finely divided state as it should be, but 
will be hard and tough and will have formed an insulating coat- 
ing over the active material, causing the charging voltage to be 
high, and the charge will proceed slowly. When most of the lead 
sulphate has been reduced to spongy lead, the charging current 
will be greater than is needed to carry on the chemical actions, 
and will simply decompose the water into hydrogen and oxygen, 
and the cell ‘‘gasses.’’ Spongy lead is rather tough and coherent, 
and the bubbles of gas which form in the pores of the negative 
plate near the end of the charge force their way to the surface 
without dislodging any of the active material. 

Changes at the Positive Plate. When a cell has been dis- 
charged, a portion of the lead peroxide has been changed to lead 
sulphate, which has lodged in the pores of the paste and on its 
surface. During charge, the lead combines with oxygen from the 
water to form lead peroxide, and acid is formed. This acid dif- 
fuses into the electrolyte as fast as the amount of sulphate will 
permit. If the discharge has been carried so far that a consider- 
able amount of sulphate has formed in the pores and on the sur- 
face of the plate, the action proceeds very slowly, and unless a 
moderate charging current is used, gassing begins before the 
charge is complete, simply because the sulphate cannot absorb 
the current. The gas bubbles which originate in the interior of 
the plate force their way to the surface, and in so doing cause 
numerous fine particles of active material to break off and fall 
to the bottom of the jar. This happens because the lead per- 
oxide is a granular, non-coherent substance, with the particles 
held together very loosely, and the gas breaks off a considerable 
amount of active material. 


CHAPTER 8. 
CAPACITY OF STORAGE BATTERIES. 


The capacity of a storage battery is the amount of electrical 
energy which can be obtained from it. The unit in which capacity 
is measured is the ampere-hour. Theoretically, a battery has a 
capacity of 40 ampere-hours if it furnishes ten amperes for four 
hours, and if it is unable, at the end of that time, to furnish any 
more current. If we drew only five amperes from this battery, 
it should be able to furnish this current for eight hours. Thus, 
theoretically, the capacity of a battery should be the same, no 
matter what current is taken from it. That is, the current in 
amperes, multiplied by the number of hours the battery furnished 
this current should be constant. 

In practice, however, we do not discharge a battery to a lower 
voltage than 1.7 per cell, on account of the increasing amount of 
sulphate and the difficulty with which this is subsequently re- 
moved and changed into lead and lead peroxide. The capacity of 
a storage battery is therefore measured by the number of ampere 
hours it ean furnish before its voltage drops below 1.7 per cell. 
This definition assumes that the discharge is a continuous one, that 
we start with a fully charged battery and discharge it continu- 
ously until its voltage drops to 1.7 per cell. | 

The factors upon which the capacity of storage batteries depend 
may be grouped in two main classifications: 

1. Design and Construction of Battery. 
2. Conditions of Operation. 
Each classification may be subdivided. Under the Design and 
Construction we have: 
(a) Area of plate surface. 
(b) Quantity, arrangement, and porosity of active mate- 
rials. 
40 


CAPACITY OF STORAGE BATTERIES 41 


(c) Quantity and strength of electrolyte. 
(d) Circulation of electrolyte. 

These sub-classifications require further explanation. Taking 
them in order: 

(a) Area of Plate Surface. It is evident that the chemical 
and electrical activity of a battery are greatest at the surface of 
the plates since the acid and active material are in intimate con- 
tact here, and a supply of fresh acid is more readily available to 
replace that which is depleted as the battery is discharged. This 
is especially true with high rates of discharge, such as are caused 
in starting automobile engines. Therefore, the capacity of a 
battery will be greater if the surface area of its plates is increased. 
With large plate areas a greater amount of acid and active mate- 
rials are available, and an increse in capacity results. 

(b) Quantity, Arrangement, and Porosity of Active Materials. 
Since the lead and lead peroxide are changed to lead sulphate 
on discharge, it is evident that the greater the amount of these 
materials, the longer can the discharge continue, and hence the 
greater the capacity. 

The arrangement of the active materials is also important, 
since the acid and pastes must be in contact in order to produce 
electricity. Consequently the capacity will be greater in a battery, 
all of whose active material is in contact with the acid, than in one 
in which the acid reaches only a portion of the active materials. It 
is also important that all parts of the plates carry the same amount 
of current, in order that the pastes may be used evenly. As a 
result of these considerations, we find that the active materials are 
supported on grids of lead, that the plates are made thin, and that 
they have large surface areas. For heavy discharge currents, such 
as starting motor currents, it is essential that there be large sur- 
face areas. Thick plates with smaller surface areas are more suit- 
able for low discharge rates. 

Since the inner portions of the active materials must have a 
plentiful and an easily renewable supply of acid, the active mate- 
rials must be porous in order that diffusion may be easy and rapid. 

(c) Quantity and Strength of Electrolyte. It is important that 
there be enough electrolyte in order that the acid may not become 
exhausted while there is still considerable active material left. 


42 THE AUTOMOBILE STORAGE BATTERY 


An insufficient supply of electrolyte makes it impossible to obtain 
the full capacity from a battery. On the other hand, too much 
electrolyte, due either to filling the battery too full, or to having 
the plates in a jar that holds too much electrolyte, results in an 
increase in capacity. There is a danger present however, because 
with an excess of electrolyte the plates will be discharged before 
the specific gravity of the electrolyte fails to 1.150. This results 
in overdischarge of the battery yith its attendant troubles as will 
be described more fully in a later chapter. 

It ig a universal custom to consider a battery discharged when 
the specific gravity of the electrolyte has dropped to 1.150, and 
that it is fully charged when the specific gravity of the electro- 
lyte has risen to 1.300. The condition of the plates is, however, 
the true indicator of charged or discharged condition. With 
the correct amount of electrolyte, its specific gravity is 1.150 
when the plates have been discharged as far as it is considered 
safe, and is 1.300 when the plates are fully charged. When 
electrolyte is therefore poured into a battery, it is essential that 
it contains the proper proportion of acid and water in order 
that its specific gravity readings be a true indicator of the 
condition of the plates as to charge or discharge, and hence show 
accurately how much energy remains in the eell at any time. 


A question which may be considered at this point is why in 
automobile work a specific gravity of 1.300 is adopted for the 
electrolyte of a fully charged cell. There are several reasons. 
The voltage of a battery increases as the specific gravity goes up. 
Hence, with a higher density, a higher voltage can be obtained. 
If the density were increased beyond this point, the acid would 
attack the lead grids and the separators, and considerable corro- 
sion would result. Another danger of high density is that of 
sulphation, as explained in a later chapter. Another factor which 
enters is the resistance of the electrolyte. It is desirable that 
this be as low as possible. If we should make resistance measure- 
ments on various mixtures of acid and water, we should find that 
with a small percentage of acid, the resistance is high. As the 
amount of acid is increased, the resistance will grow less up to 
a certain point. Beyond this point, the resistance will increase 
again aS more acid is added to the mixture. The resistance is 


CAPACITY OF STORAGE BATTERIES 43 


lowest when the acid forms 30% of the total weight of the electro- 
lyte. Thus, if the electrolyte is made too strong, the plates and 
also the separators will be attached by the acid, and the resistance 
of the electrolyte will also increase. The voltage increases as the 
proportion of acid is increased, but the other factors limit the 
concentration. If the electrolyte is diluted, its resistance rises, 
voltage drops, and the amount of acid is insufficient to give much 
eapacity. The density of 1.300 i therefore a compromise between 
the various factors mentioned above. 7 

(d) Circulation of Electrolyte. This refers to the passing o 
electrolyte from one plate to another, and depends upon the ease 
with which the acid can pass through the pores of the separators. 
A porous separator allows more energy to be drawn from the 
battery than a non-porous one. 

Considering now the operating conditions, we find several items 
to be taken into account. The most important are 

(e) Rate of discharge. 
(f) Temperature. : 

(e) Rate of Discharge. As mentioned above, the ampere hour 
rating of a battery is based upon a continuous discharge, starting 
with a specific gravity of 1.300, and finishing with 1.150. The 
end of the discharge is also considered to be reached when the 
voltage per cell has dropped to 1.7. With moderate rates of 
discharge the acid is abstracted slowly enough to permit the 
acid from outside the plates to diffuse into the pores of the 
plates and keep up the supply needed for the chemical actions. 
With increased rates of discharge the supply of acid is used up 
so rapidly that the diffusion is not fast enough to hold up the 
voltage. This fact is shown clearly by tests made to determine 
the time required to discharge a 100 Amp. Hr., 6 volt battery 
to 4.5 volts. With a discharge rate of 25 amperes, it required 160 
minutes. With a discharge rate of 75 amperes, it required 34 
minutes. From this we see that making the discharge rate 
three times as great caused the battery to be discharged in one 
fifth the time. These discharges were continuous, however, and 
if the battery were allowed to rest, the voltage would soon rise 
sufficiently, to burn the lamps for a number of hours. 

The conditions of operation in automobile work are usually 


44 THE AUTOMOBILE STORAGE BATTERY 


considered severe. In starting the engine, a heavy current is 
drawn from the battery for a few seconds. The generator starts 
charging the battery immediately afterward, and the starting 
energy is soon replaced. As long as the engine runs, there is no 
load on the battery, as the generator will furnish the. current 
for the lamps, and also send a slight charge into the battery. 
If the lamps are not used, the entire generator output is utilized 
to charge the battery, unless some current is furnished to the 
ignition system. Overcharge is quite possible. 

When the engine is not running, the lamps are the only load 
on the battery, and there is no charging current. Various drivers 
have various driving conditions. Some use their starter fre- 
quently, and make only short runs. Their batteries run down. 
Other men use the starter very seldom, and take long tours. 
Their batteries will be overcharged. The best thing that can 
be done is to set the generator for an output that will keep the 
battery charged under average conditions. 

From the results of actual tests, it may be said that modern 
lead-acid batteries are not injured in any way by the high dis- 
charge rate used when a starting motor cranks the engine. It is 
the rapidity with which fresh acid takes the place of that used 
in the pores of the active materials that affects the capacity of a 
battery at high rates, and not any limitation in the plates them- 
selves. Low rates of discharge should, in fact, be avoided more 
than the high rates. Battery capacity is affected by discharge 
rates, only when the discharge is continuous, and the reduction in 
capacity caused by the high rates of continuous discharge does not 
oceur if the discharge is an intermittent one, such as is actually 
the case in automobile work. The tendency now is to design bat- 
teries to give their rated capacity in very short discharge periods. 
If conditions should demand it, these batteries would be sold to 
give their rated capacity while operating intermittently at a 
rate which would completely discharge them in three or four 
minutes. The only change necessary for such high rates of dis- 
eharge is to provide extra heavy terminals to carry the heavy 
current. 

The Society of Automotive Engineers, in January, 1914, adopted 


—/ 


CAPACITY OF STORAGE BATTERIES. 45 


a standard method of rating, starting and lighting batteries, as 
follows: | 

‘‘Batteries for combined lighting and starting service shall 
have two ratings, of which the first shall indicate the lighting 
ability, and the capacity in ampere hours of the battery when 
discharged continuously at a 5 ampere rate to a final voltage 
of 1.8 per cell, the temperature of the battery beginning such 
discharge being 80°F. The second rating shall indicate starting 
ability and shall be the rate in amperes at which the battery 
will discharge for twenty minutes continuously to a final voltage 
‘of not less than 1.65 per cell. The temperature of the battery 
beginning such discharge to be 80°F.”’ 

The discharge rate required under the average starting con- 
ditions is higher than that specified above, and would cause the 
required drop in voltage in about fifteen minutes. In winter, 
when an engine is cold and stiff, the work required from the bat- 
tery is even more severe, the discharge rate being equivalent in 
amperes to probably four or five times the ampere-rating of 
the battery. On account of the rapid recovery of a battery after 
a discharge at a very high rate, it seems advisable to allow a bat- 
tery to discharge to a voltage of 1.0 per cell when cranking an 
engine which is extremely cold and stiff. 

(f) Temperature. Chemical reactions take place much more 
readily at high temperatures than at low. Furthermore, the 
active materials are more porous, the electrolyte lighter, and 
the internal resistance less at higher temperatures. Opposed to 
this is the fact that at high temperatures, the acid attacks the 
grids and pastes, and lead sulphate is formed, even though no 
current is taken from the battery. Other injurious effects are 
the destructive actions of hot acid on the wooden separators used 
in most starting and lighting batteries. Greater expansion of 
paste will also occur, and this expansion is not, in general, uni- 
form over the surface of the plates. This results in unequal 
strains and the plates are bent out of shape, or ‘‘buckled.’’ The 
expansion of the paste will also cause much of it to fall from 
the plates, and we then have ‘‘shedding.’’ 

When sulphurie acid is poured into water, a marked tempera- 
ture rise takes place. When a battery is charged, acid is formed. 


46 THE AUTOMOBILE STORAGE BATTERY 


and when this mixes with the diluted electrolyte, a temperature 
rise occurs. In discharging, acid is taken from the electrolyte, 
and the temperature drops. On charging, therefore, there is 
danger of overheating, while on discharge, excessive tempera- 
tures are not likely. Fig. 15 shows the temperature changes on 
charge and discharge. 

Another factor which should be considered in connection with 
capacity is the age of the battery. New batteries will seldom 


Pi TT INT TTT 


- 1.0 


g 


Vit tt tt tty 


van 
KEE EA 
NERD e 


CELL TEMP ABOVE ROOM TEMP (DEG.CENT) 


ENR, 


my 


O 
N 
W 
ul 


give their rated capacity when received from the manufacturer. 
This is due to the methods of making the plates. The ‘‘paste’” 
plates, such as are used in automobiles, are made by applying 
oxides of lead, mixed with sulphuric acid, to the grids. These 
oxides must be subjected to a charging current in order to pro- 
duce the spongy lead and lead peroxide. After the charge, they 
must be discharged, and then again charged. This is necessary 
because not all of the oxides are changed to active material on 
one charge, and repeated charges and discharges are required 


CAPACITY OF STORAGE BATTERIES AT 


to produce the maximum amount of active materials. Manu- 
facturers do not charge and discharge a battery a sufficient num- 
ber of times before sending it out, and after a battery is put 
into use, its capacity will increase for some time, because more 
active material is produced during each charge. 

When a battery has been in use for some time, a considerable 
portion of the paste will have fallen from the positive plates, and 
a decrease in capacity will result. Such a battery will charge 
faster than a new one because the amount of sulphate which 
has formed when the battery is discharged is less than in a newer 
battery. - Hence, the time required to reduce this sulphate will 
be less, and the battery will ‘‘come up’’ faster on charge. 


CHAPTER 9. 


INTERNAL RESISTANCE, 


The resistance offered by a storage battery to the flow of a 
current through it results in a loss of voltage, and in heating. 
Its value should be as low as possible, and, in fact, it is almost 
negligible even in small batteries, seldom rising above 0.05 ohm. 
On charge, it causes the charging voltage to be higher and on 


discharge causes a loss of voltage. 
tion in resistance. 


Figure 16 shows the varia- 


7 TT 
yf TTT an 

6 See on 
728 GRR an 
eee eee an 
oe ee 
‘2 CR 
see 
eT INTE ELE reer 
7 Nee see 
2 COON 
Mo +t | | Soe | TTT PT TT 
tet 
PPP Pere ann am 
ost LETT TTT aan aan 
° ' ? id HOURS . . 7 _ @ 

Fig. 16 


The resistance aS measured between the terminals of a cell 


is made up of several factors as follows: 

1. Grids. This includes the resistance of the terminals, con- 
necting links, and the framework upon which the active materials 
are pasted. This is but a small part of the total resistance, and 
does not undergo any considerable change during charge and 
discharge. It increases slightly as its temperature goes up. 


48 


INTERNAL RESISTANCE 49 


2. Electrolyte. This refers to the electrolyte between the 
plates, and varies with the amount of acid and with tempera- 
ture. As mentioned in the preceding chapter, a mixture of acid 
and water in which the acid composes thirty per cent of the 
total weight of electrolyte has the minimum resistance. Diluting 
or increasing the concentration of the electrolyte will both cause 
an increase in resistance from the minimum value. The expla- 
nation probably lies in the degree to which the acid is split up 
into ‘‘ions’’ of hydrogen (H), and sulphate (SO,). These ‘‘ions’’ 
earry the current through the electrolyte. Starting with a cer- 
tain amount of acid, let us see how the ionization progresses. 
With very concentrated acid, ionization does not take place, and 
hence, there are no ions to carry current. As we mix the acid 
with water, ionization occurs. The more water used, the more 
ions, and hence, the less the resistance, because the number of 
ions available to carry the current increases. The ionization in- 
creases to a certain maximum degree, beyond which no more ions 
are formed. It is probable that an electrolyte containing thirty 
per cent of acid by weight is at’: its maximum degree of ioniza- 
tion and hence its lowest resistance. If more water is now added, 
no more ions are formed. Furthermore, the number of ions per 
unit volume of electrolyte will now decrease on acccunt of the 
increased amount of water. There will therefore be fewer ions 
per unit volume to carry the current, and the resistance of the 
electrolyte increases. 

With an electrolyte of a given concentration, an increase of 
temperature will cause a decrease in resistance. A decrease in 
temperature will, of course, cause an increase in resistance. It 
is true, in general, that the resistance of the electrolyte is about 
half of the total resistance of the cell. The losses due to this re- 
sistance generally form only one per cent of the total losses, and 
are a practically negligible factor. 

3. Active Material. This includes the resistance of the pastes 
and the electrolyte in the pores of the active materials. This varies 
considerably during charge and discharge. It has been found that 
the resistance of the peroxide plate changes much more than that of 
the lead plate. The change in resistance of the positive plate is 
especially marked near the end of a discharge. The composi- 


20 THE AUTOMOBILE STORAGE BATTERY 


tion of the attive material, and the contact between it and the 
grid affect the resistance considerably. 

During charge, the current is sent into the cell from an external 
source. The grids therefore carry most of the current. The 
active material which first reacts with the acid is that near the 


surface of the plate, and the acid formed by the charging current | 


mixes readily with the main body of electrolyte. Gradually, the 
eharging action takes place in the inner portions of the plate, 
and concentrated acid is formed in the pores of the plate. As 
the sulphate is removed, however, the acid has little difficulty 
in mixing with the main body of electrolyte. The change in 
resistance on the charge is therefore not considerable. 

During discharge, the chemical action also begins at the sur- 
face of the plates and gradually moves inward. In this ease, 
however, sulphate is formed on the surface first, and it becomes 
increasingly difficult for the fresh acid from the electrolyte to 
diffuse into the plates so as to replace the acid which has been 


greatly diluted there by the discharge actions. There is therefore | 


an increase in resistance because of the dilution of the acid at the 
point of activity. Unless a cell is discharged too far, however, 
the increase in resistance is small. 

If a battery is allowed to stand idle for a long time it grad- 
ually discharges itself, as explained in a previous chapter. This 
is due to the formation of a tough coating of crystallized lead 
sulphate, which is practically an insulator. These crystals gradu- 
ally cover and incapsulate the active material. The percentage 
change is not high, and generally, amounts to a few per cent 
only. The chief damage caused by the excessive sulphation is 


therefore not an increase in resistance, but consists chiefly of mak- | 


ing a poor contact between active material and grid, and of re- 
moving much of the paste from action by covering it. 


CHAPTER 10. 
BATTERY DISEASES. 


Storage batteries have their own peculiar troubles which pro- 
duce injuries that are not always curable. The chief troubles 
met with are as follows: 

1. Sulphation. 

2. Loss of capacity. 

3. Buckling of plates in battery. 

4. Hardening of negative plates when exposed to air. 

5. Buckling of positive plates when exposed: to light. 

6. Internal discharge. | 

These troubles are not entirely independent of one another, 
since the causes of one of them may include some of the ethers. 

1. Sulphation: Many battery men say a battery is sulphated 
whenever anything is wrong with it. Sulphation is the forma- 
tion of lead sulphate on the plates. As a battery discharges, it 
is entirely natural and normal for lead sulphate to form. When 
the voltage of a battery has dropped to about 1.7 per cell, there is 
still a considerable portion of active material left, but much of it 
is covered by sulphate and thus made useless. A normal charge 
will change this sulphate to active material. If the discharge is 
continued after the voltage has dropped to 1.7 per cell, so much 
sulphate has been formed that it is difficult to change it to active 
material. Moreover, the expansion of the paste which takes 
place when lead sulphate is formed may be so great that it 
causes the paste to break off from the plate and fall to the bot- 
tom of the jar. 

If a battery is charged and discharged intermittently, and the 
discharge is greater than the charge, the battery may never be 
fully charged, and there will always be sulphate present. If a 
battery which has been discharged is allowed to stand idle for 
several months, the sulphate which was formed during the dis- 

51 


D2 THE AUTOMOBILE STORAGE BATTERY 


charge changes. Instead of being finely divided, it now forms 
crystals which grow by the addition of sulphate from other parts 
of the plates. These crystals can be reduced to active material 
only with the greatest difficulty, and often it is impossible to 
do so. 

Another factor which aids in the ‘‘sulphation,’’ is the self- 
discharge caused by impurities. These cause local actions which 
partly discharge the battery and add their quotas of sulphate. A 
completely charged battery can, in an emergency, be left idle for 
six months without causing an excessive amount of sulphate to 
form and crystallize. 

Usually, most of the sulphate is formed by the chemical actions 
which produce the electrical energy. Useless chemical action 
occurs however between paste and electrolyte which result in the 
formation of lead sulphate even though no current is taken from 
the battery. Thus a certain amount of sulphate forms on the sur- 
face of the spongy lead and between the lead peroxide and the 
positive grids. Since these are entirely normal actions, they can 
hardly be classified as diseases. If there is too much acid in the 
electrolyte, or its temperature is allowed to become too high, an 
abnormal amount of sulphate is formed, because hot concentrated 
acid is more active chemically than the normal electrolyte. 

Over-sulphation is often caused by the loosening of the active 
material and consequent short circuit between the plates. Sulpha- 
tion from any cause may result in shedding, buckling, loss of ca- | 
pacity, loss of efficiency and an increased temperature while 
charging and discharging. The voltage of a sulphated battery | 
will be below normal on discharge and above normal on charge. 

If the electrolyte is allowed to fall below the tops of the plates, 
so that the pastes are exposed to the air, the parts thus exposed 
will gradually sulphate, especially on the negative plates. Some , 
of the sulphate is formed because the current heats up those parts 
of the grids which are not covered by acid. This heats the pastes 
and any acid in them. The sulphate which has been formed by 
normal discharge will be dissolved on account of the heat, and 
will then form in erystals as the heat dries up the acid. This will 
take place on both positive and negative plates. After sulphate 
has been formed in this way, no more is formed on the positive 


BATTERY DISEASES : D3 


plate. On the negative plate, however, the sulphate continues to 
form. This is explained as follows: 

The negative paste is spongy lead, which is in an unstable chem- 
ical condition. The dry spaces between the plates and above the 
surface of the electrolyte contain definite amounts of sulphur di- 
oxide (SO,), and sulphur trioxide (SO,), liberated during the 
chemical reactions of the cell. These unite with the spongy lead 
to form lead sulphate. The spongy lead first absorbs oxygen 
from the air and becomes oxidized, then combines with the dioxide 
and trioxide to form lead sulphate. Gradually the entire nega- 
tive active material becomes sulphated in this way. The lead 
peroxide does not sulphate when dry because it is in a stable con- 
dition. | 

Lead sulphate does not form uniformly over the surfaces of 
the plates as a battery discharges. At the beginning of a discharge 
it is supposed that the lead sulphate forms chemical compounds. 
The reason for this belief is that a peroxide plate grows darker at 
first instead of lighter as we should expect, since lead sulphate is 
white, and a mixture of lead peroxide and lead sulphate should be 
lighter than the peroxide alone. After a time, however, patches 
of the white sulphate appear on the plate surfaces. If only a nor- 
mal discharge is given, it is not difficult to change this sulphate to 
active material. If the sulphate is allowed to erystallize, how- 
ever, it is a very difficult matter. The crystallized sulphate is 
tcugh, and is a good: insulator. Such a plate must be charged at 
a low rate, because so much of the active material is covered with 
the sulphate that the current cannot reach it. Only a small portion 
of the active material is uncovered and hence in contact with the 
acid. These parts must carry all the charging current, and if this 
current is not low, the small patches of active material which must 
earry the current become very hot, resulting in serious injury to 
them. Furthermore, if a large charging current is used, the water 
of the electrolyte is split into hydrogen and oxygen, and gassing 
results. This causes chips of the sulphate to break off and fall to 
the bottom of the cell, and thus be removed from action. 

Another danger from large charging currents in sulphated 
plates is that the parts carrying the current will become hotter 


o4 THE AUTOMOBILE STORAGE BATTERY 


than other parts. This results in an unequal expansion of paste 
and grids, and the plate may be warped and bent out of shape. 

We see, therefore, that the presence of lead sulphate is objec- 
tionable only when an excessive amount is formed, or when it be- 
comes crystallized. A small amount of sulphate in the positive 
plate is desirable, in fact. Lead peroxide does not hold together 
well, but a small amount of sulphate acts as a cement and 
binds the particles of the paste together. At the surface of 
the plate, the sulphate is almost completely removed on charge, 
and some of the peroxide loses its hold on the plate and falls to | 
the bottom of the cell. This is called ‘‘shedding’’ of the 
active material. A battery which is kept slightly undercharged 
will have a longer life than one which is continually over- 
charged. 

The best remedy for a sulphated battery is to pass a charge 
of low amperage through the cells for a long time. The charge 
rate should not be much above 1/25 of the capacity of the bat- 
tery in ampere-hours and should be continued until the specific 
gravity has risen to its normal value of 1.280-1.300 and has re- 
mained eonstant for three or four hours. At this time all of the 
cells should be gassing rather freely. The length of time required 
may be from one day to one week of continuous charging or a 
succession of charges of equivalent time. 

2. Loss of Capacity. This subject may be again subdivided, 
as quite a number of factors must be considered. Some of them 
are given under the main headings at the beginning of this chap- 
ter. They are as follows: | 

(a) Impurities in Electrolyte. These result in local action 
and self-discharge. They can sometimes be removed by giving 
the battery a complete charge, discarding the electrolyte, and 
putting in new electrolyte of the proper specific gravity to bring 
it to 1.280-1.300 when fully charged. 

(b) Low Gravity of Electrolyte. Low gravity may result 
from lack of charge, replacing spilled electrolyte or electrolyte 
which has leaked out through a cracked jar, with water. This 
condition may be remedied by charging until the cells are gassing 
freely and no further increase in specific gravity occurs, and 
then removing some of the electrolyte and adding electrolyte of 


BATTERY DISEASES ay) 


1.400 gravity. Then give battery a full charge. It may be 
necessary to empty out the old electrolyte and put in new electro- 
lyte. If the maximum specific gravity of the old electrolyte 
was 1.200, use 1.400 electrolyte, and if the old electrolyte has a 
different strength, vary the specific gravity of the new accord- 
ingly. ; 

(ce) High Gravity of Electrolyte. This is caused by incorrect 
mixtures of acid and water in preparing electrolyte, and by 
adding raw acid or electrolyte in making up for loss of elec- 

trolyte by evaporation. It results in sulphation, burned separa- 
tors, or corroded plates, all of which cause a loss of capacity. 

(d) Sulphation. This has already been explained. 

(e) Pores of Separators Filled With Impurities or Active Ma- 
terial From Bulged Plates. This prevents circulation of electro- 
lyte, which hinders chemical action and thus reduces capacity. 
Generally, a battery in this condition has been neglected or 
abused. The plates will probably be found to be in need of re- 
pairs, a subject which will be discussed more fully later. 

(f) Bulged Active Material on Negative Plates, Causing Poor 
Contact Between Paste and Grid. If the lead does not have a 
granular appearance, or if active material has not been shed 
to any considerable extent, pressing the plates in a vise or press 
(see page 215) will remedy the trouble. When the bulged paste 
has been pressed back into the grids, it will be necessary to charge 
and discharge the battery several times in order to put the spongy 
lead in an active condition. 

(¢g) lack of Sufficient Charging and Discharging of New 
Batteries, Batteries Which Have Been Sulphated, and Rebuilt, 
Batteries With New Plates. This can be remedied generally by 
eharging and discharging two or three times, and adjusting 
electrolyte so as to have proper specific gravity by removing 
some of old electrolyte and adding water or 1.400 electrolyte, as 
the case may be. 

If in doubt as to the battery’s condition, charge it until it 
gasses freely, and the specific gravity of the electrolyte does not 
inerease over several hours. Now discharge the battery at one 
fourth to one fifth of its ampere hour capacity. If, when the 
battery voltage has dropped to 1.7 per cell, the battery has de- 


06 THE AUTOMOBILE STORAGE BATTERY 


livered fifty to sixty per cent of its ampere hour capacity, based 


on its eight hour rate, the battery should give reasonable service. 


If convenient, make the cadmium test (see page 266). If this 
test shows that the plates of any cell are in a poor condition, 


the battery must be opened and the trouble found and repaired | 


(see page 187). 

(h) Corroded Grids. Caused by nonuniform mixture in 
alloy of which grids are made, by the chemical action resulting 
from electrolytic decomposition of highly dilute acid in the pores 


of the active material, and by the presence of lead dissolving acids | 


or their compounds in the electrolyte. The first condition is hope- 
less. The second is also, as it occurs in every cell if the dis- 
charge is carried too far, or if the plates have a thick layer of 
active material when the rate of discharge is high. If the elec- 
trolyte contains impurities which attack the lead, the remedy is 
to pour out the old electrolyte, and put in fresh, which is known 
to be chemically pure. 

Corrosion is also the natural result of the action of the acid on 
the plates, and is the natural depreciation occurring in the 
plates. This can be retarded by keeping the specific gravity of 
the electrolyte slightly below that for full charge. This corro- 
sion tends to take place most rapidly at the surface of the elec- 
trolyte, and the damage at this point can be lessened by keep- 
ing the plates covered with electrolyte, and making the terminal 
bars and lugs extra large in cross section. 

(i) Reversal of Negative Plates. If one cell of a battery has 
an internal short circuit, or some other defect which causes it to 
lose its charge, the cell will be discharged before the others which 
are in series with it, and when this cell is completely discharged, 
the other cells will send a current through it in a discharge direc- 
tion, and the negative plates will have a coating of lead perox- 
ide formed on them, and will assume the characteristics of posi- 
tive plates. 

This reversal may also be the result of charging a battery in the 
wrong direction, on account of reversed charging connections. 
The remedy is to charge the battery for a long time in the proper 
direction. If the reversal was caused by some defect within the 
cell itself, the cause of the defect should be found and removed. 


BATTERY DISEASES o7 


Such defects may be internal short circuit, local action caused by 
impurities, loss of active material, sulphation, ete. 

(j) Loss of Active Material, or Shedding. This is a natural 
action for positive plates, since the lead peroxide is not coherent, 
and as it expands, on discharge, outer layers are forced off, and 
fall to the bottom of the jar. Internal short circuits, sulpha- 
tion, or buckling of the grids will also cause shedding. The posi- 
tive plate becomes extremely thin and gradually wears out, or 
ages. Excessive charging rates resulting in violent evolution of 
gas. This loosens some of the active material and causes it to 
drop to the bottom of the jar. Normal charging rates will cause 
shedding in sulphated plates because gassing will take place due 
to the fact that the plates do not have enough active material 
exposed to the current to use all the current in producing chem- 
ical action. A current which is normal for a battery in good 
condition is therefore excessive for a sulphated battery. 

Should the active material be loosened from the grids and fall 
to the bottom of the cell in large quantities, it will not only result 
in short circuiting the plates but will also result in a loss of 
capacity because of the decreased volume of material remaining 
in the grids. Shedding is usually the result of overcharge or 
buckling. It is also caused by the addition of raw acid or electro- 
lyte in place of water. The remedy is to have the plates repasted 
in a battery repair depot that is equipped for such work. A 
certain amount of space is left between the bottom of the plates 
and the bottom of the cells to care for this sediment but if the 
collection is allowed to grow until it touches the plates, short 
circuiting will result. The remedy is to have the plates removed 
and the cells cleaned at intervals of nine months to one year. 

(k) Negative Plates Granulated. The spongy lead tends to 
become granulated and dense in structure, and to lose its porosity 
so that it resembles ordinary lead. This is a natural and un- 
avoidable condition, and is simply. the natural ageing of the 
spongy lead. 

The remedy for ths condition is to discharge the battery, re- 
move the negative plates, place them in a bath of electrolyte of 
1.200 specific gravity sulphuric acid, in which sheets of ordinary 
lead, 1/16 inch thick are also placed. Current is sent through 


58 THE AUTOMOBILE STORAGE BATTERY 


the combination, entering at the negative plates and leaving at 
the “‘dummy’’ electrodes of ordinary lead. The spongy lead 
first turns into lead monoxide (PBO), and then lead peroxide 
(PBO,). When all the spongy lead has been changed to lead 
peroxide, the current is reversed. Befcre reversing the current, 
however, the electrolyte is poured out and new electrolyte used, 
in order that any impurities in the old electrolyte may not be 
redeposited on the negative plates. The lead peroxide now 
changes back to spongy lead, and when the plates are replaced 
and the battery reassembled, it will be found to have regained the 
capacity which was lost by the ageing of the spongy lead. 

(1) Improperly constructed battery, or one which has been 
poorly designed. Inferior materials and poor workmanship 
result in a battery of low capacity. 

3. Buckling. This is the bending or twisting of plates, and is 
caused by unequal expanson of the various parts of the active 
material. Buckled plates are saucer shaped, the center portions 
expanding more than the edges on account of being less firmly 
braced and supported. Any conditions of operation which will 
cause excessive or non-uniform expansion of active material will 
result in buckling. These conditions are as follows: 

(a) Overdischarge. If discharge is carried too far, the expan- 
sion of the active material on account of the formation of lead 
sulphate will bend the grids out of shape, and may even break 
them. 

(b) Continued Operation With Battery In a Discharged Con- 
dition. When a considerable amount of lead sulphate has formed, 
and current is still drawn from the battery, those portions of 
the plate which have the least amount of sulphate will carry all 
the current, and will therefore become heated and expand. The 
parts covered with sulphate will not expand, and the result is 


that the parts that do expand will twist the plate out of shape. . 


A normal rate of discharge may be sufficient to cause buckling 
in a sulphated. plate. 
(c) Charging at High Rates. If the charging rate is exces- 


oe a va a ve eT 


sive, the temperature will rise so high that excessive expansion 


will take place. This is usually unequal in the different parts of 
the plate, and buckling results. With a battery that has been 


BATTERY DISEASES 59 


over-discharged, the charging current will be carried by those 
parts of the plates which are the least sulphated. These parts 
will therefore expand while others will not, and buckling results. 

(d) Non-Uniform Distribution of Current Over the Plates. In 
a battery which has not been over-discharged, buckling may 
result if the current carried by the various parts of the plate is 
not uniform on account of faulty design, or careless application 
of the paste. This is a fault of the manufacturers, and not the 
operating conditions. 

(e) Defective Grid Alloy. If the metals of which the grids 
are composed are not uniformly mixed throughout the plate, areas 
of pure lead may be left here and there, with air holes at various 
points. The electrolyte enters these air holes, attacks the lead 
and converts the grid partly into active materail. This causes 
expansion and consequent distortion and buckling. 

Buckling will not necessarily cause trouble, and batteries with 
buckled plates may operate satisfactorily for a long time. If, 
however, the expansion and twisting has caused much of the 
active material to break away from the grid, or has loosened 
the active material from the grids, much of the battery capacity 
is lost. Another danger is that the lower edges of a plate may 
press against the separator with sufficient force to cut through it, 
touch the next plate, and cause a short-circuit, and the battery 
fails. | 

If buckling is caused by defective plates, there is no remedy 
except to avoid discharging the plate very far, and protect the 
battery from the effects of light and heat. If over-discharge, 
or other conditions not resulting from defective plates have 
caused buckling, and if the active material has not been loosened 
from the grids, or has not dropped to the bottom of the cell, 
it is possible to remove the separators, put in boards having 
same thickness as the separators, and then slowly and carefully 
compress the plates in a vise until restored to shape. If the 
buckling has been so excessive that parts of the grids have 
broken, much paste has been lost, or a short circuit has resulted, 
the only remedy is to install new plates. 

4. Hardening of Negatives. When negative plates are exposed 
to air, the spongy lead, instead of being soft and finely divided, 


60 THE AUTOMOBILE STORAGE BATTERY 


erystallizes and oxidizes, and becomes hard. This causes the 
paste to become heated. The acid which remains in the plate 
will also heat, and attack the spongy lead. Negative plates 
should therefore always be immersed in water or weak electrolyte 
when removed from a battery. 

5. Buckling of Positive Plates When Exposed to Light. A phe- 
nomenon for which no explanation has been found is that positive 
plates buckle when exposed to light, the side toward the light 
becoming concave. The positive plates should therefore be kept 
in a dark box or cupboard when removed from the battery. 

6. Internal Discharge. This shows itself by the gradual los: 
of charge when a fully or partly charged battery is allowed to 
stand idle. The causes are: 

(a) Formation of layer of sulphate between the lead peroxide 
and the grid. : 

(b) Formation of a layer of sulphate on the surface of the 
negative plate. 

(ec) Impurities in plates which form small cells with the active 
materials and by their discharge take away some of the battery 
capacity. 

These points have already been explained. See page 26. 


‘CHAPTER 11. 
CONDITIONS OF OPERATION. 


The starting and lighting equipment of a gasoline automobile 
consists of three principal parts. 

1. The Battery. 

2. The Starting Motor. 

3. The Dynamo or Generator. 

The normal course of operation of this system consists of 

(a) Cranking the Engine With the Starting Motor. A switch 
is operated whereby the battery is connected to the starting 
motor, causing the latter to put the engine in motion. As soon 
as the gasoline has begun to vaporize, and is mixed with the 
correct amount of air, the sparks at the spark plugs ignite the 
mixtures of air and gasoline which are drawn into the engine 
cylinders. The engine then operates under its own power. The 
starting switch is then opened, disconnecting the motor from 
the battery. As long as the engine now continues to run under 
its own power, the starting motor is not used. | 

(b) Charging the Battery. The current taken by the start- 
ing motor is a heavy one, and discharges the battery to a con- 
siderable extent. The energy taken out must therefore be re- 
placed. This is done by the dynamo. It is important, however, 
that the dynamo should not be connected to the battery until 
the engine is operating above a certain minimum speed. This 
is necessary because a dynamo must develop a voltage which is 
greater than that of the battery before it can send a current 
through the battery so as to charge it. In order to develop this 
voltage, the speed of the dynamo must reach a certain value. 
Should the dynamo be connected to the battery at a lower speed, 
its voltage would be less than that of the battery, and instead 
of the dynamo sending a current through the battery, the battery 

61 


62 THE AUTOMOBILE STORAGE BATTERY 


will send a current through the dynamo, and thus lose more 
energy. 

In most cars, the switch which connects the dynamo to the 
battery operates automatically, and does not operate until the 
voltage of the dynamo is slightly greater than that of the bat- 
tery. It is known as the ‘‘circuit breaker,’’ ‘‘cutout relay,’’ or 
simply the ‘‘cutout.’’ When the speed of the engine decreases, 
the voltage developed by the dynamo also decreases, and it 
becomes necessary to disconnect the dynamo from the battery 
when the dynamo voltage begins to drop below that of the 


battery. This is also done by the eutout. The construction | 


cutouts will be explained more fully later. Some cars have no 


automatic cutout, but use a hand operated switch. Others have | 


both the automatic and the hand operated switches. 


(c) Furnishing Current to the Lamps. When the engine is 


not running, the battery is the only source of electricity on the 


car, and therefore operates the lights. When the engine is in | 
operation, and the dynamo is sending a current through the — 
battery, or is ‘‘charging’’ it, the dynamo also supplies the cur- | 


rent to operate the lamps. 


These conditions of operation seem to be simple enough, and © 


as long as all parts work as they should, no difficulties are en- 
eountered. In order to obtain satisfactory service, however, 4 
number of things must be considered. 


Normal Conditions of Operation, Engine Idle. 


When the engine is idle and the lamps and all other electrical 
equipment on the automobile are entirely disconnected from the 
battery by means of their controlling switches, there should be 
no current delivered by the battery. When there is no current 
delivered by the battery under the above ‘conditions, it indicates 
that there are no shorts or grounds connecting the positive and 
negative terminals of the battery or between the battery and 
the terminals of the various switches. It also indicates that the 
eutout, whether it be mechanical, electro-magnetic or manual, 
is open and no current is being deliverd by the battery to the 
dynamo armature. When the battery shows a discharge with 


CONDITIONS OF OPERATION 63 


all the various controlling switches open, it may be due to 
grounds, short circuits or improper operation of the cutout. An 
inspection of the cutout will soon tell whether it is closed or 
not, and thus eliminate this possible cause of trouble, which 
reduces the difficulty to a short circuit or ground. A thorough 
inspection of the circuit will be necessary in order to determine 
the exact location of this kind of trouble. 


It is not advisable to equip an automobile with lamps whose 
candlepower exceeds that recommended by the manufacturer of 
the car or equipment maker. If the current delivered by the 
battery with the lamps turned on exceeds the normal value for 
that particular car, it may be due to lamps 8f higher candle- 
power having been substituted for the standard equipment, or 
shorts and grounds. A short or ground may also be thrown onto 
the battery circuit when the switches controlling special elec- 
trical equipment, such as electric gear shifts, horns, trouble 
lamps, ete., are closed. It is always advisable to test each of 
these different circuits separately in order to make sure that 
they are free from shorts and grounds and not drawing an 
excessive current from the battery when in operation. 


Normal Conditions of Operation, Engine Running. 


When a manual type of cutout is used the battery and 
dynamo are connected together through a switch whose opera- 
tion is controlled by the driver of the car. These switches are 
of different forms and arrangements, some being combined with 
the ignition switch, some with the starting switch, while some 
may operate to a certain extent independent of either the start- 
ing or ignition switches. With this type of cutout the operation 
of the dynamo and the adjustment of the regulator controlling 
the output of the dynamo should be such that the battery will 
be charging when the engine is running at very low speeds. If 
this adjustment is not made, it is advisable not to run the engine 
at very low speeds at any time with the cutout closed, as the 
voltage of the dynamo will be lower than the voltage of the 
battery and, hence, the battery will discharge back into the 


64 THE AUTOMOBILE STORAGE BATTERY 


dynamo. A condition of this kind may be the cause of a dis- 
charged battery. The car speed at which the battery starts 
to discharge may be determined by connecting an ammeter in 
series with the battery and observing its indication as the speed 
of the engine or car is decreased. The speedometer indication, 
when the ear is running and the ammeter indicating zero current, 
corresponds to what might be called the neutral speed; that is, 
the voltage of the generator and battery are equal and the 
battery is neither charging nor discharging. This neutral speed 
should not be excessive, as a high neutral speed means a rela- 
tively low dynamo voltage, and hence a corresponding decrease 
in output of the dynamo. 

If a mechanical cutout is used its adjustment should be such 
that the circuit connecting the dynamo and battery is not closed 
until the speed of the dynamo is sufficient to cause a generated 
voltage in its armature winding greater than the voltage of the 
battery. If this cutout closes too soon the battery will discharg 
when the circuit is first closed and will continue to do so until 
the speed of the dynamo is ample to cause the generated voltage 
in its armature winding to be equal to or greater than the voltage 
of the battery. This type of cutout may be tested by observing 
the indications of an ammeter connected in series with the bat- 
tery while the speed of the engine is gradually increased. If 
the voltage of the dynamo is less than the voltage of the battery 
when the cutout closes, the ammeter will indicate a discharge 
from the battery. If the voltage of the dynamo happens to be 
equal to the voltage of the battery when the circuit is: closed, 
there will be no indication on the ammeter, but as the speed of 
the engine is increased, the ammeter will show a gradually in- 
ereasing charge. If the voltage of the dynamo exceeds the 
voltage of the battery when the cutout closes, the charging 
current, aS indicated on the ammeter will not gradually rise 
from zero to a maximum value with increase of engine speed, 
but the indication of the ammeter will suddenly jump from zero 
to a certain value when the cutout closes, depending upon how 
much the voltage of the dynamo exceeds the voltage of the 
battery and the resistance of the entire circuit. The indicator 


CONDITIONS OF OPERATION 65 


then gradually increases from this value to a maximum value 
with increase in engine speed. 

The operation of the electromagnetic cutout should be such 
that the dynamo and battery are connected together when the 
voltage of the dynamo is high enough to cause a charging cur- 
rent to pass through the battery when the voltage of the battery 
is at its maximum value or the battery is practically fully 
charged. The value of the charging current at the instant the 
circuit is closed will depend upon the difference between the 
voltage of the dynamo and the voltage of the battery. This 
difference will be greatest when the battery is practically or 
completely discharged and a minimum value when the battery 
is fully charged. The operation of the cutout may be determined 
as described on page 169. 

The charging rate must be sufficiently high so that with all 
lamps turned on and the car running at a speed of about fifteen 
miles per hour, an ammeter connected at the battery will show 
some charge in spite of the current being drawn for lighting 
(lamp load). This does not mean, however, that the charge 
rate with the lamps turned off should always be equal to the 
lamp load, because of the variations in dynamo control. 

The charge rate with the lamps turned off should never 
exceed in amperes one-sixth of the total ampere-hour capacity 
of the battery, and except at extreme high speeds should never 
exceed one-eighth of this capacity. 


General Operating Conditions Which Govern the Action of 
a Battery. 


The greatest drain on the storage battery is the operation of 
the starting motor. Under no conditions should the starting 
motor be used to propel the car, as there will undoubtedly be 
permanent damage done to the battery. Damage due to such 
treatment may not appear for some time, but it is sure to come 
if the practice be followed to any extent. 

The starting motor should be used as economically as possible, 
and the engine started only when it is necessary to do so. Care 
should be exercised in the adjustment of the carburetor and 


66 THE AUTOMOBILE STORAGE BATTERY 


ignition system so that it will not be necessary to erank the 


engine for a considerable period before it will start. A great 
many drivers have a habit of holding their foot on the starting 
switch after the engine starts to fire, which results in an unneces- 
sary discharge of the battery. 


The adjustment of the output of some dynamos is such that | 


the dynamo very seldom reaches its maximum output due to the 
fact that the driver may not ordinarily operate the car at a high 
enough speed, on account of traffic regulations or road con- 
ditions, to enable the dynamo to develop. its maximum voltage. 
In such cases the output of the dynamo should be increased 
when such an adjustment is possible. 


In some cases a car may be used almost entirely at night or | 
at least a large part of the time that it is in use may be at night, | 


and in such cases the drain on the battery may be excessive for 
the amount of charge put into it. The driver should use his 


starting motor as sparingly as possible, substitute lamps of lower | 


candle power for the ones regularly supplied if such substitution 
gives ample light for driving purposes, and be careful in the 
_use of the electric horn and other electrical accessories. In no 
ease should the charging rate be increased to such an extent 
by adjusting the regulator that the dynamo or battery will he 
damaged. 


The efficiency of a storage battery is considerably less in cold | 


weather than it is in warm weather, and this, coupled with the 


fact that the number of hours of darkness during which the car | 


is likely to be used is greater in cold weather than in warm, often 
results in the battery becoming discharged, or failing to carry 
the load imposed upon it during the winter, even though it oper- 
ated very satisfactorily during the warm summer months. The 
engine is always harder to start in cold weather than it is in 
warm weather, due to the fact that the gasoline does not vaporize 
as readily and the oil in all the bearings and around the pistons 
is stiff, making the engines much harder to turn over. In such 
eases it is often necessary to increase the output of the dynamo 
during certain months of the year in order to make up for the 
loss in efficiency and increase in output the battery is called upon 
to supply. 


CONDITIONS OF OPERATION 67 


The condition of operation during the warm summer months 
and long days may on the other hand result in serious damage to 
the battery on account of excessive charging in proportion to 
discharge. During the summer. the engine turns over more easily, 
the battery is much more efficient, the gasoline vaporizes more 
easily, and the lamps are not used nearly as much as they are 
in the winter. This condition of over-charging can be relieved 
to a certain extent by means of a touring switch, by means of 
which the driver may disconnect the battery from the dynamo, 
or by turning on all of the lamps with the engine idle and allowing 
the battery to discharge for a few hours at certain intervals, 
depending upon the speed at which the car is driven when in 
use, that is, upon the amount of charge put into the battery. 


CHAPTER 12. 
HOW TO TAKE CARE OF THE BATTERY ON THE CAR. 


The manufacturers of Starting and Lighting Equipment have 
designed their generators, cutouts, and current controlling devices 
so as to relieve the car owner of as much work as possible in 
taking care of batteries. The generators on most cars are auto- 
matically connected to the battery at the proper time, and also 
disconnected from it as the engine slows down. The amount of 
current which the dynamo delivers to the battery is automatically 
prevented from exceeding a certain maximum value. Under the 
average conditions of driving, a battery is kept in a good con- 
dition. It is impossible, however, to eliminate entirely the need 
of attention on the part of the car owner, and battery repairman. 

The repairman, especially, should know what charging currents 
the various makes and types of generators with which the auto- 
mobiles are equipped should produce. It is a good plan always 
to put an ammeter in series with the battery, run the engine with 
the lamps turned off, and measure the charging current which 
is being delivered to the battery. This should be done on every 
car that is brought in for repairs. The charging current actually 
received by the battery should be checked with the current the 
generator is intended to deliver, and for which the generator 
is adjusted before the car leaves the factory. If the generator 
is not delivering the proper current, find out why, and remedy 
the trouble. Otherwise the battery cannot be expected to do 
its work satisfactorily, and be fully charged. 

The storage battery requires but little attention, and this is 
the very reason why many batteries are neglected. Motorists 
often have the impression that because their work in caring for 
a battery is quite simple, no harm will result if they give the 
battery no attention whatever. If the battery fails to turn over 
the engine when the starting switch is closed, then instruction 

68 


HOW TO TAKE CARE OF BATTERY ON CAR 69 


books are studied. Thereafter the motorists pay more attention 
to the battery. The rules to be observed in caring for a battery 
on a car are given in the remainder of this chapter. Some of them 
apply to car owners tlone, while the others are intended for 
garagemen. 


Preparing Battery for Use. 


1. Unpacking. If the battery arrived packed, unpack it care- 
fully, being careful to keep it right side up. Brush off all dirt, 
excelsior, etc. 

2. Inspect for Leakage. Remove the vent plugs and see that 
the electrolyte covers the plates. Rough handling in shipping 


Fig. 17. The Battery Installed 


may have cracked one of the jars. If the electrolyte does not 
cover the plates, or if there is electrolyte around the jars or at 
the joints in the box, one or more of the jars are probably broken. 
In this case, take the matter up with the transportation company, 
or party from whom the battery was received. 

3. Installation of the Storage Battery. A special battery com- 
partment is provided on the automobile in the majority of cases 
which provides both an electrical and mechanical protection. The 


70 THE AUTOMOBILE STORAGE BATTERY 


battery must be firmly fastened in a definite position in the battery 
box or compartment, so as to prevent any movement due to the 
vibration of the car. Special hooks are usually provided for hold- 
ing the battery in place by fastening their upper ends in openings 
or handles on the wooden containing case, their lower ends passing 
through the bottom of the battery compartment. See Figure 17. 
A thumb-nut or other adjustment is provided on these hooks by 
means of which they may be drawn up. It is advisable to place 
the battery on several small wooden cleats laid on the bottom of 


Fig. 18, Battery Short Circuited by a Pair of Pliers 


the battery compartment unless such cleats are provided, and 
then place the battery in such a position in the compartment that 
there will be an air space on all sides as well as top and bottom. 
This arrangement gives the maximum mechanical and electrical 
protection as well as the best ventilation. It is not advisable to 
use any packing of any kind about the battery, but depend en- 
tirely upon the hooks to hold it firmly in place. Lack of care in 
properly securing the battery will undoubtedly result in broken 
battery jars, broken electrical connections or cracked sealing 
compound, any one of which may result in serious damage to the 


HOW TO TAKE CARE OF BATTERY ON CAR 71 


battery and at the same time make the electrical system inop- 
erative. Under no conditions use the battery compartment in 
storing tools, oil cans, pieces of wire, etc., as they are likely to 
jolt around and short cricuit one or more of the cells. 

The leads coming into the battery compartment should be long 
enough so that the terminals on their ends may be easily attached 
to the terminals of the battery and still have ample slack in the 
leads so as to prevent the terminals or connections being broken 
should the battery happen to move. Care should be exercised 
in making the electrical connections to the battery to see that the 
surfaces coming into contact are thoroughly cleaned and the area 
of the contact is as large as possible, which means a minimum 
resistance. Under no condition connect a copper wire directly 
to the terminal of a storage battery, as the acid fumes will attack 
the eopper and start corrosion, which will eventually result in the 
end of the wire being eaten off entirely and at the same time a 
badly corroded battery terminal.. If such connections are neces- 
sary in order to take care of additional circuits and equipment 
other than the regular equipment, connection may be made to the 
leads from the battery some distance from the battery or pref- 
erably at a terminal block when one is provided. 

There is room for great improvement in the design of battery 
terminals and cable connections. The best method has the cables 
burned directly to the battery posts. This eliminates the possi- 
bility of corrosion at the connection between the cable and the 
post. The burned-on cables should be fastened to a terminal block 
placed on the side of the box. The cables and wires leading to 
the starting motor and other parts of the car should be fastened 
to these terminal blocks also. If all batteries were connected in 
this fashion, much of time spent in the cleaning of terminals, and 
charging made necessary by loose or corroded connections would 
be saved. 

4, Connection of Battery. The cables attached to the battery 
lead to the starting motor, dynamo, lighting system, and very 
frequently the ignition system also. As far as the starting, light- 
ing, and ignition systems are concerned, it makes no difference 
which cable is connected to the positive (marked ‘‘P,’’ ‘‘Pos,’’ or 
‘19. battery terminal post and which cable is attached to the 


72 THE AUTOMOBILE STORAGE BATTERY 


negative (marked ‘‘N,’’ ‘‘Neg,’’ or ‘‘—’’) battery terminal post. 
With some dynamos this is also true. With most dynamos, how- 
ever, the cable which is attached to the positive battery terminal 
must lead to the positive dynamo terminal, and the cable which 
is attached to the negative battery terminal must !ead to the 
negative dynamo terminal. On many cars, one battery terminal 
is connected to the iron car frame. In this case the corresponding 
terminal on the dynamo must also be connected to the iron car 
frame. The other battery terminal is connected to the remaining 
dynamo terminal. If it is not known which cable leads to the posi- 
tive and which to the negative dynamo terminal, the following 
test may be made: 

Fill a tumbler with electrolyte or 
salt water. Fasten a wire to each 
cable, insert the wires in the tumbler, 


Now start the engine, and run it at 
a speed corresponding to a car speed 
of not less than 20 miles per hour. 


one of the wires, and.the cable to 


the negative dynamo terminal, and 
should be connected to the negative 
battery terminal. See Figure 19. 

B. Freshening Charge. Battery should be given a charge just 
before installing on car, or immediately after, at the charging 
rate stamped on the nameplate. Directions for charging will be 
given later. 

6. Keep Battery and Interior of Battery Box Wiped Clean 
and Dry. For this purpose use a rag dipped in ammonia or baking 
soda. Do not bring an open flame near the battery vent holes. 
The reason for this is that bubbles of hydrogen and oxygen 
escape from the electrolyte, and the mixture is very explosive. 

In ease the electrolyte or water has been spilled on top of the 
battery, the surface should be rubbed off with a cloth that has 
been moistened with ammonia water and should then be wiped 
with a dry cloth. 


keeping them at least one inch apart. | 


which this wire is attached leads to | 


Fine bubbles of gas will collect at | 


se" 


HOW TO TAKE CARE OF BATTERY ON CAR 73 


The battery terminals and other connections must be clean and 
free from corrosion. Should erystals or cakes of blue-green copper 
sulphate be found the parts should be washed with a solution 
of baking soda in hot water and should then be covered with 
vaseline to prevent further action by the acid. 

7. Inspect the Battery Twice a Month in Winter, and Once a 
Week in Summer, to Make Sure That the Electrolyte Covers the 
Plates. To do this, remove the filling plugs and look down through 
the opening, as shown in Figure 20. If a light is necessary for 
this purpose, use an electric lamp. Never use an open flame, such 
as @& match or candle. An 
explosion may result from 
the gases of the battery. Dur- 
ing the normal course of op- 
eration of the battery, water 
from the electrolyte will 
evaporate. The acid never 
evaporates. The surface of 
the electrolyte should be not 
less than one half inch above 
the tops of the plates. A con- 
venient method of measuring 
the height of the electrolyte 
is shown in Figure 21. Insert 
one end of a short piece of 
a glass tube, having an open- 
ing not less than one-eighth 
inch diameter, through the 
filling hole, and allow it to "#,,20;,Fraplgine the jae of Bat 
rest on the upper edge of the See the Height of Solution 
plates. Then place your finger over the upper end, and withdraw 
the tube. A column of liquid will remain in the lower end of the 
tube as shown in the figure, and the height of this column is the 
same as the height of the electrolyte above the top of the plates in 
the cell. If this is less than one-half inch, add enough distilled 
water to bring the electrolyte up to the proper level. Never use 
well water, spring water, water from a stream, or ordinary faucet 
water. These contain impurities which will damage the battery if 


xe THE AUTOMOBILE STORAGE BATTERY 


used. If no distilled water is available, clean rain water, if collected 
in the country, or melted artificial ice may be used. Rain water in 


Fig. 22 


the city is seldom pure enough. 
City atmospheres usually contain 
ammonia, and other gases which the 
rain absorbs in falling, making it 
unfit for use. In winter time, if 
the air temperature is below freez- 
ing (32°F), start the engine before 
adding water, and keep it running 
for about one hour after the battery 
begins to ‘‘gas.’’? A good time to 
add the water is just before starting 
on a trip, as the engine will then 
usually be run long enough to 


charge the battery, and cause the water to mix thoroughly with 
the electrolyte. Otherwise, the water, being lighter than the electro- 


‘UNSCREW 
‘THIs CAP 


FILL UP TO 
THIS POINT: 


Fig, 22. Cross Section of Battery, Showing Correct Level of Water 


HOW TO TAKE CARE OF BATTERY ON CAR) 75 


Ff. 23. Pour Some of the Dis- Fig. 24. Release the Pressure on 
tilled Water Into a Glass. the Bulb, Thus Drawing Water 
Squeeze the Air Out of the Up Into the Hydrometer 
Bulb of the Hydrometer. Put . 


Rubber Tip in the Glass 


Fig. 25. Insert the Tube in Vent Hole in Center of Battery, and Squeeze the 
‘drometer Bulb Until the Cell Is Filled to the Proper Level 


6 THE AUTOMOBILE STORAGE BATTERY 


Fig. 2B. Release the Pressure on the Bulb and Hold Syringé in Horizontal, Position 
Prevent Water from Dripping on Battery. Return Excess Water to Glass 


Fig. 27. Replace the Screw Plugs and Wipe Dirt and Moisture from Top of Battery 


HOW TO TAKE CARE OF BATTERY ON CAR 77 


Fig. 28. Showing Battery with Electrolyte too High 


Fig. 29. Showing Battery with Electrolyte too Low 


78 THE AUTOMOBILE STORAGE BATTERY 


lyte, will remain at the top and freeze. Be sure to wipe all water 
from the battery top after filling. It is essential that distilled 
water be used for this purpose, and it must be handled carefully 
so as to keep impurities of any kind out of the water. Never 
use a metal can for handling water or electrolyte for a 
battery, but always use a glass or porcelain vessel. The 
water should be stored in glass bottles, and poured into a 
porcelain or glass pitcher when it is to be used. A con- 
venient method of adding the water to the battery is to draw 
some up in a hydrometer syringe and add the necessary amount 
to the cell by inserting the rubber tube which is at the lower 
end into the vent hole and then squeezing the bulb until the 
required amount has been put into the cell. This is shown pic- 
torially in Figures 22 to 29 inclusive. 

The acid in the electrolyte does not evaporate, and it is very 
seldom necessary to add acid. Acid is lost when a cell gasses; 
electrolyte may be spilled; a cracked jar will allow electrolyte 
to leak out; if too much water is added, the expansion of the 
electrolyte when the battery is charging may cause it to run over 
and be lost, or the jolting of the car may cause some of it to be 
spilled; if a battery is allowed 
to become badly sulphated, 
some of the sulphate is never 
reduced, or drops to the bottom 
of the cell, and the acid lost in 
the formation of the sulphate is 
not regained. Thus it is seldom 
necessary to add acid. If acid 
or electrolyte is added instead 
of water, when no acid is need- 
ed, the electrolyte will become 
too strong, and sulphate plates 
will be the result. If a battery 
under average driving condi- 
tions never becomes fully 
charged, it should be removed 
from the ear and charged from 8,3 0., ,thls Shows How Eiaies snd 


an outside source as explained ing Acid Solution Instead of Water 


HOW TO TAKE CARE OF BATTERY ON CAR 79 


later. If, after a long continued charge, the battery is still not fully — 
charged, some of the electrolyte should be removed, fresh electro- 
lyte having a specific gravity of 1.400 should be added instead of 
water. This should preferably be done by an experienced battery 
man. 

Care must be used not to fill the battery cells too far above the 
plates. By looking down through the opening left when the filler 
plug is removed a second opening may usually be seen, between 
a half inch and one inch below the top. The level of the liquid 
should be at this lower hole but should not be brought above it. 
See Figure 28. 

If the battery is filled above this point, the electrolyte will run 
over the top of the tube, cause a short circuit between the battery 
terminals, and run down the sides of the box. It may get into 
the metal battery box and eat out the bottom, as well as rot the 
wooden battery case. 

8. The specific gravity of the electrolyte orm, 
should be measured every two weeks anda ft'(/(..\'\." 
permanent record of the readings made for 
future reference. ) 

As already explained, the specific gravity 
of the electrolyte is the ratio of its weight 
to the weight of an equal volume of water. 
Acid is heavier than water, and hence the 
heavier the electrolyte, the more acid it con- 
tains, and the more nearly it is fully 
charged. In automobile batteries, a specific 
gravity of 1.3800-1.250 indicates a fully 
charged battery. Other readings are as 
follows: 

1.300-1.250—Fully charged. 

Se 1,250-1.200—More than half charged. 
Fig. 31 1.200-1.150—Less than half charged. 
1.150 and less—Completely discharged. 

For determining the specific gravity, a hydrometer is used. This 
consists of a small sealed glass tube with an air bulb and a quan- 
tity of shot at one end, and a graduated scale on the upper end. 
This scale is marked from 1.100 to 1.300, with various intermediate 


80 THE AUTOMOBILE STORAGE BATTERY 


markings as shown in Figure 31. If this hydrometer is placed in 
a liquid, it will sink to a certain depth. In so doing, it will displace 
a certain volume of the electrolyte, and when it comes to rest, the 
volume displaced will just be equal to the weight of the hydrometer. 
It will therefore sink farther in a light liquid than in a heavy one, 
since it will require a greater volume of the light liquid to equal 
the weight of the hydrometer. The top mark on the hydrometer 
scale is therefore 1.100 and the bottom one 1.300. 

For convenience in automobile work, the hydrometer is enclosed 
in a large glass tube having a short length of rubber tubing 
at its lower end, and a large rubber bulb at the upper end. 
The combination is called a hydrometer-syringe, or simply hy- 

drometer. See Figure 32. In 
measuring the specific gravity 
of the electrolyte, the filler plug 
is removed, the bulb is squeezed 
{so as to expel the air from it, 
and the rubber tubing inserted 
in the hole from which the plug 
was removed. The pressure on 
the bulb is now released, and 
electrolyte is drawn up into the 
glass tube. The rubber tubing 
on the hydrometer should not 
be withdrawn from the cell. 
When a sufficient amount has 
entered the tube, the hydrom- 
eter will float. In taking a 
reading, there must be no pres- 
sure on the bulb, and the hy- 
drometer should be floating 

Fig. 33. Taking a Specific Gravity freely and not touching the 

Reading walls of the tube. The tube 
must be held in a vertical position, and the stem of the hydrometer 
must also be vertical. The reading will be the number on the 
stem at the surface of the electrolyte in the tube. Thus if the 
hydrometer sinks in the electrolyte, until the electrolyte comes 
up to the 1.150 mark on the stem, the specific gravity is 1.150. 


HOW TO TAKE CARE OF BATTERY ON CAR. 81 


Having taken a reading, the bulb is squeezed so as to return 
the electrolyte to the cell. 

Care should be taken not to spill the electrolyte from the hy- 
Crometer syringe when testing the gravity. Such moisture on top 
of the cells tends to cause a short circuit between the terminals 
and to discharge the battery. 

In making tests with the hydrometer the electrolyte should 
always be returned to the same cell from which it was drawn. 
Failure to do this will finally result in an increased proportion of 
acid in one cell and a deficiency of acid in others. 

The specific gravity of all cells of a battery should rise and fall 
together, as the cells are usually connected in Series so that the 
Same current passes through each cell both on charge and dis- 
charge. Some batteries are divided into two or more sections 
which are connected in parallel while the engine is running, and 
in such cases the cables leading to the different sections should 
all be of exactly the same length, and the contacts in the switch 
which connect these sections in parallel should all be clean and 
tight, If cables of unequal length are used, or if some of the 
switch contacts are loose and dirty, the sections will not receive 
equal charging currents, because the resistances of the charging 
circuits will not be equal. The section having the greatest 
resistance in its circuit will receive the least amount of charge, 
and will show lower specific gravity readings than for other sec- 
tions. In a multiple section battery, there is therefore a tendency 
for the various sections to receive unequal charges, and for one 
or more sections to run down continually. An ammeter should be 
attached with the engine running and the battery charging, first 
to one section and then to each of the others in turn. The am- 
meter should be inserted and removed from the circuit while the 
engine remains running and all conditions must be exactly the 
same, Otherwise the comparative results will not give reliable 
indications. It would be better still to use two ammeters at the 
same time, one on each section of the battery. In case the am- 
perage of charge should differ by more than 10% between any two 
sections, the section receiving the low charge rate should be 
examined for proper height of electrolyte, for the condition of its 


82 | THE AUTOMOBILE STORAGE BATTERY 


terminals and its connections at the starting switch as described. 
Should a section have suffered considerably from such lack of 
charge its voltage will probably have been lowered. With all 
connections made tight and clean and with the liquid at the 
proper height in each cell this section may automatically receive a | 
higher charge until it is brought back to normal. This high | 
charge results from the comparatively low voltage of the section 
affected. 


30 


Fig. 34 Fig. 35 
Hydrometer Reading, 1.300 ‘Hydrometer Reading, 1.150 


{ 
In case the car is equipped with such a battery, each section 
must carry its proper fraction of the load and with lamps turned 
on or other electrical devices in operation the flow from the sev- 
eral sections must be the same for each one. An examination 
should be made to sce that no additional lamps, such as trouble \ 
finders or body lamps, have been attached on one side of the { 
battery, also that the horn and other accessories are so connected 
that they draw from all sections at once. 


HOW TO TAKE CARE OF BATTERY ON CAB 83 


Some starting systems now being used have not been designed 
carefully in this respect, one section of the battery having longer 
cables attached to it than the others. In such systems it is impos- 
sible for these sections to receive as much charging current as 
others, even though all connections and switches are in good con- 
dition. In other systems, all the cells of the battery are in series, 
and therefore must receive the same charging current, but have 
lighting wires attached to it at intermediate points, thus dividing 
the battery into sections for the lighting circuits. If the currents 
_taken by these circuits are not equal, the battery section supplying 
the heavier current will run down faster than others. Fortunately, 
multiple section batteries are not being used to any great extent 
at present, and troubles due to this cause are disappearing. 

If one cell of a battery shows a specific gravity which is de- 
eidedly lower than that of the other cells in series with it, and 
if this difference gradually increases, the cell showing the lower 
gravity has internal trouble. This probably consists of a short 
circuit. If the electrolyte in this cell falls faster. than that of the 
other cells, a leaky jar is indicated. The various cells should have 
specifie gravities within twenty-five points of each other, such as 
1.250 and 1.275. 

If the entire battery shows a specific gravity below 1.200, it is 
not receiving enough charge to replace the energy used in starting 
the engine and supplying current to the lights, or else there is 
trouble in the battery. The troubles which cause low gravity 
are given on pages 172 to 174. It is often difficult to determine 
what charging current should be delivered by the generator. 
Some generators operate at a constant voltage slightly higher 
than that of the fully charged battery, and the charging current 
will change, being higher for a discharged battery than for one 
that is almost or fully charged. Other generators deliver a con- 
stant current which is the same regardless of the battery’s con- 
dition. To give data on this subject is beyond the scope of this 
book. Complete information is given in the Ambu Charts pub- 
lished by the American Bureau of Engineering, Ine. 

In the constant voltage type of generator, the charging current 
automatically adjusts itself to the condition of the battery. In 
the constant current type, the exact value of current for which 


84 THE AUTOMOBILE STORAGE BATTERY 


the generator is designed and adjusted is determined by the manu- 
facturer, and is intended to keep a battery charged under the 
average driving conditions. Individual cases often require that 
another current value be used. In this case, the output of the 
generator must be changed. With most generators, a current 
regulating device is used which may be adjusted so as to give 
a fairly wide range of current, the exact value chosen being the 
result of a study of driving conditions and of several trials. The 
charging current should never be made so large that the tem- 
perature of the electrolyte in the battery is above 90° Fahrenheit. 
A dairy thermometer is very useful in determining the tempera- 
ture. See Figure 36. The thermometer bulb is immersed in the 
electrolyte above the plates through the filler hole in the tops of 
the cells. Complete information on generators is given in the 
Ambu Charts referred to above. 

Specific gravity readings should never be taken soon after dis- 
tilled water has been added to the battery. The water and elec- 
trolyte do not mix immediately, and such readings will give mis- 
leading results. The battery should be charged several hours 
before the readings are taken. It is also a good plan to take a 
specific gravity reading before adding any water, since accurate 
results can also be obtained in this way. 

If the gravity, before filling, was below 1.150, the battery should 
be removed from the car and fully charged from an outside 
source. If the gravity was 1.150 or above the engine should be 
run at a speed that corresponds to 15 to 20 miles per hour, with- 
out any lamps turned on, for‘a total of at least twelve hours. This 
treatment should be continued until the specific gravity of the 
battery does not show any further rise for two hours. If the 
gravity was 1.100 or below the charging must be continued for a 
total of sixty hours or more. If the battery is recharged on the 
ear, it will be best to substitute lamp bulbs of lower candle power 
than those regularly used until the gravity comes up to 1.275. 

A completely discharged battery will ordinarily take about 
twenty hours’ charging to bring it up, but if the battery has stood 
for a considerable length of time in a discharged condition or has 
been reversed it may take several days to bring the gravity up to 
normal, 


HOW TO TAKE CARE OF BATTERY ON CAR 85 


The temperature of the electrolyte affects the specific gravity, 
since heat causes the electrolyte to expand. If we take any bat- 
tery or cell and heat it, the electrolyte will expand and its specific 
gravity will decrease, although its actual strength will be the 
same, because the actual amount of acid is the same. The change 
in specific gravity amounts to one point, approximately, 
for each degree Fahrenheit change. If the electrolyte 
has a gravity of 1.250 at 70°F, and the temperature is 
raised to 73°F, the specific gravity of the battery will be 
1.249. If the temperature is decreased to 67°F, the spe- 
cific gravity will be 1.251. Since the change of tempera- 
ture does not change the actual strength of the electro- 
lyte, the gravity readings as obtained with the hydrom- 
eter syringe should be corrected one point for every three 
degrees change in temperature. Thus 70°F is considered 
the normal temperature, and one point is added to the 
electrolyte reading for every three degrees above 70°F. 
Similarly, one point is subtracted for every three de- 
grees below 70°F. For convenience of the hydrometer 
user, a special thermometer has been developed by bat- 
tery makers. This is shown in Figure 36. It has a 
special scale mounted beside the regular scale. This 
scale shows the corrections which must be made when 
the temperature is not 70°F. Opposite the 70 point on 
the thermometer is a ‘‘0’’ point on the special scale. 
This indicates that no correction is to be made. Op- 
posite the 67° point on the regular scale is a —1, indi- 
eating that 1 must be subtracted from the hydrometer 
reading to find what the specific gravity would be if 
the temperature were 70°F.. Opposite the 73° point on 
the regular scale is a -++1, indicating that 1 point must 
be added to reading on the hydrometer, in order to 
reduce the reading of specific gravity to a temperature 
of 70°F. Fig. 36 

. Special 

9. Operating Temperatures. Storage batteries are Thermon- 
Strongly affected by changes in temperature. Both ex- eter 
tremely high, and very low temperatures are to be avoided. At low 
temperatures the electrolyte grows denser, the porosity of plates 


ST S.e FLELS. EL 


| ee 


UE Uo TES Oe EO 


pj] jo] Be] S| Bl 


86 THE AUTOMOBILE STORAGE BATTERY 


and separators decreases, circulation and diffusion of electrolytes 
are made difficult, chemical actions between plates and acid take 
place very slowly, and the whole battery becomes sluggish, and acts 
as if-it were numbed with cold. The voltage and capacity of the 
battery are lowered. . 

As the battery temperature increases, the density of the electro- 
lyte decreases, the plates and separators become more porous, the 
internal resistance decreases, circulation and diffusion of electro- 
lyte take place much more quickly, the chemical actions between 
plates and electrolyte proceed more rapidly, and the battery voltage 
and capacity increase. A battery therefore works better at high 
temperatures. 

Excessive temperatures, say over 100°F, are, however, more 
harmful than low temperatures. Evaporation of the electrolyte 
takes place very rapidly, the separators are attacked by the hot 
acid and are ruined, the active materials and plates expand to 
such an extent that the active materials break away from the grids 
and the grids warp and buckle. The active materials themselves 
are burned and made practically useless. The hot acid also attacks 
the grids and the sponge lead and forms dense layers of sulphate. 
Such temperatures are therefore extremely dangerous. 

A. battery that persistently runs hot, requiring frequent addi- 
tion of water is either receiving too much charging current, or 
has internal trouble. The remedy for excessive charge is to de- 
crease the output of the generator, or to burn the lamps during 
the day time. Motorists who make long touring trips in which 
considerable day driving is done, with little use of the starter, 
experience the most trouble from high temperature. The remedy 
is either to install a switch with which the generator may be dis- 
connected from the battery, or to use the lamps as mentioned 
above. 

Internal short-circuits cause excessive temperature rise, both 
on charge and discharge. Such short circuits usually result from 
buckled plates which break through the separators, or from an 
excessive amount of sediment. This sediment consists of active 
material or lead sulphate which has dropped from the positive 
plate and fallen to the bottom of the battery jar. All battery 
jars are provided with ridges which keep the plates raised an inch 


HOW TO TAKE CARE OF BATTERY ON.CAR 87 


or more from the bottom of the Jar, and which form pockets into 
which the materials drop. See Figure 22. If these pockets be- 
come filled, and the sediment reaches the bottom of the plates, 
internal short circuits result which cause the battery to run down 
and cause excessive temperatures. 

If the electrolyte is allowed to fall below the tops of the plates, 
the parts of the plates above the acid become dry, and when the 
battery is charged grow hot. The parts still covered by the acid 
also become hot because all the charging current is carried by 
these parts, and the plate surface is less than before. The elec- 
trolyte will also become hot and boil away. A battery which is 
thus ‘‘charged while dry’’ deteriorates rapidly, its life being very 
short. : 

Sulphated plates will also grow hot, even with a normal charg- 
ing current, because only those parts of the active material which 
are not covered by lead sulphate carry the current, and therefore 
heat up. This results in buckling and fracture of plates. 

If a battery is placed in a hot place on the ear, this heat in 
addition to that caused by charging will soften the plates and 
jars, and shorten their life considerably. 

In the winter, it is especially important not to allow the battery 
to become discharged, as there is danger of the electrolyte freez- 
ing. A fully charged battery will not freeze except at an extremely 
low temperature. The water expands as it freezes, loosening the 
active materials, and cracking the grids. As soon as a charging 
current thaws the battery, active material is loosened, and drops 
to the bottom of the jars, with the result that the whole battery 
may disintegrate. Jars may also be cracked by the expansion of 
the water when a battery freezes. 

To avoid freezing, a battery should therefore be kept charged. 
The temperatures at which electrolyte of various specific gravities 
freezes are as follows: 


Specific Gravity Freezing Pt. Specific Gravity Freezing Pt. 
1.020 30°F. 1.170 0°F. 
1.060 26°F, 1.220 -28°F. 
1.100 21°F. 1.260 -65°R, 


1.140 12°F. 1.290 -98°R, 


88 THE AUTOMOBILE STORAGE BATTERY 


No anti-freeze solution of any kind is required for use in the 
battery. The addition of alcohol or anything else except pure 
water to the cells will result in internal damage. 

10. Care of Storage Battery When Not in Service. A storage 
battery may be out of service for a considerable period at certain 
times of the year, for example, when the automobile is put away 
during the winter months, and during this time it should not be 
allowed to stand without attention. When the battery is to be out 
of service for only three or four weeks, it should be kept well 
filled with distilled water and given as complete a charge as possi- 
ble the last few days the car is in service by using the lamps and 
starting motor very sparingly. The specific gravity of the elec- 
trolyte should be tested in each cell, and it should be somewhere 
between 1.270 and 1.300. All connections to the battery should 
be removed as any slight discharge current will in time completely 
discharge it, and the possibilities of such an occurrence are to 
be avoided. If the battery is to be put out of service for several 
months, it should be given a complete charge by operating the 
dynamo on the car or by connecting it to an outside charging 
eircuit. During the out-of-service period, water should be added 
to the cells every six or eight weeks and the battery given what is 
called a refreshing charge; that is, the engine should be run until 
the.cells have been gassing for perhaps one hour, and the battery 
may then be allowed to stand for another similar period with- 
out further attention. Water should be added and the battery 
fully charged before it is put back into service. It may be neces- 
sary to charge the battery for 40 or 50 hours at one-half the 
normal raté before it will be fully charged if it has stood for five 
or six months without being charged. It is desirable to have the 
temperature of the room where the battery is stored fairly eon- 
stant and as near 70 degrees Fahrenheit as possible. 


| CHAPTER 13. 
MANUFACTURE OF STORAGE BATTERIES. 


To supply the great number of batteries needed for gasoline 
automobiles, many large companies have been formed and huge 
factories erected. Each company has its special and secret pro- 
cesses which it will not reveal to the public. Only a few com- 
panies supply batteries in any considerable quantities, the great 
majority of cars being supplied with batteries made by not more 
than five or six manufacturers. This greatly reduces the number 
of possible different designs in general use today. 

The design and dimensions of batteries vary considerably, but 
the general constructions are similar. The special processes of 
the manufacturers are of no special interest to the motoring pub- 
lic, and only a general description will be given here. . 

A starting and lighting battery consists of the following prin- 
cipal parts: 


1. Plates. ; 4. Jars. 
2. Separators. 5. Top connectors and. covers. 
3. Electrolyte. 6. Case. 


Plates. Of the two general types of battery plates, Faure and 
Plante, the Faure or pasted plate type is used on the great ma- 
jority of automobiles. In the manufacture of the Faure or 
pasted plates there are several steps which we shall describe 
in the order they are carried out. 

Moulding the Grid. The grid is a casting made of lead and 
antimony, about 6 to 10% of antimony being used. This gives 
a grid which is harder and stronger than pure lead, less liable 
to deformation, and one which is not affected by the battery acid 
to any appreciable extent. On the other hand, the grid is more 
brittle, and more liable to be fractured or broken if the active 
materials should expand abnormally. 

The lead and antimony are melted together, thoroughly mixed, 

89 


90 THE AUTOMOBILE STORAGE BATTERY 


and then poured into the molds. The Willard Co. makes two plates 
in one casting. The mold resembles a waffle-iron, the plates being 
molded bottom to bottom. The casting therefore has a lug at each 
end, and is thus easily handled, the lugs being used to hold the cast- 
ing in racks during the various processes through which it passes. 
The casting is not split into two plates until the paste has been 


Fig. 37. A Pair of Grids Trimmed and Ready to be Pasted. The Lugs at the Top Are 
for Burning in to the Connector Straps to Make a Group 

applied, and the plates formed and dried. The two parts of the 
casting are, of course, made into plates of the same polarity. 
After cooling, the grids are removed from the molds, and cleaned. 
The rough edges are trimmed off, and the parts polished. The 
grid is now ready for pasting. 

Figure 37 shows a Willard grid ready for pasting. It will be 
noticed that a heavy lug is at the upper left hand corner. This 


Pos, Connecting Strap Neg. Connecting Strap 
Fig. 38 


is later burned into a cross bar, together with other plates, and 
from this cross bar extends the outer battery terminal to which a 
battery cable or connecting link is attached. (See figure 38.) 
Seven vertical stiffening ribs, together with the four heavy ribs 
at the tops and side, serve to make the plate strong and rigid. 
It will be noticed that the top and left hand side piece taper away 


MANUFACTURE OF STORAGE BATTERIES 91 


from the lug. This gives strength and also provides a greater 
current carrying area near the lug. The amount of current carried 
by these ribs is greatest near the lug, and grows less toward the 
right hand end and bottom of the grid. 

In the Willard Battery the ribs all run at right angles to one 
another. This is true of most of the different'makes. In the 
Philadelphia Diamond grid, these ribs are arranged at smaller 
angles to each other, so as to form diamond shaped openings. 
The purpose of the ribs in any grid is to form a rigid supporting 
frame for the paste, and to distribute the current uniformly to 
all parts of the paste. The pastes used are weak mechanically, 
and could not be made into plates without the supporting grids, 
especially in automobile service, where batteries are often sub- 
jected to severe jolting. 


Fig. 39. A Pair of Formed Plates Ready to be Burned to the Connecting Straps 


Pastes. There are many formulas for the active materials. 
For the positive plates, litharge (PbO), or red lead, (Pb,O,), or 
a combination of the two is mixed with dilute sulphuric acid. A 
paste is made which is just thick enough to make it easy to 
work it into the spaces between the ribs of the grid. For the 
negative plates litharge (PbO) is generally made into a paste 
with dilute sulphuric acid. 

Various methods and machines are used for making the pastes. 
Some manufacturers use mixers which resemble the ordinary 
cement mixer and which are power driven. The lead com- 
pounds and acid are dumped into the mixers and the latter are 
then set in motion. Iland rotated drums are also used. 

Applying the pastes.. This may be done with the bare hands, 
or with wooden paddles, or with machines, as in the USL Machine 


92 THE AUTOMOBILE STORAGE BATTERY 


Pasted Plate. In hand pasting the pastes are worked first into 
one side of the grid, and then into the other. In machine pasted 
plates, both sides are filled with the pastes simultaneously. Fig- 
ure 40 shows a pasting room in a Willard factory. The pastes 
begin to harden from the time they are mixed, and the pasting 
is done quickly so as to apply the pastes before they are too 
stiff to be worked into spaces of the grids. 

The freshly pasted plates are now allowed to dry in the air, 
are put into drying ovens and dried by a hot air blast, or are 


Fig. 40. Pasting Room in the Willard Storage Battery Co. Factory 


immersed in dilute sulphuric acid for several days. In either 
ease, the pastes set to a hard mass, this being due to the forma- 
tion of lead sulphate, which hardens, and cements the particles 
of the paste. This sulphate becomes crystallized into a firm bind- 
ing mass without which the pastes would soon fall from the grids. 
The plates become so hard that they may be pounded on the 
floor without losing any paste. Both positive and negative plates 
are allowed to sulphate in this way. 

Forming. After the sulphation, or cementing process is com- 
pleted, the plates are brushed clean, and sent to the forming 


MANUFACTURE OF STORAGE BATTERIES 93 


room. This is usually a large room containing a number of acid 
filled tanks, into which the plates are placed. Figure 41 shows 
a forming room in the Willard factory. Negative and posi: 
tive plates are arranged very much as they appear in the finished 
battery. All positives are connected together, as are also the 
negatives. Current is then passed through the plates for from 
three to six days so as to change the pastes into sponge lead and 
lead peroxide; the process being called ‘‘forming”’ the plates. 
The forming current used varies with the size, design, and make, 


Fig- 41. Forming Room in the Willard Storage Battery Co, Factory 


the Willard Co. using a current of one-half ampere per plate. 
The ‘pastes as applied to the grids could not enter into chemical 
actions with the electrolyte so as to provide electricity for operat- 
ing a starting motor, or lamps. They must be changed consider- 
ably before becoming ‘‘active’’ material. The changes they 
undergo must be produced mainly by an electric current. 

At the beginning of the ‘‘forming”’ process, the positive plate 
contains about 55% of litharge (PbO), 25% of lead peroxide, 
(PbO,) and 20% of lead sulphate (PbSO,). The lead oxide 
begins to change to lead peroxide as soon as the forming current 
is started. The amount of lead sulphate begins to increase, and 


24 THE AUTOMOBILE STORAGE BATTERY | 


continues to do so for several hours. This is probably caused by 
the plate becoming more porous, so that the acid is able to reach 
more oxide, which it changes to sulphate. The sulphate soon 
changes to lead peroxide, however, and when the forming is 
completed, the positive plates contain nine per cent of litharge 
(PbO), 88% of lead peroxide (PbO,), and 3% of lead sulphate 
(PbSO,). This 3% of lead sulphate probably is never changed 
into lead peroxide if a battery is used normally, but it remains 
and acts as a cement to bind the particles of lead peroxide 
together. 


The negative plate cements until it contains 30% of lead sul- | 


phate. As soon as the forming current is passed through the neg- 
atives, lead begins to form immediately, but the amount of sulphate 
also increases. The amount of sulphate reaches a maximum and 
turns into spongy lead quite rapidly. The fully formed plate 
contains but a very small amount of lead sulphate, being com- 
posed of 98% of metallic lead and 2% of litharge. Very little 
lead sulphate is left, but the spongy lead is itself a tough, coher- 
ent substance, which sticks together all over the plate surface. 
When the forming current is turned off, the positive grids have 
a chocolate brown color, and negative plates have a slate gray 
color. 

Manufacturers have more complicated methods and formulas 
in mixing pastes for the plates. Some add organic acids, salts 
or sugar. These are mixed with the pastes, and are used either 
to increase the hardness of the paste, or to increase its porosity. 
Magnesium sulphate is also used for this purpose. These ‘‘form- 
ing’’ agents generally disappear after the battery has been used 
for some time. 

The sulphate which remains in the positive plate at the sur- 
face is soon changed to lead peroxide when the battery has been 
charged several times. The lead peroxide then drops to the 
bottom of the jars, and the plates are said to be ‘‘shedding.”’ 

In mixing the paste for the negative plates, magnesium sul- 
phate, or graphite are added to make the plate more porous. 
The value of these porosity agents is questionable, and they may, 
in fact, have a harmful effect upon the plate. 

As the forming progresses, the plates are tested from time 


MANUFACTURE OF STORAGE BATTERIES 95 


to time with a voltmeter, and the cadmium test is also made. 
(See Page 266.) In this way, the conditions of positive and nega- 
tive plates are determined separately. 

‘When the forming process is complete, the positive plates are 
rinsed in warm water and allowed to dry in the air. The nega- 
tive plates are also dried in the air. This results in the spongy 
lead on the negative plates changing back to litharge (PbO). 
The plates are now ready to be assembled into cells. , 


Separators. 


In batteries used both for starting and for lighting, separa- 
tors made of specially treated wood are largely used. Lately, 
however, the Willard Company has adopted an insulator made of 


Fig. 42. A Pile of Prepared Wooden Separators Ready to be Put Between the Pos- 

itive and Negative Plates to Form the Complete Element 
a rubber fabric pierced by thousands of cotton threads, each 
thread being as long as the separator is thick. The electrolyte is 
carried through these threads from one side of the separator to 
the other by capillary action, the great number of these threads 
insuring the rapid diffusion of electrolyte which is necessary 
in batteries which are subjected to the heavy discharge current 
required in starting. 

In batteries used for lighting or ignition, sheets of rubber 
in which numerous holes have been drilled are also used, these 
holes permitting diffusion to take place rapidly enough to per- 
form the required service satisfactorily, since the currents in- 
volved are much smaller than in starting motor serivee. 

For the wooden separators, porous wood, such as basswood, 


96 THE AUTOMOBILE STORAGE BATTERY 


cypress, or cedar are used. Redwood has been used to some 
extent. The wood is cut into strips of the correct thickness. 
These strips are passed through a grooving machine which cuts 
the grooves in one side, leaving the other side smooth. The strips 
are next sawed to the correct size, and are then put in a warm 
alkaline solution to neutralize any organic acid, such as acetic 
acid, which the wood naturally contains. Such acids would cause 
unsatisfactory battery action and damage to the battery. _ The 
alkali is finally washed out, and the separators given a final 
trimming. They are now ready for assembling. 


Electrolyte. 


Little need be said here about the electrolyte, since a. full 
description is given elsewhere. Acid is received by the battery 
manufacturer in concentrated form. Its specific gravity is then 
1.835. The acid commonly used is made by the ‘‘contact’’ pro- 
cess, in which sulphur dioxide is oxidized to sulphur trioxide, 
and then, with the addition of water, changed to sulphuric acid. | 
The concentrated acid is diluted with distilled water to a_ 
specific gravity of 1.300. 


Jars. 


The jars are made of vulcanized rubber. The complete jars 
are inspected carefully for flaws which might result in a leaky, 
short lived battery. Across the bottom gums 
of the jar are several stiff ribs which ex- 
tend up into the jar so as to provide a 
substantial support for the plates, and 
at the same time forming several pockets 
below the plates in which the sediment re- 
sulting from shedding of active material 
from the positive plates accumulates. 


Top Connectors and Covers. 


The connectors with which the cells are 
connected to each other are castings of 
lead, which, in batteries used for starting 
motors are made extra heavy so as to carry the heavy starting 
current without overheating. The covers are made of vulean- 


Fig, 48 


MANUFACTURE OF STORAGE BATTERIES 97 


ized rubber, and various manufacturers have developed special 
designs, their aims being to so construct the covers as to 
facilitate the escape of gases which result from charging, to 
provide space for the expansion of the electrolyte, to simplify 
filling with distilled water, to make leak-proof joints at the 
terminals and jars, and to simplify the work of making re- 
pairs. 


Fig. 44. Between Cell Link Fig. 45. Term. Link in Perspective 


Several designs «re shown below. Figure 22, page 74, shows 
a Willard construction. The rubber cover is shown in gray 
at the top of the cell. It is made in one piece, and contains 
the expansion’ chamber. The method of obtaining a leak-proof 
joint at the terminals is clearly shown. The sealing compound 
with which the joint between the cover and jar is made is 
shown in black at the top. 


Sectional View of Cover, Plug in Place. Air Lock (A) In Po- 
sition to Allow Free Escape of Gas Through Passages (BB) 


‘Top View of Cover and Filling Plug, Plug Removed 
- 
£ 


°c 8 a @ 

Sectional View of Cover, Plug Removed. Alr Passages (BB) 

Closed and Air Lock (A) in Position to Prevent Overfilling 
Fig. 46 


98 THE AUTOMOBILE STORAGE BATTERY 


Figure 46 shows the Non-Flooding Vent and Filling Plug used — 
in the ‘‘Exide’’ Battery. This is described by the Electric Storage 
Battery Company as follows, in one of its bulletins: | 

From the illustrations of the vent and filling plug, it will be | 
seen that they provide both a vented stopper (vents F, G, H) and 
an automatic device for the preventing of overfilling and flood- 
ing. In a simple and effective manner, the amount of water that 
can be put into the cells is limited to the cxact amount needed 
to replace that lost by evaporation. This is accomplished by 
means of the hard rubber valve (A) within the battery cover 
and with which the top of the filing plug (E) engages, as shown 
in the illustrations. The action of removing the plug (E) turns 
this valve (A), closing the air passage (BB), and forming an air 
tight chamber (C) in the top of the cell. When water is poured 
in, it cannot rise in this air space (C) so as to completely fill 
the cell, As soon as the proper level is reached, the waiter rises 
in the filling tube (D) and gives a positive indication that suffi- 
cient water has been added. Should, however, the filling be con- 
tinued, the excess will be pure water only, not acid. On re- 
placing the plug (E), valve (A) is automatically turned, opening 

the air passages (BB), leaving 

Sectional Views of Cover the air chamber (C) available for 

the expansion of the solution, 

which occurs when the battery is 
working. 

Fig. 47 shows the top construc- 
tion, and Figure 48 the method 
of filling USL batteries. The 
top is in one piece, and dome 
shaped so as to give strength, 
and to provide for an expansion 
chamber large enough to allow 
for the greatest expansion of 
electrolyte which is likely to oc- 

; . cur, even in the severest charge. 
with Bushings and Post Straps The holes through which the ter- 
minals posts pass each have a 

lead-antimony bushing which is flanged and molded in with the 
rubber so as to form a leak-proof joint. In assembling the battery, 


; 
Z 
p 
G 


g 
y) 
4 
g 
y 
y 
y 
4 
4 


MANUFACTURE OF STORAGE BATTERIES 99 


the cover is placed over the posts, and both the post and flange lead- 
burned to the connecting links. Figures 47 and 48 show clearly the 
large expansion chamber and the method of filling with distilled 
water. This is done as follows: 
A finger is placed over 
the vent tube shown in Fig- 
ure 48. The water is then 
poured in through the fill- 
ing tube. When the water 
reaches the bottom ‘of the 
tube, the air imprisoned in 
the expansion chamber can 
no longer escape. Conse- 
quently the water can rise 
no higher in this chamber, 
but simply fills up the tube. 
Water is added till it 
reaches the top of the tube. 
The finger is then removed 
from the vent tube. This 
allows the air to escape 
from the expansion ‘cham- 
ber. The water will there- 
fore fall in the filling tube, 
and rise slightly in the ex- 
pansion chamber. This con- 
struction makes it impossi- 
ble to overfill the battery, _ 
provided that the finger is 
held on the vent tube as di- 
rected. 


rere 


Cases. 

The wooden ease in which 
the battery cells are ‘placed 
is usually made of the best 
grade of white oak, which 
is kiln dried before being used to make it as nearly acid proof as 
Possible. The wood is inspected carefully, and all pieces are re- 


Fig. 48 


100 THE AUTOMOBILE STORAGE BATTERY 


jected that are weather-checked, or contain worm-holes or knots. 
The wood is sawed into various thicknesses, and then cut to the 
proper lengths and widths. The wood is passed through other 
machines that cut in the dovetails, put the tongue on the bottom 
for the joints, stamp on the part number, drill the holes for the 
serews or bolts holding the handles, cut the grooves for the seal- 
ing compound, ete. The several pieces are then assembled and 
glued together, this being done, in the Willard factory, by one 


Fig. 49. Battery Box or Case with Handles, It Is Made from Kiln-Dried Oak 
Lumber and Thickly Coated with Acid-Proof Paint. All Metal Parts, Other Than 
Lead, Are Lead-Coated to Keep Them from Corrosion by the Acid in the Battery 
Solution 

machine. The finishing touches are then put on, these consisting 
of cutting the cases to the proper heights, sandpapering the boxes, 
ete. The cases are then inspected and are ready to be painted. 

Asphaltum paint is generally used, the bottoms and tops being 

given three coats, and the sides two. The handles are then put 
on by machinery, and the box is complete, and ready for assem- 
bling. 


Assembling and Finishing. 


The first step in the assembly of a battery is to burn the correct 
number of positive and negative plates to their connecting straps, 


MANUFACTURE OF STORAGH BAYTRRIES 101 


thus forming the positive an@ negat %< gentipe or ““elements.”” 
The ‘‘burning”’ consists of melting the straps drfd lugs on the 
plates together with an oxygen-hydrogen, or oxygeu-acetylene 
flame so as to form one solid mass of lead. Positive and negative 
groups are next put together, with the separators between them. 
The completed groups are placed into the jars which are filled 
with electrolyte up to the proper points. The covers are put in 
position on the jars and the sealing compound poured over the 
joint between cover and jar so as to make a leak-proof joint. 
Figure 50 shows a cross-section of a completed cell. 


nk 
Sealing 
P ng 
ate 
Ne 


Fig. 50 


The completed cells are now ‘‘formed”’ again, a current of 
about one-half ampere per plate being sent through the cell for 
six to seven days. When the plates have thus been formed again, 
the negative plate again consists of pure spongy lead, and 
the positive of lead peroxide. When the second forming is 
finished, the cells are put in the wooden case, the connecting 
links burned to the strap posts, nameplate put on, date stamped 
on, a careful general inspection given, specific gravity again meas- 
ured, and the battery is ready for use on the car. 


CHAPTER 14. 
THE WORK SHOP. GENERAL INSTRUCTIONS. 


The degree of success which the battery repairman attains de- | 
pends to a considerable extent upon the workshop in which the 
batteries are handled. It is, of course, desirable to be able to | 
build your shop, and thus be able to have everything arranged 
as you wish. If you must work in a rented shop, select a place 
which has plenty of light and ventilation. The ventilation is 
especially important on account of the acid fumes from the bat- 
teries. A shop which receives most of its light from the north is 
the best, as the light is then more uniform during the day, and 
the direct rays of the sun are avoided. Figure 51 shows a light, 


Fig, 51. ‘Typical Work Room Showing Bench About 84 Inches High, Tanks of 
Hydrogen and Oxygen for Lead Burning, Hot, Plates for Melting ‘Sealing Cot 
bound and Hand: Drill-Press for Drilling off Top Connector 


102 
| 


THE WORKSHOP. GENERAL INSTRUCTIONS 103 


well ventilated workroom. At least 600 square feet of floor sur- 
face are needed, a shop 25 feet square being well suited for a 
small repair business. 

The fioor should be in good condition, since acid rots the 
wood and if the floor is already in a poor condition, the acid will 
soon eat through it. A tile floor, as described below, is best. A 
wooden floor should be thoroughly scrubbed, using water to which 
washing soda has been added. Then give the floor a coat of 
asphaltum paint, which should be applied very hot so as to flow 
into all the cracks in the wood. When the first coat is dry, several 
more coats should be given. Whenever you make a solution of 
soda for any purpose, do not throw it away when you are through 
with it. Instead, pour it on the floor where the acid is most likely 
to be spilled. This will neutralize the acid and prevent it from 
rotting the wood. 

If you can afford to build a shop, make it of brick, with a floor 
of vitrified brick, or of tile which is not less than two inches 
thick, and is preferably eight inches square. The seams should 
not be less than one-elghth inch wide, and not wider than 
one-fourth. They should be grouted with asphaltum, melted as hot 
and as thin as possible, (not less than 450°F). This should be 
poured in the seams. The brick or tile should be heated near the 
seams before pouring in the asphaltum. When all the seams have 
been filled, heat them again. After the second heating, the 
asphaltum may shrink, and it may be necessary to pour in more 
asphaltum. 

If possible, the floor should slope evenly from one end of the 
room to the other, with a drop of about one inch to the foot. A 
lead drainage trough and pipe at the lower end of the shop will 
carry off the acid and electrolyte. 

It is a good plan to give all work benches and storage racks 
and shelves at least two coatings of hot asphaltum paint. This 
will prevent rotting by the acid. 


Shop Equipment. 


The exact equipment of any shop will be governed by the 
size and shape of the shop, and the amount of money available 
for fitting it up. Six things are absolutely essential. These are: 


104 THE AUTOMOBILE STORAGE BATTERY 


1, Work benches with vise. 

2. Lead burning outfit. 

3. Sink with water supply. 

4, Charging bench and equipment. 

5. Shelving, for storing boxes, plates, jars, tools, burning lead, 
€. 
6. 


. Stove for heating sealing compound. 


Fig. 62. Suggested Layout for a Small Battery Repair Shop 


The arrangement of these parts will depend upon the size and 
shape of the workshop, and the ideas of the repairman. Figure 
52 shows a convenient design for a shop 25 feet square, and 
figure 53 is from an actual photograph of an up-to-date, pro- 
gressive small repairshop. Near the door is the desk where the 


THE WORKSHOP. GENERAL INSTRUCTIONS 105 


»0ok-keeping is done. A table is placed next to it for catalogues, 
nagazines, etc., and for eating lunch. 

The work bench extends across one end of the shop, and is six- 
een feet long. At one end is a sink, in which the sediment may 
»e washed out of the jars. Figure 54 is a photograph. The bent 
dipe extending upward is perforated with a number of 1-16 inch 
roles. In cleaning out jars, the battery box is inverted over the 


Fig. 53. Corner of Workshop, Showing Burning Outfit, Burning Bench and Vises 


Pipe. The water supply is controlled by a foot operated valve, 
so that the box may be held in both hands while it is washed. At 
the other end of the bench is the lead burning outfit, the use of 
which is explained later. The bench should be made of lumber 
two inches thick, and given several coats of hot asphaltum paint. 


Special Work Bench. 


The cross -shaped, double work bench shown at the ieft in Fig- 
ure 52 is of a special design, and requires a detailed explanation. 
The bench is to be used by two men, one sitting at each end, and 
with the following explanation, you should have little difficulty 


106 THE AUTOMOBILE STORAGE BATTERY 


in constructing one. Figure 55 is a photograph of this bench, 
as it has been used for several years. Figure 56 is a drawing 
giving dimensions. Give the various parts of the bench a good 
coat of asphaltum paint, not too thick, as you assemble it so as to 
cover the surfaces which will later be covered by other parts‘ 


Fig. 54, Sink with Faucet, and Extra Swinging Arm Pipe for Washing Out Jars. 
Four Inch Paint Brush for Washing Battery Cases 
and thus be impossible to paint. When completed, give the bench 
a second coat of asphaltum, and let it dry thoroughly before 
using. 

The bench should have a permanent location so that gas, if 
available, can be piped to it. Otherwise, a gasoline torch may 
be used. It is a good plan to have it near a wall or partition 
where each workman may have, within easy reach, shelves on 


THE WORKSHOP. GENERAL INSTRUCTIONS 107 


hich are kept labeled boxes with parts for different batteries 
process of repair and rebuilding. You will note that there are 
1 middle of bench, directly in front of each workman, elevated 
aelves, one for each workman, forming two pockets for tools, 
> that each may keep his own tools separate, with very little 
hance of becoming mixed. On the edge of shelves you ean put 
everal nails and hang any special wrenches, such as Exide lead 
ut wrench, monkey wrench, a pair of snips, a lead funnel, and 


Fig. 55. Double Work Bench 


a hammer or two, (bore holes in handles so you can hang up.) 
Tn each workman’s separate pocket there should be a pair of 
rubber gloves, four screw drivers, four putty knives,14 and ¥4 inch 
chisels, 2 pairs bent nosed pliers, 2 or 3 pairs different sizes of 
gas pliers, a good knife, a wire brush, a lead pencil, some good 
Tags and as asortment of pieces of boards 144x7% inches, and 
just long enough to go in between the handles of the different 
standard makes of batteries. These should be oiled, or a thin 
film of vaseline spread over them. They are used to even up 


108 THE AUTOMOBILE STORAGE BATTERY 


the separators in assembling, and also in pressing down the top 
covers when finishing rebuilding of batteries, as described later. 
You should also have one piece 114x% inch and one piece 114x!4 
inch, each 8 or 10 inches long. 

You will find the tool scraper (shown at J in figure 56) to 
the right of each workman very convenient for removing the 


DOUBLE WORK BENCH 


Fig. 56 


compound sticking to your tools, Always have a box under it 
to catch the compound. When a battery is on the bench and the 
workman sitting up to it, straddling battery and bench, he is 
in the best possible position to open it. 

A gas, gasoline, or oil pilot light should be mounted on one side 
of the two uprights. By using two screw drivers in opening a 
battery, one can be warming in the flame, while you are using 
the other. 


THE WORKSHOP. GENERAL INSTRUCTIONS 109 
Shelving. 


The dimensions of the shelving depend upon the nature of the 
material to be stored. For miscellaneous. parts, such as empty 
jars, empty boxes, groups of plates, tools, separators, cans of 
grease, bottles of ammonia, or soda solution, and so on, one 
inch stock is strong enough. For storing completely assembled 
batteries, two inch lumber should be used as they must carry 


Fig. 67. Typical Stockroom Showing Heavy Shelving Necessary for Storing Batterles 


loads of hundreds of pounds. The vertical distance between 
shelves should be two feet if there is sufficient space, in order to be 
able to take specific gravity readings without removing the bat- 
teries from the shelves. A space should be left between batteries 
for ventilation. Figure 57 shows the type of shelving required. 


Concerning Light. 


Many battery shops are unfortunately situated in basements. 
Light is essential to good work, so you must have plenty of 


110 THE AUTOMOBILE STORAGE BATTERY 


good light and at the right place. For a light that is needed 
from one end of a bench to the other, to look mto each individual 
battery, or to take the reading of each individual battery, there is 
nothing better than a 60 Watt tungsten lamp under a good metal 
shade, dark on outside and white on inside. | 

A unique way to hang a light and have it movable from one 
end of the bench to the other, is to stretch a wire from one end 
of the bench to the other. Steel or copper about 10 or 12 B &S 
gauge may be used. Stretch it about four or five feet above top 
of bench directly above where the light is most needed. If 
you have double charging bench, stretch the wire directly above 
middle of bench. Before fastening wire to support, slip an old 
fashioned porcelain: knob (or an ordinary thread spool) on the 
wire. The drop cord is to be tied to this knob or spool at what- 
ever height you wish the light to hang (a few inches lower than 
your head is the right height). | 

Put the ceiling rosette above middle, endwise of bench; eut 
your drop cord long enough so that you can slide the ight from 
one end of bench to the other after being attached to rosette. 
Put vaseline on the wire so the fumes of gas will not corrode it. 
This will make the spool slide easily. This gives you a movable, 
flexible light, with which you will reach any battery on bench 
for inspection. The work bench light can be rigged up the same 
way and a 75 or 100 Watt nitrogen lamp used, 


Charging Methods. 


A man must have food and exercise to retain his health and 
strength. Moreover, there must be a proper balance between 
the food and exercise. Unused muscles become stiff and weak, 
and food alone will not restore their strength. A man who takes 
more food than his body needs becomes fat, sluggish and diseased. 
Tf, on the other hand, he works hard, and does not eat a suffi- 
cient amount of food, his body becomes exhausted, and he is sick, 
and unable to work. Even when no exercise is taken, the man 
must have food, or he will die of starvation. 

The storage battery is quite human in many respects. It must 
have the proper amount of food and exercise in order to be 


THE. WORKSHOP. GENERAL INSTRUCTIONS 111 


in the best of health. It must have food, even though it may 
be idle; but, on the other hand, it must not have too much food 
at any time, even though it may be working regularly and using 
ip energy supplied by the food. 

A battery, unlike a man, has no mind to enable it to regulate 
its food and exercise, and is entirely at the mercy of the ear 
ywner and garage battery man. When called upon it must work 
as long as a bit of energy remains, and until it is completely ex- 
aausted and often hopelessly injured. It must also accept all 
the food offered to it,,even though the amount is far in excess of 
that needed to restore the amount of energy used up in doing its 
work. Since the battery is thus unable to defend itself against 
any abuse and mistreatment to which it may be subjected, it 
osecomes necessary for the car owner and repairman to think for 
the battery, and to treat it as he does his own body, giving it 
the proper amount of food and exercise. 

Electricity is the battery’s food, and you feed the battery 
when you charge it. The electricity must be digested just as 
our own food is.- The process of digestion in the battery consists, 
of the formation of spongy lead and lead peroxide from the lead 
sulphate. When all the sulphate has been thus changed, the bat- 
tery has received as much food as it can digest, and if it is given 
more, the energy of the food will be wasted. 

The battery works by using the energy resulting from the di- 
gestion of the electricity, and it should not be forced to work 
until its energy is completely exhausted, any more than a man 
should work until he drops from weariness. A man in such an 
overworked condition is sick, and requires careful nursing and 
feeding to restore his health. An overworked battery or starved 
battery requires slow feeding, because its weakened elements 
cannot absorb the food or charging current quickly, but must 
be charged at a low rate. 

The feeding of a battery is in the repairman’s hands, and he 
must see that the battery is not overworked or starved any more 
than he overworks or starves himself. Thus, charging the bat- 
tery means more than simply sending a current through it. The 
eurrent must not be supplied faster than the battery can absorb 


112 THE AUTOMOBILE STORAGE BATTERY 


it. Batteries of different sizes must not be given the same amount 
of food any more than men of different sizes must be. 

The great majority of battery men have adopted the plan of 
connecting batteries in series while charging them. This is un- 
doubtedly the cheapest and most convenient method, but has 
several disadvantages. 

Batteries which have different voltages and capacities require 
different charging currents, and great care should be taken that 
the batteries which are connected in series require approximately 
the same charging currents, and are of the same voltage. Garage- 
men are often careless in this respect, and the smaller batteries are 


PosiTvEe NEGATIVE 
BATTERY BATT ERY 


Fig. 58 


POSITIVE CHARGING NEGATIVE CHARGH 
LINE WwWiRme LINE WIRE 


CHARGING BATTERIES IN SERIES | 
Fig. 59 


greatly overcharged and literally ‘‘boiled to death.’’ In charg-. 
ing, therefore, do not connect batteries of various sizes in series | 
and send the same charging current through them. The smaller 
batteries will heat up in their attempt to absorb the heavier 
current required by the larger batteries, and may be permanently 
injured. 

Furthermore, the batteries should be in approximately the same 
state of discharge, as shown by the specific gravity readings. If 
these readings differ considerably among the various batteries, 
those with the highest readings should be watched carefully, and 
removed from the circuit when there is no further rise in specific . 
gravity after all cells are gassing freely. Never start a charge 


THE WORKSHOP. GENERAL INSTRUCTIONS 113 


at such a high rate that gassing takes place immediately, or 
before the specific gravity stops rising. | 


In connecting a battery to a charging line, always connect the ‘ 


positive battery to the positive line wire, and connect the nega- 
tive battery terminal to the negative line wire, figure 58. If 
you connect a number of batteries in series for charging, connect 
the positive terminal of one battery to the negative terminal 
of the next, figure 59. . 

Instead of connecting all the cells in series, it is a good plan 
to have several charging circuits in parallel, and connect enough 
batteries in series on each circuit to obtain the correct charging 
eurrent. In this way, batteries of various capacities may be 
charged at once, each circuit being composed of batteries of ap- 
proximately the same capacity. 

The sum of the voltages of the batteries which are connected 
in series should never be greater than the voltages of the charg- 
ing circuit. This would result in the batteries discharging back 
into the line, instead of being charged. 


Charging Equipment. 

The apparatus to be employed in charging starting and light- 
ing batteries depends largely upon the source of electricity which 
is available. If a 110 volt, direct current supply is used, .the 
simplest and cheapest apparatus is the charging bench with lamps 
for resistance, which will be described. Instead of the lamps, a 
motor-generator set may be used, which has a 110 volt, direct cur- 
rent motor, and a low voltage generator. ‘Such an outfit is far 
more expensive than the lamps, however, and has no marked 
advantages to justify its installation. 

Where only alternating current is available, a rectifier or motor- 
generator must be installed. The rectifier changes the alternating 
current into a direct current. It may do this by means of a 
mechanical device, an electrolytic cell, or a tube of mercury 
vapor. The motor-generator set consists of an alternating cur- 
rent motor driving a direct current generator. Both the Mercury 
Arc Rectifier and the Motor-Generator are efficient. 


a 


114 THE AUTOMOBILE. STORAGE BATTERY 
Double Charging Bench. 


The charging bench, as shown in Figures 60 and 61 is designed 
to accommodate thirty-two batteries. The bench shown in Fig- 


ure 60 has been in actual use for several years. The wiring shown , 


in Figure 62 is somewhat different from that of the bench shown 
in the photograph, and is intended to furnish any current up to 
about 30-36 amperes. This type of bench has several advantages. 
Ist. It occupies a minimum amount of floor space. 
2nd. Any number of batteries from 1 to 32 may be charged at 


Fig. 60. Double Charging Bench 


the same time. Any battery may be disconnected from the charg- 
ing circuit by throwing up the knife switch for that battery. 
This will allow the other batteries to continue charging. 

3rd. To each switch are attached two 18 inch flexible, No. 8 
rubber covered wires, each of which has a hold-fast clip at the 
free end. These clips are snapped on the battery posts in an 
instant. This arrangement does away with the unsightly, time- 
consuming, inefficient method of tying batteries in series with any 
“odd bits of wire which may be at hand, and after you once use 
this bench, you will never go back to the old, untidy, haphazard 
way of charging. 

4th. The elevated shelf extending down the center of the 
bench is convenient for holding jars of distilled water, chalk for 


THE WORKSHOP.: GENERAL INSTRUCTIONS 115 


marking on the battery what is to be done with it, such as, 
1 D.C. for one dead cell, R.B. for rebuild, R.S. for reseal, ete. 
The hydrometer may also be kept on the shelf. 


HW 


L668 6 
3-9: 


BATTERY DOUBLE CHARGING BENCH 


. 2 
6 
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| a 
3 hes t—+ | i 
5 * ow | \ 
. a} NI | U1 «1 
4 iw | E 8 
b to 
é ae ® | o La 
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14 ty | 
(< S 
Hea}? 0) 
. \e +—-+ | 
< ls i 
Fie I\ ° 
$ |i 4 | 
; 
% ito 


Figure 61 shows the various dimensions in sufficient detail to 
enable you to build the bench. Give each part a coat of asphal- 
tum paint before assembling the bench. When you have the bench 
assembled, give it two coats of hot asphaltum paint, being care- 


116 THE AUTOMOBILE STORAGE BATTERY 


ful to thoroughly cover all parts. If you want to charge more 
than 32 batteries at one time extend the bench so as to make it 
wider, and add more switches. 

To do this use lumber of the same thickness as the top, and 
twelve inches wide. Brace with two by fcurs nailed to the side 
of the bench. 


+32: 
rh 


Fig. 62 


Figure 62 shows the wiring diagram, using 36 thirty-two 
candle power, carbon filament lamps. These give one ampere each 
on 110 volts. Other sized lamps may be used, depending on the 
amount of current desired. The switches shown at A, B, C, D,E 
and F control the various groups of lamps. These may be the or- 
dinary 10 ampere snap switches, or 10 ampere, single pole, single 
throw knife switches. Any current from 1 to 36 amperes may be 


THE WORKSHOP. GENERAL INSTRUCTIONS 117 


obtained in one ampere steps by turning on one or more of these 
switches as needed. The snap switch covers should be dipped in 
hot asphaltum paint, and the current carrying contacts covered 
with vaseline or grease. 

The board carrying the lamps should be mounted at one end of 
the bench, as shown in figures 60 and 61. 1t should be of one-inch 
stock, which has been given two coats of asphaltum paint. The 
porcelain sockets should be the ‘‘Edison cleat receptacle’’ or of 
similar design. These sockets have two screw holes in front for 
fastening to the board. They also have the binding posts in front. 
The wire connections for the whole board should be made on the 
front. For the connections to the sockets, use No. 12 rubber cov- 
ered wire. For all other connections, including the two feed wires 
to the battery switches on the bench, use No. 6 rubber covered wire 
or cable. No. 10 wire may be used if the No. 6 cannot be obtained. 
Keep all metallic parts covered with vaseline or grease to prevent 
corrosion from acid fumes. 

The double pole, double throw switch with fuse extensions 
should have a -capacity of 50 amperes. This may be bought 
mounted on a slate base, or the various parts may be bought un- 
mounted, and then mounted directly on the board. Use 50 am- 
pere enclosed fuses or 50 ampere fuse links for this switch. The 
lower studs are to be used for an auxiliary source of power, such 
as a rectifier, motor generator, or a shop dynamo driven by a gas 
or gasoline engine. These will be described later. The ammeter 
should be of the round, iron-clad switch board type, with a scale 
reading up to 50 amperes. The connections to this meter will 
probably have to be made in back of the board. 

Terminals M, N, and O are provided for the purpose of 1 using 
the lamp bank for tests on anything in other parts of the shop 
which may require an adjustable current. If two wires are at- 
tached to terminals N and O, the current will first pass through 
the lamps, and it may be adjusted to any value within the range 
of the lamp bank. If the wires are attached to M and 0, the full 
line voltage will be available for test purposes. The binding posts 
on the board should be made of heavy brass, with knurled heads 
about three-fourths of an inch in diameter. 

Instead of lamps, you may use Ward Leonard Enameled Re- 


118 THE AUTOMOBILE STORAGE BATTERY 


sistance Units, ‘‘EB’’-size. These are fitted with standard Edison 
bases for screwing into the lamp bases. These units are made in 
various capacities from 0.24 to 71 amperes each. The units listed 
as EB 90 will each give approximately one ampere, which is the 
current obtained through one 32 candlepower, carbon filament 
lamp. 

If you can afford it, make two lamp and switch boards, putting 
oue at each end of the bench, and connecting sixteen of the battery 
switches to each board. Such a bench is more useful than one 
having only one lamp board and charging line. The reason is 
that the majority of batteries have a ‘‘starting’’ and a ‘‘finishing’”’ 
rate of charge. That is, when these batteries are first put on 
charge, a rather high rate is used until the cells are gassing. 
Then, the current is lowered to the ‘‘finishing’’ rate. All bat- 
teries in the charging line will not in general begin to gas at the 
same time, because the internal condition varies among the bat- 
teries, and some will begin to gas much more quickly than others. 
Since the current must be reduced in the gassing cells, it is con- 
venient to disconnect these batteries from the line which is still 
carrying the ‘‘starting’’ current, and connect them to a second 
line carrying the ‘‘finishing’’ current. 

The pivot screws, switch blades, spring contacts the blades enter 
should be kept covered with graphite and oils or vaseline to keep 
them from corroding from the acid fumes. For the same purpose, 
the hold-fast clips, after they are connected to the drop cord or 
flexible wire should be dipped in hot thin asphaltum paint together 
with several inches of the drop cord to keep them from being 
attacked by acid. It is well to make up a few extra cords 18 
inches or 2 feet long, with hold-fast clips at each end, as they are 
handy in connecting two or more batteries in series and in paral- 
leling batteries. It is well to make two charging benches while 
you are at it, instead of just one, and not mount the center shelf 
on one of them until really needed, but use the bench as a con- 
venient place to keep charged batteries. Always keep your bat- 
teries in an orderly way on this bench, and whenever you put 
one on it, be sure and have the positive end in so that the tag, 
which should always be attached to the negative handle, will hang 
out. Then you can readily find any battery you are looking for. 


THE WORKSHOP. GENERAL INSTRUCTIONS | 11 


In Figures 63 and 64 are shown the wiring diagrams for othe 
charging boards to be used on a 110 volt, direct current circuit. 


9 


r 


The connections shown may be made by any automobile repair- 
man or by any electrician. In Figure 63 the necessary resistance 


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Sux eke 
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fh A maw 8 
ree “~ Q 

\ = . De 
Q GX ~ 
HQ <u es 
#2 fa eh Q 
meat LE t 
ce ox PE x 
HEES FO Q 
AHR AN Go 


TEITIIT eee 


Ke 
NR 
HN y + 
ay: 
eet 7 
~ 3 { wu Y 
G Sku @: 
§ GEN EVA 
oa + 
N = : 
SE etal 


Fig. 63. Another Type of Charging Board 


is supplied by means of five banks of incandescent lamps, one 
bank carrying two bulbs, one carrying four and the remaining 
three carrying eight bulbs, each. At the left is shown a double 
Pole, single throw knife switch of 25 amperes capacity to one side 


Oo 


120 THE AUTOMOBILE STORAGE BATTERY 


of which the supply line is attached. From one blade on the other 
side of the switch a line leads to one side of each of the lamp 
banks, and from the other blade a line leads through the ammeter 


w 
= 
z 

= o% 

x -2 
wor Ky 
De wy oH “* sf 
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MEK vse @ 
<8 x 
& ny A ua) 
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movi st f 
Frigg ra § 

" (MOREA Ay O 


Fig. 64. Resistance Coils for Charging Batteries 


9 


le 
‘teh 


iN 


54m peres 


Throw Knife S, 


rf Double Pole Sin 


M0 belts OC 


7) 


to the bus-bar shown at K-L-M-N-O. From the other side of lamp 
bank number 1 a wire leads to the single pole, single throw, 29 


ampere knife switch which carries a 20 ampere fuse, this switch | 


being marked E. From the bank of four lamps a line leads to a 


| 
| 
| 
| 


THE WORKSHOP. GENERAL INSTRUCTIONS 121 


similar switch, F, and from the banks of eight lamps each, lines 
lead to the switches G, H and J. These lines may be connected 
with each other by means of the single pole, single throw, 25 
ampere knife switches A, B, C and D. Batteries to be charged are 
attached between the fused switches and the bus-bar at the points 
marked V, W, X, Y and Z. 

Carbon bulbs of 50 watt or 16 candle power capacity should be 
used in each of the thirty lamp sockets. One bulb of this size 
allows a current flow of approximately 14 ampere. ‘With the 
arrangement shown, batteries of five different ampere-hour ca- 
pacities may be charged at the same time, each capacity at its 
proper amperage. The various amperages may be obtained ac- 
cording to the following instructions, all switches being left open — 
except those you are directed to close. The main line switch 
should, of course, be closed for all the combinations given: 


1 ampere—Attach battery at V, close switch E. 

2 amperes—Attach battery at W, close switch F. 

3 amperes—Attach the battery at W and close switches A, E, 
and F’. | 

4 amperes—Attach the battery at X, Y or Z and close switches 
G, H or J, respectively. 

5 amperes—Attach the battery at X and close switches A, B, E 
and G.. | 

6 amperes—Attach the battery at X and close switches B, F 
and G. 

7 amperes—Attach the battery at X and close switches A, B, H, 
F and G. 

8 amperes—Attach the battery at Y and close switches C, G 
and H. . 

9 amperes—Attach the battery at Y and close switches A, B, C, 
BE, G and H. 

10 amperes—Attach the battery at Y and close switches B, C, F, 
G and H. 

11 amperes—Attach the battery at Y and close switches A, B, C, 
E, F, G and H. 

12 amperes—Attach the battery at Z and close switches C, D, G, 
H and J. 


e 


122 THE AUTOMOBILE STORAGE BATTERY 


13 amperes—Attach the battery at Z and close switches A, B, C, 
D, E, G, H and J. 

14 amperes—Attach the battery at Z and close switches B, C, D, 
F, G, H and J. 

15 amperes—aAttach the battery at Z and close all switches. 


With the positive and negative wires connected as shown, the 
positive terminals of the battery should always be connected to 
the bus-bar and the negative terminals to the switch leads. In 
case it is desired to charge two or more batteries requiring the 
Same current they should first be placed in series with each 
other by connecting the positive terminal of one to the negative 
terminal of the next one, thus leaving one positive and one nega- 
tive terminal, the positive to be connected to the bus-bar and the 
negative to the switch lead. It will be seen that this method 
allows you to handle any number of batteries at any rate of charge 
from one to fifteen amperes. For connecting batteries in series in 
this way, make about two dozen lengths of No. 12 flexible lamp 
cord, each about one foot long, and having a ‘‘hoid-fast’’ snap on 
terminal on each end. By using 100 watt or 32 candle power bulbs 
with carbon filaments the charging rate will be exactly doubled 
for each connection; that is, where one ampere was given two will 
be secured, where two amperes were given four will be secured, 
etc. In this case the switch and fuse capacities must be doubled. 

In Figure 64 is illustrated a system similar to that described 
with the exception that coils of resistance wire are used in place 
of the lamp banks. The conneetions for various currents will be 
exactly the same as in the lamp system and the explanation using 
the reference letters will be the same in all particulars. The coil 
windings from number one to number five may be made up as 
follows: 


Coil 1—With German Silver wiring, 75 feet of 28 gauge. With 
Nichrome wiring, 30 feet of 28 guage. 

Coil 2—-With German Silver wiring, 38 feet of 28 gauge. With 
Nichrome wiring, 15 feet of 28 gauge. 

Coils 3, 4 and 5—With German Silver wiring, 19 feet of 28 gauge. 
With Nichrome wiring, 8 feet of 28 gauge. 


— 


. ee 
THE WORKSHOP. GENERAL INSTRUCTIONS 123 
‘Motor-Generator Sets. 


Small motor-generator sets with control panels may be pur- 
chased from any of the larger electrical manufacturers and supply 
houses. A list of such companies is given in Chilton’s Automobile 
Trade Directory. In selecting a motor-generator set, the voltage 
of the supply circuit, the maximum and minimum charging rates, 
the voltage of the batteries, and the number of batteries to be 
charged at one time determine the size and type of the motor and 
generator. The current which the generator is capable of deliver- 
ing depends upon the maximum and minimum charging rates. 
The charging rates recommended by battery manufacturers vary 
from a minimum of about 3 amperes to a maximum of approxi- 
mately 25 amperes. The average length of time required for a 
normal complete charge varies from eight.to twelve hours, but in 
charging sulphated batteries, a much longer time, at a low rate 


is required. The charging voltage is from 2.6 to 2.7 volts per cell. 


| 


Multiplying this by the total number of cells in the batteries which 
are to be connected in series on the charging circuit gives the. 


' generator voltage. 


The motor-generator sets include the necessary voltmeter, am- 
meter, and rheostat. Motor and generator shafts are coupled di- 
rectly together, and are mounted on solid timbers. The meters 
and rheostat are usually mounted on the frames of the two 
machines, and the entire set may be mounted on a bench. Charg- 


ing eurrent is regulated by varying the generator voltage with 


the rheostat, which changes the resistance of the generator field 
circuit. | 
Mercury Arc Rectifier. 


The operation of the mercury arc rectifier depends upon the 
fact that a tube containing mercury vapor under a low pressure 
and provided with two electrodes, one of mercury and the other 
of some other conductor, offers a very high resistance to a current 
tending to pass through the tube from the mercury electrode to 
the other electrode, but offers a very low resistance to a current 
tending to pass through the tube in the opposite direction. The 
low resistance offered when the current tends to pass through the 


124 THE AUTOMOBILE STORAGE BATTERY 


tube toward the mercury electrode depends upon the formation 
of an arc in the tube by tilting it so the mercury bridges the gap 
between the two electrodes just for an instant, as will be explained 
more fully later on. 

Mercury arc rectifiers find their chief application as a means 
of charging storage batteries. They are used to some extent in 


SOURCE oF 
| ALTERNATING CURRENT | 


CONDEN SING 


CHAM BER. 


Fig. 65. Mercury Arc Rectifier 


supplying current to certain types of direct-current are lamps 
from an alternating current supply circuit. Some very large mer- 
cury arc rectifiers have been constructed and used on electric cars 
and locomotives, power being supplied to the car or locomotive 
from a high-voltage alternating current trolley, the pressure 
being reduced on the car or locomotive by means of statie trans- 
formers and then converted into a low voltage direct current suit- 


THE WORKSHOP. GENERAL INSTRUCTIONS 125 


able for the direct current motors. This scheme promises to work 
out quite well with the higher voltage direct-current motors, such 
as 1,000 or 1,200 volt kind. The chief objection to this appli- 
cation of the mercury arc rectifier lies in the difficulty of pro- 
ducing a tube of rugged construction and lasting qualities. 
The outline of a mercury arc tube is shown in Figure 65. It is 
made of glass in the smaller sizes used in charging storage bat- 
teries. It is exhausted to a high degree of vacuum and contains 
a small quantity of mercury in the bottom. The upper part of 
the tube is used only as a condensing chamber wherein the heated 
mereury-vapors are cooled and condensed so they may again settle 
at the bottom. The cathode, or negative electrode is always at 
the bottom and two or more anodes, or positive poles, are arranged 
around the side of the tube. Two anodes are required for a single- 
|phase operation and three for three-phase operation. There is 
tito a small starting electrode, ‘‘C,’’ connected to one side of 
the alternating-current circuit through a resistance and used for 
starting the are. When the rectifier tube is rocked so as to form 
,and break a bridge of mercury between the mercury cathode at 
the bottom and the starting anode ‘‘C,’’ a small are is formed. 
This small are produces mercury vapor in the tube and the are 
immediately jumps to one or the other of the main anodes and 
| then alternates on these during regular operation. 
The operation of the mercury arc rectifier may be analyzed as 
follows: Let us assume an instant where the point ‘‘A’’ is posi- 
' tive and the point ‘‘B”’ is negative in Figure 65. Current will then 
flow from anode ‘‘1’’ at the left to cathode ‘‘2,’’ through the load 
‘“‘L,’? which in this case is a storage battery,through the reactance 
‘“Rl,”’ and back to the negative terminal of the source at ‘‘B.”’ 
The current cannot jump from anode ‘‘1’’ to anode‘‘3’’on account 
of the high counter-electromotive force of the are. The full line 
arrows show the direction of the current for the half cycle of the 
alternating current wave when the terminal ‘‘A’’ is positive and 
the terminal ‘‘B’’ is negative. During the next half cycle the 
terminal ‘‘B’’ is positive and the current flows from ‘‘B’’ to the 
anode ‘‘3,’’ to the cathode ‘‘2,’’ through the load ‘‘L,’’ and the 
-yeactance ‘‘R,’’ back to the negative terminal of the source 
which in this case is the terminal ‘‘A.’’ The dotted arrows show 


126 THE AUTOMOBILE STORAGE BATTERY 


the path of the current during this half of the cycle. During a 
whole eyele the cathode ‘‘2’’ is continuously negative, but first 
one anode and then the other is active. Should the voltage and 
current become zero at exactly the same time the are would be- 
come extinguished and operation cease. In order to prevent an 


Fig. 66. Wave Form of Mercury Arc Rectifier 


occurrence of this kind the reactances ‘‘R,’’ and ‘‘R,’’ are intro- 
duced. At the end of the first half cycle described above when 
the line voltage has dropped to zero, the reactance ‘‘R,’’ main- 
tains the current and a local circuit is formed through ‘‘R,”’ 
anode ‘‘1,’’ cathode ‘‘2’’ and load ‘‘L,’’ which maintains the are | 
until the voltage at ‘‘B’’ has increased to a value.that will main- 


THE WORKSHOP. GENERAL INSTRUCTIONS = 127 


tain the are. The rectifier thus makes use of both half waves, or 
the entire alternating current, and the result is quite a uniform 
pulsating unidirectional current. On account of the reactance in 
the circuit the current in the load never falls to zero value and, 
in fact, with sufficient resistance, may: be made very nearly con- 
stant. This condition is not always desirable as it produces a 
very bad distortion of the alternating current wave. 

The general form of the waves produced by a mercury are 
rectifier are shown in Figure 66. The upper wave represents the 
alternating voltage wave. . 

The second and third waves are those of the currents in the 
two positive electrodes. The fourth wave is a combination of 
the second and third and it represents the current in the load 
“¢T.?? . 

At present mercury arc rectifiers are generally used with auto- 
transformers, and these transformers are. usually designed in such 
a manner as to make the reactances ‘‘R,’’ and ‘‘R,,’’ as shown 
in Figure 65 unnecessary, sufficient reactance being provided in 
the auto-transformer to accomplish the desired results. A proper 
proportion of reactance may be made to stop the action of the 
rectifier when the current falls to a certain value. This arrange- 
ment is particularly useful in connection with storage battery 
charging. 

The resistance ‘‘R’’ connected in series with the starting elec- 
trode ‘‘C,’’ as shown in Figure 65, is to prevent an excessive cur- 
rent passing through the circuit when the tube is tilted for start- 
ing. 

The temperature of a tube must never be allowed to rise too 
high as the life of the tube is greatly reduced. Some of the 

larger-tubes are immersed in oil to facilitate cooling. The vacuum 
in the tube may be tested by removing the tube from its supports 
and shaking it, if the vacuum is good, the mercury will give out 
a metallic sound. If the tube is dirty on the inside and there is 
a tendency for the mercury to stick to the sides, the vacuum is 
poor. | 

An average life of over 600 hours is claimed for the sizes com- 
monly used in charging the batteries in electric automobiles and 
in some cases a useful life of 5,000 hours has been obtained. The 


128 THE AUTOMOBILE STORAGE BATTERY 


average life of small tubes used in charging ignition batteries is 
much greater. 

The efficiency of the rectifier varies with the voltage used on 
the direct-current side, as there is always a drop in voltage 
through the mercury vapor, which is practically independent of 
the current used. For rectifiers of 30 to 50 ampere capacity, the 
drop in voltage across the rectifier terminals is equal to about — 
15 volts. The lower the direct-current voltage therefore, the | 
greater the percentage of loss. This loss is in addition to the 
losses in the auto-transformer and brings the average efficiency | 
down to 75 or 80 percent for a direct current voltage of about 
80 volts. 

When used for charging storage batteries, rectifiers require 
considerable variation of the direct current voltage, and for this 
reason are usually provided with variable reactance in the pri- 
mary circuit of the transformer, also with taps in the secondary 
winding. They are, as a rule, specially designed for the class of 
work for which they are intended. 


The Electrolytic Rectifier. 


nesourceorenercy The action of the Electrolytic Rectifier is ex- 
plained by the fact that certain electrolytic 
, cells having electrodes of different metals will 
allow a current to pass through them in one 
direction only. Thus, if a plate of iron and 
a plate of aluminum be immersed in a solution 
of ammonium phosphate as shown diagrammat- 
ically in Figure 67, and the two plates con- 
nected to a source of alternating current, the 
following results will be obtained. 
The alternating pressure between the termin- 
als A and B tends to send a current through the cell first in one di- 
rection and then in the other direction, and if the resistance of the 
cell was independent of the direction of the current, there would 
be an alternating current produced and this current would be rep- 
resented by a curve of the form shown in Figure 68, with the dis- 
tance of the curve above or below the line MN corresponding to the 
value of the current, the current being in one direction when it is 


Fig. 67 


THE WORKSHOP. GENERAL INSTRUCTIONS = 129 


above the line MN and in the opposite direction when it is 
below the line MN. There is, however, quite a high resistance of- 
fered by the electrolytic cell when an attempt is made to send a 
current through it in a direction from the aluminum to the iron 
plate, and as a result of this high resistance te the current, there is 
in reality practically no current through the cell in one direction 


Fig. 68 


Fig. 69 


as compared with the current through it in the opposite direction. 
This results in the current curve being of the general form shown 
by the full line in Figure 69. The dotted line represents the 
part of the current curve shown in Figure 68, which must be 
reduced to zero by the action of the electrolytic cell. . 
This resistance offered by the cell is sup- 
' posedly due to a-high resistance film being 
formed at the surface of the aluminum when 
the current is in a direction from the alumi- 
num to the electrolyte or iron plate. In the 
case just described, use is made of the avail- 
able pressure just one-half of the time and 
hence there is current in the circuit only half 
of the time. A storage battery connected in 
such a circuit could not be charged very sat- 
isfactorily or efficiently. 
A better arrangement of the cell may be made as shown 
diagrammatically in Figures 70 and 71. Two aluminum plates 


Fig. 70 


130 THE AUTOMOBILE STORAGE BATTERY 


are used instead of one and they are connected to the| 
source of alternating current through a choke coil as shown in 
Figure 71. The operation of this arrangement may be followed 
briefly, as follows: Let us assume there is a current in the alter- 
nating current line in the direction indicated by the arrows 
marked 1 and 2. The current meets with a high opposition in | 


Fig. 71 


trying to pass from the left-hand aluminum plate to the iron 
plate and as a result, the current in this circuit is practically zero. 
There is, however, a path of relatively low resistance from 
the point A to the point B through the battery to the iron plate 
through the cell to the right-hand aluminum plate and then to 
the point C. As a result of this current passing through the 


zi 


\ / 


Fig. 72 


\ 
choke coil from the point A to the point B, there will be a current | 
induced, due to transformer action, in the part of the winding | 
between the points B and C, and its direction will be from the | 
point C toward the point B where it combines with the current 
from the point A, and gives the total current through the battery. 


This results in the current in the battery being 10 amperes when 


THE WORKSHOP. GENERAL INSTRUCTIONS 131 


the current in each of the two sections of the choke coil is approx- 
imately 5 amperes. 

Now when the current in the alternating current circuit re- 
verses, there will be no change in the direction of the current in 
the two sections of the choke coil, but both will still be toward 
the point B and through the battery, which results in the battery 
current being of the general form shown in Figure 72. The 
dotted section of the curve which was wiped out entirely by the 
arrangement shown in Figure 67, is now reversed in the direction 
relative to the other loops of the current curve and as a result, 
all of the loops are now in the same direction, which gives a much 
better charging current for the battery. 

If the electrolytic cell is to be self cooling, the aluminum plates 
should be of such a size that there are about 7 square inches of | 
surface per ampere direct current, and the iron plate should be 
at least twice this size and better still if it is three times the area 
of the aluminum plates. The distance between the aluminum 
plates should be about. one-half inch. The containing vessel 
should be of such a size that there is approximately one square 
foot of radiating surface per ampere direct current. An ordi- 
nary granite-ware bucket may be used as a containing vessel. 
The plates may be mounted on one-half inch strips of wood of 
ample length to reach across the top of the containing vessel. 
The dimensions of the plates may be made such that they will best 
fit in the containing vessel and small ears may be left on their 
corners to be used in attaching them to the wooden supporting 
strips. The electrolyte should consist of a saturated solution of 
pure neutral ammonium phosphate. The size of the plates and the 
volume of the electrolyte required to fill the large containing 
vessel in order to give ample radiating surface may be greatly 
reduced by using some artificial means of cooling. Cold water 
may be circulated through pipes placed in the electrolyte or the 
electrolyte itself may be made to circulate through outside cool- 
ing coils. 

The direct current voltage is roughly one-half of the alternat- 
ing current voltage and this relation is not fixed but depends upon 
the temperature of the electrolyte and the condition of the sur- 
face of the plates. mo 


132 THE AUTOMOBILE STORAGE BATTERY. 


With the arrangement shown in Figure 71, it will be necessary 
to reduce the direct current voltage in order to charge a six-volt 
battery, if the source of alternating current is a 110-volt circuit. 
This reduction can be made by means of a resistance in series 
with the choke coil, or better still, by means of a small trans- 
former with several secondary taps so that current at sev- 
eral different voltages may- be taken from the secondary 
winding. A resistance may be placed in series with the battery 
and the charging current regulated by varying the amount of this 
resistance. The transformer is, of course, the most efficient means 
of bringing about the desired voltage reduction. 

The construction of the choke coil will depend upon whether 
it 1s to be connected directly to the 110-volt circuit or to the 
secondary terminals of a transformer. If used directly connected 
to the alternating current circuit, it may be made by winding 
300 turns of No. 18 B. & S. cotton covered wire on an iron ring 
5) inches in diameter. This iron ring may be made by winding a 
quantity of small soft iron wire in a form until the area of the 
cross section of the ring is about % sq. in. 

Remember that your direct current is not steady in value and 
as a result direct-current and alternating current instruments 
will not indicate the same value of current, as the direct-current 
instrument gives an indication of the average current and the 
alternating current instrument gives an indication of the effective 
current. 


Other Charging Equipment. 


If there is no electric lighting in the shop, it will be necessary 
to install a generator and a gas, gasoline, or steam engine, or 
a water-wheel installed to drive it. The generator should, of 
course, be a direct current machine, and large enough to furnish 
lights for the shop in addition to charging the batteries. The 
size of the generator will depend upon the average number of 
batteries to be charged, and the amount of money available. 
Any of the large electrical manufacturers or supply houses will 
give any information necessary for the selection of the type 
and size of the outfit required. 


THE WORKSIIOP. GENERAL INSTRUCTIONS — 133 


If an old automobile engine, and radiator, gas tank, etc., are 
on hand, they can be suitably mounted so as to drive the gener- 
ator. 


Discharge Board. 


It is often desirable to make discharge tests on a battery. A 
good way to determine the condition of the battery is to draw 
current of several values from it, and then measure the battery 


HEAVY CABLES FOR ATTACHING TO BATTERY 


WIRING FOR DISCHARGE BOARD 
Fig. 73 


voltage and the number of ampere hours it will deliver before 
discharged. ‘Trouble in a battery or cell is indicated by its 
voltage dropping to a low value while the current is passing 
through it. If it is desired to draw a current of approximately 
100 amperes from a 6-volt battery, a special resistance is neces- 
sary. For this purpose, four feet of No. 4 Nichrome wire may 


134 THE AUTOMOBILE STORAGE BATTERY 


be used. Mount this on the discharge board, fit it with terminals, 
and attach two cables to it which may be connected to the bat- 
tery which is to be tested. Measure the voltage of the battery 
while discharging it through the Nichrome wire. 

Another use of the discharge board is in conection with charg- 
' ing and discharging a battery which has been badly sulphated. 

Figure 73 shows the wiring for the discharge board. The size 
and type of resistances or lamps is shown. To discharge a bat- 


80 FT. OF N23 
{RON WIRE 


DISCHARGE BOARD 


Fig. 74 


tery,-snap a pair of the hold-fast clips on the battery terminals, 
throw the double-pole switch for that battery down, and throw 
all other double-pole switches up. Then throw the snap switches 
on so as to obtain the desired discharge. The drawing shows 
eight switches, for discharging eight batteries in series, or any 
number from one to eight. 

For the bench, use the dimensions of Figure 61, but make the 
length six feet instead of sixteen. 

A simpler discharge resistance is shown in Figure 74. The 


: 
™ 


THE WORKSHOP. GENERAL INSTRUCTIONS = 135 


terminal on the end of the cable attached to the right hand bat- 
tery post is movable, and may be clamped on any part of the 
resistance wire to obtain various currents. A detail of the termi- 
nal is shown at the right in figure 74. | 


Tools and Equipment. 


Do not attempt to handle battery repair work until you have 
provided yourself with the proper tools. A good workman with 
poor tools cannot do better work than an average workman with 
good tools. The tools listed below are those recommended by 
three of the largest battery manufacturers in the United States. 

Tools recommended and sold by the U.S. Light and Heat Cor- 
poration of Niagara Falls, New York: 

- (1). Gas still for distilling water, in capacities of 14, 1, and 
0 gallons per hour. 
(2). Plate burning rack for holding connecting strap and plates 
while burning. 
(3). A plumber’s or tinner’s triangular scraper for scraping 
posts, lugs on plates, ete. | 
(4). Steel wire brush, for cleaning terminals, etc. 
(5). Putty knife for removing sealing compound. 
(6). Two combination pliers for pulling out elements, etc. 
(7). One pair long flat nosed pliers for pulling out jars and 
Separators. 
(8). One pair end cutting nippers for cutting connectors, posts, 
plates, lugs, ete. 
(9). One coarse bastard file for cleaning lead parts, and a file 
brush. 
(10). One ladle for sealing compound. 
(11). One Syringe hydrometer for measuring specific gravity, 
drawing off electrolyte, or adding distilled water. 

(12). One lead lined acid box, 24 inches by 36.inches by 24 
inches high, for storing acid or separators. 

(13). Bottle of 1.800 Specifie gravity electrolyte. 

(14). Bottle of 1.400 Specific gravity electrolyte. 

(15). Rods of lead-antimony for burning plates to straps. 

(16). Rods of pure lead for burning in top connectors. 


136 THE AUTOMOBILE STORAGE BATTERY 


(17). Sealing compound. 

The above list of tools may be obtained by communicating with 
the U.S. L. factory at Niagara Falls, New York. 

The next list is that recommended by the Gould Battery Com- 
pany: 

(1). 1 pair rubber gloves, to protect the hands from acid. 

- (2). 17-inch end cutting nippers, for cutting connectors, posts, 
plate, lugs, ete. 

(3). 2 combination pliers, for pulling elements, ete. 

(4), 1 triangular lead scraper, for. scraping burning lead, 
plate lugs, ete. 

(5). 1 putty knife for removing sealing compound. 

(6). 1 4-inch wood chisel for removing sealing compound. 

(7). 1 5-inch screw driver for removing sealing compound and 
covers. 

(8). 1 single end wrench for removing taper terminals. 

(9). 1 10-inch file and handle, for filing plate lugs, lead, ete. 

(10). 1 steel wire brush, for cleaning terminals, ete. 
_ (11). 1 ball point hammer for general work. 

(12). 1 10-inch ratchet brace, for drilling connecting links 
loose som posts. 

(13). 1 5g-inech bit stock drill for removing . 5g-inch connect- 
ors. 

(14). 1 %-ineh bit stock drill for removing Y%-inch connect- 
ors. 

(15). 1 center punch, for centering terminals to drill. 

(16). 1 adjustable hack saw frame for general work. 

(17). 3 hack saw blades, 8 inches, for the above. 

(18). 1 Iron ladle for pouring sealing compound. 

(19). 1 pair blue glasses, for use when operating burning 
outfit. : . 
(20). 1 soft rubber bulb syringe, for flushing and equalizing 
electrolyte. 

(21). 1 steel file brush for cleaning lead parts and file. 

(22). 1 burning rack with extra guides, for holding plates and 
connecting straps in place while burning. . 

(23). 1 hydrometer for mixing electrolyte. 

(24). 1 thermometer to determine the temperature of the cell. 


{ 
{ 
| 


THE WORKSIIOP. GENERAL INSTRUCTIONS — 137 


- (25). 1 lead burning outfit. 

Prices on above repair kit in box, including burning rack with 
one spacing guide, but not including lead burning outfit, $17.85 
fF. o. b. Depew, New York. Price in force November, 1917. 

The Willard Storage Battery Company of Cleveland, Ohio, rec- 
ommends the following tools and equipment: 

(1). 1 lead burning outfit. 

(2). Carboy of Sulphuric Acid for generating gas for lead 
burning outfit, and for making electrolyte. 

(3). Granulated Zine for making Hydrogen Gas for lead burn- 
ing outfit. 

(4). Burning rack for holding connecting strap and plates 
while burning. 

(5). 2 pairs Gas pliers for removing top connectors, taking 
out elements, etc. 

(6). Pair of flat nose pliers for removing jars and separators. 

(7). A plumber’s or tinner’s triangular scraper for scraping 
posts, lugs on plates, ete. 

(8). A putty knife for removing the sealing compound from 
between the top and inside covers; also the excess on top, around 
outside and between covers. 

(9). An 8-inch screw driver for removing compound, or a 
14-inch wood chisel. 

(10). A ten-quart iron kettle for melting sealing compound. 

(11). A long handled ladle with extra large spout for pouring 
sealing compound. 

(12). Single burner gas stove for heating sealing compound. 

(13). A porcelain pitcher for handling and pouring sulphuric 
acid and electrolyte. 

-(14). A 10-Ib. bundle of lead and antimony burning bars for 
burning plates to connecting straps. 

(15). A 10-Ib. bundle of pure lead burning bars for burning in 
top connectors. 

(16). Brace and 34-inch drill for drilling out top connectors 
and terminal posts. 

(17). Hydrometer Syringe for testing specific gravity of solu- 
tion in battery cells. 

(18). Lead funnel for filling batteries. 


138 THE AUTOMOBILE STORAGE BATTERY 


(19). Aluminum nipple for holding tapered connectors while 
burning in cable. This is to prevent cable from becoming too 
hot. One end is tapered to fit positive, and one to fit negative 
terminal. 

(20). Gas still for distilling water for refilling batteries and 
making electrolyte. 

(21). Wire brush for cleaning off top of connectors after they 
are burned in. | 
- (22). Wood form with holes to fit over posts while pressing 
down the top covers with a heavy weight. 

- (28). Sealing Compound. 

(24). Dairy thermometer for measuring temperature of elec- 
trolyte. 

(25). Hand punch for punching out connector straps where 
plate lugs have been broken off. 

(26). Iron nipple made from a piece of gas pipe 1 inch long, 
reamed out with a tapered reamer so that large end fits over top 
of post which has been drilled off. 

(27). Lead lined wooden tank for storing wood separators. 
Should also have a second tank for mixing electrolyte. 

(28). Lead cup for soldering acid. (A glass bottle or jar will 
serve the purpose equally well, although more easily broken.) 

In addition to these tools and equipment recommended by the 
above manufacturers, the following will be found very useful: 

(1). Gasoline torch. 

'*(2). Two-way burner if natural or ordinary ituminating gas 
is used for lead burning. 

(3). Screw drivers: 

Two with 10-inch blades. 
One with 8-inch blade ground rather narrow. 
One with small 6-inch blade. 

(4). Several wood chisels, 14 to %4-inch wide. 

- (5). Pieee of 1-inch angle iron about 8 inches long to place 
on top edge of battery when prying off the covers with screw 
drivers. 

(6). Several old stew pans to be used for boiling connectors in 
soda water to remove acid. : 

(7). Coffee pot for heating and pouring compound. 


THE WORKSHOP. GENERAL INSTRUCTIONS 139 


(8). A number of pieces of wood %-inch thick, 144 inches wide, 
nd just long.enough to fit between the handles of the various 
ized batteries. 

(9). Metal stamps for stamping date, repairman’s initials, and 
‘+7? and ‘‘—” or ‘‘P”’ and ‘‘N”’ on top connectors. 

- (10). Cans of asphaltum paint for painting battery boxes, 
vork bench, ete. 

-(11). Plate press for straightening buckled plates, and for 
‘oreing bulged active material back into the grids. (See page 142.) 

(12). Steam boiler and steaming box for softening sealing 
sompound preparatory to opening battery. (See page 140.) 
>> (18). Molds for making burning lead. (See page 146.) 


Fig. 75. Handy Boxes for Keeping Covers, Plugs, Connectors, Ete. The Smaller 
Boxes are Horseshoe Plug Tobacco Boxes 

(14). Battery turntable, to be used when painting battery, 
burning on the top connectors, pouring compound, ete. (See 
page 144.) 

(15). Two pairs bent nose pliers. 

(16). A good pocket knife. 

(17). Lead pencil, and chalk for marking batteries. 

(18). Monkey wrench. 

(19). Clean Rags. 

(20). For convenience in keeping track of tops, stoppers, wells, 
connecting and terminals, you should procure a number of shallow 
boxes, as shown in figure 75. A card holder should be placed 
on one end. The name of owner of battery, also diagram of 
connections of batery and date letter or number are to be put on 
the ecard. With this card in holder, no mistakes are likely to 
occur. These boxes should be 12 inches long, 8 inches wide, and 


140 THE AUTOMOBILE STORAGE BATTERY 


4 inches deep. Gather up the long lead drillings and put in a box! 
procured for this purpose, about 9 inches by 14 inches by 6 inches 
in size. Figure 75 shows both kinds of boxes. The boxes shown 
at the left may be used if you can get them, and card holder put 
on one end. The box shown at the right is for the lead scraps. li 
you have old battery cases the bottom portions of which ara 
sound, these may be cut down and used for this purpose.. 

(21). The large Exide vehicle hydrometer, type V-2A, is a 
most excellent one for general use: It has a round bulb, straight 
barrel, with projections on the enlarged portion of the float which 
make the latter keep an upright position when taking readings 
of specific gravity. This eliminates the annoying sticking of the 
float to the sides of the barrel. This hydrometer may be obtained 
from the Electric Storage Battery Co. 


The Battery Steamer. 


The Battery Steamer is an apparatus for softening the sealing 
compound on starting and lighting batteries, by means of steam, 
so that the battery-may be opened easily and quickly, and with- 
out the use of a gas flame or blow torch. It consists of only three 
parts, as shown in Figure 76: 

1. The Steam Generator. 

2. The Steaming Box. 

3. The Water Supply Tank. . 

When a battery is to be opened, the connectors are first re- 
moved and the battery then placed in the Steaming Box and 
steam passed into the box for about half an hour. This makes 
the sealing compound so soft that it can be removed readily with 
the point of a screw driver, the entive operation of opening 
the battery being performed within five minutes after the bat- 
tery is removed from the steaming box. 

The Steam Generator, or Boiler, is made of heavy, galvanized 
iron, and furnishes the steam. Water enters the generator 
through the cover which is connected to the Water Supply tank 
by a rubber hose. The amount of water in the generator is al- 
ways the same, and is regulated by the motion of a float. When 
the water reaches a height of about three inches, the float rises and 


THE WORKSHOP. GENERAL INSTRUCTIONS 141 


closes the valve through which the water enters. The generator 
is set on a gas, oil, or gasoline stove, and because of the small 
amount of water in it, steam is produced very quickly. As the 
water boils away, the float lowers, opens the valve, and allows 
more water to enter. Thus the level of the water is maintained 
constant as long as the supply in the tank lasts, and a continuous 
supply of steam is available in several minutes after the heat is 
applied to the bottom of the generator. For the average repair 


Fig. 76. Battery Steamer 


shop, the supply tank need not be filled but once a day, and the 
entire apparatus requires absolutely no attention after the stove 
is once lighted. 

The supply tank is also made of galvanized iron, and is con- 
nected to the generator by means of a small hose: It is placed 
a foot or two higher than the generator so that the water will 
flow into the latter by gravity. The steaming box is a stout 
wooden box, and is steam tight throughout. Steam is introduced 


142 THE AUTOMOBILE STORAGE BATTERY 


through a connection in the cover by a steam hose which le 
to the generator. The box is made acid proof both inside an 
outside, so that it is not damaged if acid should be spilled on it 
accidentally, When the apparatus is assembled, the box is 
placed on the floor, or raised several inches above the floor. The 
batteries are placed in the box, the lid put on, and the repairman 
then does some other work for a half hour or so. At the end of 
this time the battery is lifted out, and the softened compound 
removed with the point of a screw driver. If it is desired to 
remove jars from an ‘old case, the top, plates, and acid are re- 
moved, the jars washed out with a stream of water, and the box 
then placed in the steaming box for fifteen minutes. The jar 
can then be lifted out easily with two pairs of pliers. 

To remove one jar, insert the end of the hose directly in the 
jar, and pack old rags or paper. around the hose to hold the heat, 
or cut a board to fit the top of the jar, and drill a hole in it for 
the hose. | 

If there are any old covers, jars or battery boxes which have 
compound sticking to them, these may also be placed in the 
steaming box and the compound then removed easily with a 
putty knife. A further advantage of this apparatus ‘is that the 
steaming loosens all dirt which may be on the battery box, so 
that it may be wiped off and make the battery look like new, if 
the wood is in good condition. 


The Battery Plate Press. 


Every battery repair shop must have some means of pressing | 
plates, especially the negative plates. In ‘‘pressing’’ plates, tran-— 
site boards of the proper thickness are placed in each space be- | 
tween successive plates, with two boards on the outside of the | 
end plates. The group of plates is then put under pressure, 
either to straighten the plates, or to force the active materials | 
back into the grid, flush with the surfaces of the grids. A large 
majority of negative plates require such pressing, as the most | 
common fault with negative plates is the bulging out of the 
aetive material, thus causing a poor contact with the grids 
and consequently resulting in a loss of battery capacity. 


THE WORKSHOP. GENERAL INSTRUCTIONS 143 


Never put negative plates into service if the active material is 
bulged. Such plates will never give good service, and will cause 
the battery to be sluggish. Always press the active materials 
of such plates back into place. This will give the battery its 
approximate normal capacity, and will lengthen its life. 


Fig. 77. Battery Plate Press 


Many garagemen press battery plates in an ordinary bench 
vise. This is hard on the vise, as acid drops from the plates on 
the iron parts of the vise, which in time become badly corroded. 
and rusted. Such a vise is weak, breaks easily, and grows very 


144 THE AUTOMOBILE STORAGE BATTERY 


stiff and hard to operate. The vise is therefore not well suited 
for this work because it is made of metal. 

The Battery Plate Press, figure 77, is especially designed for 
pressing battery plates, and is so constructed that there is no 
metallic part which can be reached by. acid dripping from the 
plates. A trough is so arranged that the acid which is squeezed 
from the plates is carried off into a drain, and there is conse- 
quently no rotting of the floor beneath the press by dripping 
acid, and no wet, acid covered floor to ruin your shoes and 
clothes. 

A further advantage of the Battery Plate Press is that there 
are no iron parts near the plates from which bits of iron may 
fall on the plates. Iron is one of the greatest enemies of storage 
battery plates, as it ruins them in a short time. Figure 121 shows 
plates which have been disintegrated by. impurities, probably 
iron, since iron is removed only with the greatest difficulty after 
it once comes in contact with a plate. Figure 124 shows negatives 
which need pressing. | 

Three groups of plates may be pressed at once in the Battery 
Plate Press, thus resulting in a considerable saving of time. 
Figure 77.shows clearly the construction of this press. 


The Battery Turntable. 


Every repairman knows that the most disagreeable feature 
of a battery is its weight. No one moves a battery about unneces- 
sarily, especially when it is on the work bench. In cleaning, : 
painting and repairing the case, however, it is. necessary to get 
at all sides of the battery, and the battery must be turned around. 

To eliminate the back-breaking lifting of the heavy battery, 
every repairman should have a battery turntable, as shown in 
figure 78. The turntable is made of two pieces of well seasoned 
hardwood, ten inches long, eight inches wide, and two inches 
thick. The illustrations shows the cast iron fittings which form 
the pivot bearing. Figure 79 shows how the battery is placed 
on the turntable. Thé battery can be turned around easily with 
one hand while cleaning, painting, or repairing the case. The | 
turntable is not fastened to the work bench, and may be taken 
to the battery instead of bringing the battery to it. | 


THE WORKSHOP. GENERAL INSTRUCTIONS 145 


Fig. 78. Battery Turntable 


Fig. 79. Battery on Turntable 


146 THE AUTOMOBILE STORAGE BATTERY 


Every shop should have several of these convenient, time and 
labor saving turntables. 


The Burning Lead Mold. 


In every shop there is an accumulation of scrap lead: from most 
drillings, old connecting straps, old plate straps, and old plates. 
These should be kept in a special box provided for that purpose, 
and when a sufficient amount has accumulated, the lead should 
be melted and run off into molds for making burning lead. 

The Burning Lead Mold is designed to be used for this purpose. 
As shown in figure 80, the mold consists of .a sheet iron form 
which has been pressed into six troughs or grooves into which the 


Fig. 80. Burning Lead Molds, Showing Lead Made in Them. 


melted lead is poured. This sheet iron form is conveniently 
mounted on a block of wood which has a handle at one end, mak- 
ing it possible to hold the mold while hot without danger of 
being burned. A sheet of asbestos separates the iron form from the 


wood, thus protecting the wood from the heat of the melted | 


lead. A hole is drilled in the end of the handle to permit the 
mold being hung on a nail when not in use. The grooves in the 
iron form will produce bars of burning lead 15 inches-long, 5-16 
inch thick, 34 inch wide at the top, and 44 inch wide at the 
bottom. 

The advantage of this type of Burning Lead Mold over a 
east iron mold is obvious. The form being made of sheet iron, 


heats up very quickly, and absorbs only a very small amount of | 


heat from the melted lead. The cast-iron mold, on the other 
hand, takes so much heat from the melted lead that the latter 


THE WORKSHOP. GENERAL INSTRUCTIONS 147 


cools quickly and is hard to pour. Furthermore, this Burning 
Lead Mold is very light and convenient to handle, whereas the 
cast-iron mold is heavy and inconvenient. 

In melting lead scrap, add a pinch of powdered sulphur and 
rosin to the melted lead to purify it. Stir the lead thoroughly, 
' and skim off the surface dirt before pouring in the mold. Be 
careful not’ to heat the lead too hot after.it has melted. If you 
add from 2 to 4 per cent antimony to the melted lead, the finished 
strips will melt more easily, and simplify the burning-in process. 


Tagging Batteries. 


Every battery concern has its system of marking and tagging 
batteries, usually a ecard system or books for making records of 
the work. Some of these systems are complicated and confusing. 
Make your system as simple as possible, but have it complete. 
Then stick to it, and keep it in an orderly, businesslike way. 
There are a few essential items that must be recorded correctly, 
or your whole system will be confusing and worthless. When. 
a battery comes in, and before the driver or owner leaves, be sure 
that you have recorded the following information: 

1. The owner’s name, address, and telephone number if he 
has one. 

‘2. What is to be done with the battery—charged, repaired, or 
rebuilt. | 

3. What the trouble with the battery is (dead cell, box eaten 
by acid, cracked jar, loose top connectors, broken sealing com- 
pound, etc.), and what caused it (trouble in starting, lighting 
or charging circuits; neglect on part of owner; driver left switch 
on, ete. See BATTERY TROUBLE CHARTS). 

Fill out all these items on the tag, and attach the tag to the 
handle near the negative battery terminal. Then record the 
job in a book kept for that purpose, or save the tag as a record. 
A good plan is also to mark with chalk on the battery box what 
the trouble is and what is to be done, such as, 1.D.C. for ‘‘one 
dead cell,’’ R.S. for ‘‘reseal,’’ R.B. for ‘‘rebuilt,’’ ete. 

You are now ready to make repairs, charge the battery or 
open and rebuild it, as the case may be. 


148 THE AUTOMOBILE STORAGE BATTERY 


Figure 81 shows the front and back side of a charging or 
repair tag. Figure 82 shows a set of pigeon holes for tags alpha- 
betically arranged. The top row is for charging or repair tags 
for owners whose names begin with A to G. The next row is for 
rent tags for owners whose names begin with Ato G. The third 
row is for charging or repair tags for owners whose names begin 
with II to N. The fourth row is for rent tags for owners whose 


© 


The Auto Battery Specialists. 


CHARGED 
Any PAIRED 
Battery SEALED 


UILT 


Itemized Cost 


Recharjin§  «--..-1----00Ple 
Electrolyte 
Separators 


Compound 


Fig. 81. Two Sides of Repair Tag 


names begin with H to N. The other rows are similarly arranged 
In pairs, one of a pair for charging or repair tags, and the other 
for rent tags. Unused tags should be kept on hooks near the 
pigeon holes, as shown in figure 82. The top edge of the rows 
for the rent tags should be painted the same color as the rent 
tags. You will notice that one side of the tag, figure 81, per- 
mits you to keep a correct account of material used, trouble 
with battery and what to do with it, and has a space for a bat- 
tery diagram, so that you can place position of terminals and 


THE WORKSHOP. GENERAL INSTRUCTIONS 149 


Fig. 82. Pigeon Holes for Tags 


date mark on it. A sample drawing is shown on the tag. This 
- tag is perforated across the center. The upper part is tied to 
the handle near the negative terminal, and the lower port is kept 


© 


The AutoBattery Specalists 

7068 Phone 
ckeon St 
Tope 


Fig. 83. Rent Tag 


in the proper compartment of the set of 
pigeon holes shown in figure 82. 

Your rent tags should be green, red, 
blue, or some color different from the 


-charging tag, figure 83. A good way to 


keep aluminum or lead rent tags is on 
10 hooks. Tags 1, 11, 21, 31, etc., should 
go on hook No. 1; 2, 12, 22, 32, ete. on 
hook No. 2; 3, 13, 23, 33, ete., on hook 
No. 3. The last figure of a number goes 
on the corresponding hook number. If 
you use aluminum or lead tags, you are 
almost compelled to have a registering 
book to keep track of the numbers, un- 
less you have them in pairs, two of a 
kind, and hang. on racks as above. 
Another plan is to have one set of num- 
bered aluminum or lead tags, and 
attach atag on each battery. Then 


number the paper tags shown in figures 81 and 83, and put 
these in the pigeon holes shown in figure 82. 


150 THE AUTOMOBILE STORAGE BATTERY 
Precautions to be Taken by the Repairman. 


(From bulletin of the Associated Edison Illuminating Companies.) 


1. Do not work on an empty stomach—you can then absorb 
lead easily. 

2. Keep your fingers out of your mouth when at work. 

3. Keep your finger nails short and clean. 

4. Do not chew tobacco while at work. In handling tobacco, 
the lead oxides are carried to your mouth. Chewing tobacco 
does not prevent you from swallowing lead. 

Do. When you leave the shop at night, and before eating, wash 
your face, hands, and arms with soap, and clean your nose, 
mouth, and finger nails. 

6. Do not eat in the repair shop. 

7. Drink plenty of good milk. It prevents lead poisoning. 

8. Use Epsom Salts when constipated. This is very important. 

9. Bathe frequently to prevent lead poisoning. 

10. Leave your working clothes in the shop. 

11. It is better not to wear a beard or mustache. Keep your 
hair covered with a cap. 

12. Before sweeping the shop, dampen the floor to keep down 
the dust. 

13. Do not drink beer or whiskey, or any other alcoholic liquors. 
These weaken your ‘system and make you more susceptible 
to lead poisoning. 

14. In handling lead, wear gloves as much as possible, and 
wash and dry the gloves every day that you wear them. 

‘15. Wear goggles to keep lead and acid out of your eyes. 

16. When melting lead in a hydrogen flame, as in burning on 
the top connectors, the fumes given off may be blown away by a 
stream of air. The air supply to the flame may be tapped for this 
purpose. | 

17. The symptoms of lead poisoning are: gums darken or be- 
come blue, indigestion, colic, constipation, loss of appetite, mus- 
cular pains. In the later stages there is muscular weakness and 
paralysis. The hands become limp and useless. 

18. Wear rubber shoes or boots. Leather shoes should be 


THE WORKSHOP. GENERAL INSTRUCTIONS 151 


painted with a hot mixture of equal parts of paraffine and bees- 
wax. . 

19. Wear woolen clothes if possible. Cotton clothing should 
be dipped in a strong solution of washing soda, and dried. Wear 
a flannel apron covered with sacking. 

20. Keep a bottle of strong ammonia handy. If you should 

spill acid on your clothes, apply some of the ammonia immediately 
to neutralize the acid, which will otherwise burn a hole in your 
clothes. 
* 21, Keep a stone, earthenware, or porcelain jar filled with a 
solution of washing soda or bicarbonate of soda. Rinse your 
hands in this solution occasionally to prevent the acid from irri- 
tating them. 

22. If you should splash acid in your eye, wash it out imme 
diately with warm water, and drop olive oil on the eye. If you 
have no olive oil at hand, do not wait to get some, but use any 
lubricating oil, or vaseline. 


Lead Burning. 
‘‘Lead Burning,” so called, refers to the melting together of 


plates and straps, or posts and top connectors and terminals. 
There are three general methods used: 


Fig. 84. Carbon Lead Burning Outfit 


1. Soldering Irons. These are inconvenient, and should not 
be used unless a gas outfit is not available. A description of this 
method is given later, beginning on page 244. 


152 THE AUTOMOBILE STORAGE BATTERY 


2. The Electric Arc. This is a very simple method, and re- 
quires only a spare 6 volt battery, a 4% inch carbon rod, carbon 
holder, cable, and clamp for attaching to battery. This outfit 1s 
shown in Figure 84. It may be bought from the Electric Storage 
Battery Co., of Philadelphia. 

In using this outfit, one terminal of an extra 6 volt battery 1s 
connected by a piece of cable with the connectors to be burned. © 
The contact between cable and connector should be clean and © 
tight. The cable which is attached to the carbon rod is then con- 
nected to the other terminal of the extra battery, if the battery 
is not fully charged, or to the connector on the next cell if the 
battery is fully charged. The number of cells used should be 
such that the carbon is heated to at least a bright cherry red 
color when ‘it is touching the joint which is to be burned together. 

Sharpen the carbon to a pencil point, and adjust its position so 
that it projects from the holder about one inch. Occasionally 
plunge the holder and hot carbon in a pail of water to prevent 
carbon from overheating. After a short time, a scale will form 
on the surface of the carbon, and this should be scraped off with 
a knife or file.. 

In burning in a connector, first melt the lead of the post and 
connector before adding the burning lead. Keep the carbon 
point moving over all parts to be joined, in order to insure a 
perfectly welded joint. The directions beginning page 239 for 
lead burning with the hydrogen flame may also be used for the 
carbon. 

3. Gas flame. A.number of outfits are used. These are 
described below: | 

(a) Oxygen. and Hydrogen gases under pressure in separate 
tanks. These gases are sent through a mixing valve, where the 
proper proportions of the two gases are obtained. This is prob- 
ably the most satisfactory and convenient of all methods, but it 
is not always possible to obtain the gas. The simplicity of this 
set is shown in Figure 85. 

(b) Hydrogen and air under pressure in separate tanks. This 
set is fully as simple as the Oxygen-Hydrogen, is cheaper, and 
is more easily obtained than the Oxygen-Hydrogen. 


THE WORKSHOP. GENERAL INSTRUCTIONS 153 


Fig. 85. Hydrogen-Oxygen Lead Burning Outfit. A and B are Regulating Valves, C 
is the Safety Flash Back Tank, D is the Mixing Valve. E is the Burning Tip 


154 THE AUPOMOBILE STORAGE BATTERY 


(c) The Prestolite Company of Indianapolis sells a lead burn- 
ing outfit which uses Prestolite gas and oxygen under pressure. 

(d) The Electric Storage Battery Company of Philadelphia 
sells a Hydrogen-Air set which includes a gas generator. The 
parts of the outfit are as follows: 


1 Gas generator. 

1 Wash ‘bottle. 

1 Branch pipe. 

2 Rubber stoppers. 

1 Air pump and air tank combined. 

1 Finger pipe, and set of tips. 

1 50-ft length of 5-16 inch rubber tubing. 
1 2-ft. length of 34 inch rubber tubing. 
1 Triangular scraper. 


) Finger Pee 


Cet 


Relief Velve i Ww 
* a ‘g ~ “4 


Fig. 86. Hydrogen Generating Outfit 


Three sizes, F, E, and D, are made. The materials used for 
generating the gas are Granulated Zine, Water, and Sulphurie 
acid. The arrangement of parts is shown in Figure 86. 

(e) Figure 87 shows a similar gas generating and lead burning | 
set. 

(£) Ordinary illuminating gas (coal gas) may be used. A 


THE WORKSHOP. GENERAL INSPRUCTIONS 155 


Fig. 87 


Fig. 88. Mlumtnating Gas Valve and Burning Tip 


156 THE AUTOMOBILE STORAGE BATTERY 


special tip and mixing valve are necessary. The burner and valv 
are shown in Figure 88. This set may be bought from the Electric 
Storage Battery Co. Enough 5-16 inch rubber tubing should b 
provided to make the connections. The hose should be fastened 
with wire or clamps to the nipples to prevent leaks. 

The air should have a pressure of from 5 to 10 pounds, depend- 
ing on the length of hose, and the size of flame desired. In using 
air from a tire air compressor, a reducing valve is necessary for 
reducing the pressure. Referring to Figure 88, connect the air 
hose at A, the gas hose at B, and the hose leading to the burn- 
ing tip at C and D. This hose should not be more than five or 
six feet long. 2 

In using, close the air valve A, and turn the gas valve B, on 
full. Light the gas at the burning tip, and then turn on the air. 
The air pressure should not be high enough to blow out the flame. 

When the gas is turned on full, the flame will look ragged, and 
will ‘‘show a waist,’’ or become narrow about 14 inch from the 
burning tip, and will then spread out. Do not use such a flame 
for burning. | 

Turn the gas off slowly until the outer portion of the flame at 
the waist breaks and spreads, with an inner tongue. of flame 
issuing through the outer ring. The flame will now have a green- 
ish color, and is suitable for burning. 

If the gas is turned off further, or too much air is turned on, 
the flame will become blue and then invisible. It is not suitable 
for burning. 

When the flame is properly adjusted, the hottest part is just 
beyond the end of the inner point. The burning tip should not be 
held too close to the work when burning, as the flame becomes 
cooler near the burning tip. 

The burning tip has a sleeve and lock nut. The position of 
the sleeve should be adjusted so as to give the best flame. 

(¢) A tank of illuminating gas, either natural or manufactured, 
and a tank of oxygen may also be used. This is a simple method. 
Full information may be obtained from the Electric Storage Bat- 
‘tery Co. of Philadelphia, Pa. 


THE WORKSHOP. GENERAL INSTRUCTIONS 157 


‘When tank gas or air is used, an automatic pressure valve must 
be inserted in each line so as to regulate the pressure at any 
point. Tank hydrogen must have, in addition, a safety flash back 
water tank inserted in the line, as shown in Figure 85. 


Saving the Sediment. 


Many batterymen throw away the sediment which they wash 
from battery jars. This sediment is often called ‘‘lead mud,’’ 
and should be saved and sold to junkmen. Figure 89 shows a 


SETTLING "TANK TO SAVE 
SEDIMENT FROM JARS 


LEA! 
LINE JEL 


SEWER 
Fig. 89 


' scheme for collecting the sediment. Run the drain pipe from the 
sink at which the jars are washed out to a lead lined box as shown. 
The water and sediment enter at A. The sediment settles to the 
bottom of the box, while the water escapes to the sewer at B. 
The lead mud may be cleaned out periodically. 

The lead lined box is best to use, but is somewhat expensive. 
Tf the inside of the box is given two coats of very hot asphaltum 
paint, it will be fairly well protected from the action of acid. 


158 THE AUTOMOBILE STORAGE BATTERY 


The box may be placed wherever convenient. One batteryman 
uses an old enameled bathtub as a settling tank. 
Mixing Electrolyte. 


The simplest scheme for handling electrolyte is to have only 
the 10-gallon carboys of 1.400 specific gravity acid, and the bottles 
of distilled water on hand, and mixing the electrolyte for each 


A CHEAP METHOD OF DRAWING © 
ACID FROM CAR BOY 


V2 ROUND ROCK- 
ERS-I4 THICK 


Fig. 90 


particular battery. Pour some water into an earthenware or 
porcelain pitcher or jar, and then add the acid very slowly until 
the desired specific gravity is obtained. Never add water to 
acid, as an explosion might result which would injure you. Stir 
the mixture thoroughly as you add the acid. 

Figures 90, 91 and 92 show three methods of handling acid 
or distilled water. Figure 90 shows the simplest method. Cut 
two half round pieces: of wood, using a radius which is half the 


height of the wooden case in which the bottle is placed. Screw 


| 


THE WORKSHOP. GENERAL INSTRUCTIONS 159 


these on the side of the case. These will act as rockers for tipping 
the bottle when emptying. 
Figure 91 shows a simple siphon ar- 
rangement. A is the container, B a rub- 
. ber stopper, C and D glass or lead tubes, 
E a rubber tube having a pinch clamp at 
the lower end. To use, the stopper and 
tubes are inserted in the bottle, and air - 
blown in at C while the pinch clamp is 
open, until the tube E is full. The pinch 
clamp is then released. Whenever the 
_ liquid is to be drawn from the bottle, 
the pinch clamp is pressed, so as to re- 
» lease the pressure on the tube. The 
hquid will flow automatically down the 
tube E as long as the clamp is open. To 
stop the flow release the clamp. 

The clamp may be made of flat or 
round spring brass or bronze. This is 
RD SO CR ING bent round at (a). At (c) an opening 

is made through which the part (b) is 

bent. The clamp is operated by pressing 
at (d) and (e). The rubber tube is passed through the opening 
between (b) and (c). | 

Figure 92 shows a similar arrangement, except that an air foot 
pump is used to force out the liquid. To operate, the finger is 
placed over the opening at D and the pressure is applied. The 
liquid will flow out as long as the pressure is applied and the 
finger held at D. To stop the flow, the finger is lifted, thus re- 
leasing the pressure. | 

The following table shows the number of parts of distilled 
water to one part of 1.400 specific gravity electrolyte to pre- 
pare electrolyte of various specific gravities. The specific gravity 
of the mixture must be taken when the temperature of the mix- 
ture is 70° F. If its temperature varies.more than 5 degrees 
above or below 70° F, make the corrections described on page 85 
to find what the specific gravity would be if the temperature were 
70° FF. 


Fig. 91 


160 THE AUTOMOBILE STORAGE BATTERY 
BY WEIGHT. 


For 1.300 specific gravity use 5 ounces of distilled water for each 
pound of 1.400 electrolyte. 

For 1.280 specific gravity use 614 ounces of distilled water for 
each pound of 1.400 electrolyte. 


COMPRESSED AIR SYPHON PUMP 
FOR EMPTYING ELECTROLYTE CARBOYS 


Fig. 92 


For 1.275 specific gravity use 614 ounces distilled water for each 
pound of 1.400 electrolyte. 

For 1.260 specific gravity use 7/4 ounces distilled water for each , 
pound of 1.400 electrolyte. | 


BY VOLUME. | 

For 1.300 specifie gravity use 314 pints distilled water for each 
gallon of 1.400 electrolyte. 

| 


THE WORKSHOP. GENERAL INSTRUCTIONS 161 


“or 1.280 specific gravity use 414 pints distilled water for each 
gallon of 1.400 electrolyte. 

“or 1.275 specific gravity use 5 pints distilled water for each 
gallon of 1.400 electrolyte. 

“or 1.260 specific gravity use 514 pints distilled water for each 
gallon of 1.400 electrolyte. 

In ease you wish to use other measuring units than those given 
n the above table, this table may be written as follows, giving 
‘he number of parts distilled water to 10 parts of 1.400 specific 
yravity electrolyte: 


Specific Gravity Parts by Parts by 
Desired Weight Volume 
V.B00.. 2. cece eee ees Bivcccccccccccecececs 4l/, 
5 || Sr 51, 
5 1 bs re 6 
5 1 | 47-10 ............08. 6% 


The next table gives the number of parts of distilled water to 
10 parts of concentrated sulphuric acid (which has a specific 
gravity of 1.835) to prepare electrolyte of various specific grav- 
ities : 


Specifie Gravity Parts by Parts by 
Desired Weight Volume 
1.400... 0... cece ee eee BY Loc ccc eee eeee 15 8-10 
1.300..... ccc cece caeeeeees WWE eee ees ev eee 25 
1.280... . 0. ccc eee eee | hs rr a 27 
p41 bs 5 28 


CHAPTER 15. 
ANALYSIS OF THE CONDITION OF THE BATTERY. | 
What is the Trouble? 


With some batterymen it is a ease of ‘‘blind leading the blind,’’ 
when a man brings his car to the shop. Generally the car owner 
only knows that his lights are dim, or his starting motor will! 
not crank the engine; he does not know what is wrong, and usually: 
does not care particularly. He wants you to make his lights and 
starter work properly, and the sooner you do it, the better sat- 
isfied he will be, and the greater the probability of his coming 
back to you the next time he has trouble. 

‘*What is the Trouble?’’ That is what you must determine at 
once, and tell the car owner how soon he may again have his ear. 
Ife may have a long tale of woe and may think he knows just 
what is wrong and what must be done, and say that he merely 
brought the car to you because he lacks the proper tools and 
equipment. If you go ahead on the strength of what the car 
owner tells you, unless you are well acquainted with him and 
know that he has a better knowledge of electricity than you 
have and has made a thorough study of his car, you are in the 
position of one blind man being led by another. You will have 
a vague feeling of uneasiness and dissatisfaction with yourself 
which you eannot analyze. You will most likely feel ashamed of 
vourself and be very apt to do a very poor job of putting the 
ear in good shape. You started by not using your head or doing 
your own thinking, and you very likely will not do any thinking 
on the whole job. You will feel that the ear owner is your 
superior, and that you must do just what he said the ear needed. 

Tf vou run your battery repair business on such a basis, you are | 
bound to be a flat failure. For the sake of your success, self- 
satisfaction and peace of mind, do not let the car owner be the 

162 


ANALYSIS OF CONDITION OF BATTERY 163 


aaster of the situation. You have a head on your shoulders 
vhich you should use. You are the expert, and it is up to you 
Oo make a quick, accurate analysis of the situation and decide 
what the remedy is. You would not think of going to a doctor 
when you feel ill and telling him you have such and such a 
trouble, that you wanted a certain medicine to cure it, and that 
you were merely coming to him because you needed his official 
prescription in order to get the medicine at the drug store. If 
any doctor allowed you to do this, you would have a feeling of 
dissatisfaction with him because he allowed you to make the diag- 
nosis when, because of his special training and experience, he 
should be able to make it himself, and do it better and more 
quickly. You like to have him listen to what you think is wrong 
with yourself, but not to be guided entirely by your opinions. 
If he does not examine you himself, and ask you questions that 
show he is analyzing your condition carefully, you will go away 
dissatisfied, and your anxiety about your pains will not be re- 
heved. Most likely, you will go to another doctor who will not 
let your talk influence him too much in his diagnosis and pre- 
Secription. 

When a car is brought to your shop, you are the doctor.. Some 
part of the mechanism is in trouble, and it is your duty to put 
yourself in charge of the situation. Examine and test the battery 
earefully. Listen to what the driver or car owner has to say. 
It will probably give you a clue to the trouble. Question him 
so as to establish certain points in your mind. Then decide for 
yourself what must be done, and tell the man who brought the 
ear or battery what repairs you consider necessary, regardless 
of whether he thinks you are right or not. If he disagrees, explain 
to him clearly and courteously what you think must be done, 
and if you show that you have been careful in your analysis, he 
will think more of you for-insisting on certain repairs. 

It is Just as disastrous if you go too far in doing your own 
thinking. If you have any hopes of being successful in your busi- 
ness, do not assume such air of superiority that says, ‘‘I know it 
all,’’ and shows a contempt for the knowledge of the owner or 
driver. If you are told that the lights won’t work, turn on the 
lighting switch to see if they will. If the driver says that the 


164 THE AUTOMOBILE STORAGE BATTERY 


starter won’t crank the engine, try it. Listen attentively and 
courteously to what the driver has to say. Disregarding his 
story entirely will most likely make him angry, and he may never 
return to your shop. 

What the owner wants to know is how much the repairs will 
cost, and when he can have his car again. The following direc- 
tions will enable you to decide what must be done. Estimate 
carefully, if possible, what the work will cost. If a considerable 
amount of work is required, and you cannot tell how much time 
and material will be needed, tell the owner you will let him know 
the approximate cost later, when you have gone far enough to be 
able to make an estimate. 

If the owner cannot leave his car, take off the battery and 
put a “‘renter’’ in its place until the repairs are completed. 

’ The first thing to do, therefore, when a car comes to your shop 
is to greet the driver courteously and ask him what the trouble 
seems to be. He certainly has noticed that something is wrong 
with the electrical system of his ear, or he would not have brought 
the car to you. Generally the driver complains that his lights 
burn dimly, or that the motor will not start his engine, or else 
turns the engine over very slowly. Dim lights usually come 
first, that is, a battery which will not give bright lights will 
operate the starter satisfactorily. A drop in battery voltage 
which will give dim lights may not cause failure to start. The 
immediate trouble which caused the owner to send the car to you 
may, of course, be due to one or more conditions which you can 
discover by merely making an inspection of the battery, or which 
may be more difficult to determine. It is best, therefore, to go at 
each car in the same way, making the same tests and inspections, 
but always bearing in mind the trouble which the driver has de- 
scribed. You will be able to analyze the conditions you find more 
clearly. If, for instance, there is starter trouble, and you find 
that there is a loose connector between two cells, you will know, 
when you find the loose connector, that you have probably dis 
covered the cause of the trouble. Do not, however, be satisfied 
with merely reburning Phe joints between the connectors and the 


posts. Make other tests to determine what the exact condition © 


ANALYSIS OF CONDITION OF BATTERY 165 


of the battery is in other respects: One trouble very often leads 
to others, and curing the one will not eliminate the others. 

If trouble exists and the battery is badly discharged, tell the 
owner he has an abnormal condition or trouble some place on 
his ear, and that his battery will have to be taken off his car, and 
a renter put in its place while his is being charged, repaired or 
rebuilt, as the ease may be, and that the trouble or abnormal con- 
dition must be removed or his battery will run down again in a 
short time. It is your business to get the job; do it in as agree- 
able a manner as possible. If you have good reasons to believe 
it is some trivial trouble, fix it as quickly as possible in a work- 
manlike manner. If it proves to be anything serious that will take 
considerable time, make an appointment with the man to have 
him leave his car, and when he leaves it, locate the direct cause 
of trouble, repair it as quickly as possible, in a conscientious, 
workmanlike manner, so that it will stay fixed and give satisfac- 
tory service. Your business will grow just in proportion as you 
give satisfactory service. Satisfy every customer and give him a 
square deal. The public is not slow in locating and patronizing 
this kind of repair shop. 

You must have'a standard method of procedure. It is the only 
way to avoid the haphazard, hit-or-miss habits of an inferior re-— 
pairman. Go through the steps described below, and you will 
soon have the: business-getting, profit-making habits which you 
need in order to be successful. | 

The Standard procedure is as follows: 

1. Ask the driver or owner why he brought the car to your 
shop. Remember what he says when you take the remaining 
steps. 

». Open the battery box and make a general inspection. 

(a) Is the battery covered with dust and dirt? Brush off 
the coarser dirt with an old whisk broom. Then take a rag wet 
with ammonia or solution of soda and wipe all parts clean. 

(b) Are the cables tight? Feel each connection at the pos- 
itive and negative terminals. If any age loose, tighten them. 
' See that no cable is partly broken through, especially at the end 
of the terminal. See that cables are well insulated. | 

(c) Are the top connectors tight? Feel each connector. If 


166 THE AUTOMOBILE STORAGE BATTERY 


one or more are loose, you must take battery from the car and 
reburn the connector. 

(d) Is there corrosion at the battery terminals? This is indi- 
cated by a green deposit, especially at the positive terminal. 
Scrape deposit off with a knife, and remove cable if possible. 
Clean contact surfaces on cable terminal and post with fine sand- 
paper. If corrosion has proceeded so far that you cannot remove 
the cable, use cable tongs, bore off the terminal connection, and 
soak in boiling soda water for a few minutes. The cable can 
then be removed easily, and the connector will be clean. 

(e) Are all the connections clean? Remove cables and if 
there is any dirt on contact surfaces, soak in boiling soda water 
or clean with knife or fine sandpaper. 

(f) Is the battery loose in the box? If so, put in new hold 
down bolts. A loose battery will cause broken jars, spilled elec- 
trolyte (causing corrosion at terminals, short-circuits, rotted 
box, rotted case, low gravity, low liquid in cells), and loose cables. 

Always examine closely the battery box on car. See if it is 
hung loosely, or not properly braced, or no hold downs attached, 
or if loose in the box, or if the terminal cables jump around with 
vibration of car. The trouble may be due to any one of the above 
causes. Never put a battery on a car without noticing carefully 
all the above possible conditions and if any exist call the car 
owner’s attention to them and ask him if he wants them fixed; 
fix them right and charge him for the time and material used. 
Always have a supply of hold down bolts, %4 or 5-16 inch on 
hand of two lengths, 11 inches and 121% inches; also have good 
heavy spring washers and winged nuts for same. 

It is a fact that a battery should be firmly fastened down; do 
not overdo it, however, by screwing the hold downs so tight as 
to pull off the handles or break the sealing on end of case, but it 
must be firmly clamped down, and the box or hanger the battery 


is in must be solidly fastened to the car, and have no percepti- | 


ble vibration other than the movement of the car. For repairing 
handles that have pulled off, see page 225. 

(zg) Is any of the sealing compound on top of the cells broken 
at the posts, filling vent, or around the edges? See Trouble Chart. 
No. 7, page 176. This will cause the battery to be a ‘‘slopper,”’ one 


ae 


ANALYSIS OF CONDITION OF BATTERY 167 


in which electrolyte is thrown out through the cracks in the com- 
pound by the jolting of the car on the road. If so, remove bat- 
tery from car and open it. See page 187. 

(h) Are the ends of battery bulged out? If so, the battery 
has been frozen. See Trouble Chart No. 11, page 178. Remove 
battery from car and open it. See page 187. 

(i) Is the battery case, or metal box, rotted and eaten through? 
See Trouble Chart No. 8, page 177. If condition of box is very bad, 
remove battery from car and open it. See page 187. 

3. Read the date marks on the battery. If you cannot find 
them, ask the driver how long the battery has been on the ear. 
If he says it has been in use for fifteen months or more, the bat- 
tery is probably worn out, and needs new plates. Open the bat- 
tery. See page 187. If battery has been in use only a short time, 
or less than a year, try to find out if battery was new when in- 
stalled on car. It may have been a second hand battery in the 
first place, and may now be old enough to need new plates. _ 

If battery looks new, proceed with remainder examination. 

4. Remove filling vents and inspect level of electrolyte. If 
electrolyte is below tops of plates in any eell, fill with distilled 
water. See Trouble Chart No. 3, page 174. If it requires a con- 
siderable amount of water to fill any cell, that cell has been in- 
jured in proportion to the length of time the electrolyte has 
been below the tops of the plates. 

Ask the driver when water was last added. If more than a 
month has since passed, remove battery from car and give 
charge for sulphated battery. See page 184. If the electrolyte 
level sinks below tops of plates soon after filling with water, the 
jar is cracked. In this case remove battery from car and open 
it. See page 187. 

If it is necessary to add only a normal amount of water, bat- 
tery may be charged on car by running engine for several hours, 
or battery may be charged in shop at the charging bench. 

5. Turn on the lighting switch or switches. Measure the 
voltage of each cell. Each cell should have a voltage of 2 or 
more. If any cell shows no voltage, that cell is ‘‘dead.’’ Re- 
move battery from car and open it. See page 187. See also 
Trouble Chart No. 1, page 172, and No. 12, page 178. If all cells 


168 THE AUTOMOBILE STORAGE BATTERY 


show from 1.8 to 2 volts, remove battery from car and give it 
a normal charge. See page 183. | 

6. Close the starting switch, and if battery will not crank 
motor while switch is closed, measure the voltage of the whole 
battery. If this drops to a very low value, say 1 volt per cell, | 
make sure that there is no trouble outside of the battery. If 
there is none, remove battery from car and charge it. See page 
183. Instead of measuring the voltage you may turn on the lamps 
before closing the starting switch. If the lights then become very 
dim when the switch is closed remove the battery and put it on 
charge, unless it is in a bad condition. It should then be opened. | 

7. Measure the specific gravity of each cell. Make a record 
of the readings for use later. See page 79, and Trouble Charts | 
1 and 2, pages 172 and 174. If you have added water to bring the — 
level of the electrolyte above the plate tops, do not measure the > 
specific gravity unless you have, in the meantime, run the 
engine till the cells have been gassing freely. The meaning of | 
the various values of specific gravity are: 


1.300 to 1.250—Fully charged. 

1.250 to 1.200—More than half charged. 

1.200 to 1.150—Less than half charged. 
—Run engine several hours to charge 

1.150 or less—Completely discharged. 
—Remove battery from car. See page 187. 


Note:—It sometimes happens that gravity readings of 1.200 
or over are obtained, and the voltage is high, and yet the lights 
are dim and the starter will not crank the engine. This shows 
that acid has been added instead of water. Remove battery 
from car and open it, as battery has probably been damaged 
internally. See page 187. | 

8. There may be other symptoms of trouble such es:— 7 

(a) Battery overheats while car is running. See Trouble 
Chart No. 4, page 175. Electrolyte is below surface of plates, 
or generator is delivering too much charging current. Battery | 
may also be located near a hot place such as the exhaust pipe. { 
Look for low electrolyte (See 4, above) ; measure charging current 
with ammeter; if battery is near a hot place, change its location. 


ANALYSIS OF CONDITION OF BATTERY 169 


(b) Battery runs down quickly on car after being charged. 
Generator not delivering charging current, or too small a current. 
There may be short circuits or grounds in wiring which cause a 
continuous discharge. Use the AMBU Trouble Shooter. See 
Trouble Chart No. 10, page 177. 

(c) Battery will not take a charge. See Trouble Chart No. 6, 
page 176, and No. 5, page 176. Look for loose connections. If 
none are found, remove battery from car and open it. See page 187. 

(d) Specific gravity low even though generator is delivering 
the proper charge. May not be enough acid in the electrolyte. 
If specific gravity will not rise after long continued charge, re- 
move water and add 1.400 specific gravity electrolyte, so as to 
bring specific gravity of each cell up to 1.275-1.300. 

(e) Lights on one side of car burn dim, and on other bright. 
This occurs when a three wire lighting system is used with a 12 
volt battery. It indicates that one side of the battery is carry- 
ing a heavier load than the other. Change wiring so that same 
current is drawn from each:half of battery. Remove battery from 
car and give it a normal charge. See page 183. 

(f) Battery run down after storage. Remove and give bat- 
tery a long charge, as for sulphated battery. See page 184. It 
may be impossible to put any life into the battery, on account of 
badly sulphated or disintegrated plates. - 

9. In order to do the best work and, build up a reputation for 
thoroughness, test the lighting system and the generator, with all 
the wiring. Your battery trouble may be due to some fault in other 
parts of the starting and lighting system, and unless you find this 
trouble, it is of little use to put the battery in shape, as the same 
trouble will soon return. For such testing you should have an 
‘‘AMBU’’ Trouble Shooter, which quickly and accurately locates 
troubles in the starting and lighting system of all American made 
cars. 

10. The action of the cutout relay in opening or closing the 
charging circuit must be correct. This should always be checked 
according to the directions given below: 

The cutout should close the circuit between the battery and 
dynamo as soon as the voltage of the dynamo is sufficiently above 
that of the battery to cause a charging current to flow from the 


170 THE AUTOMOBILE STORAGE BATTERY 


dynamo to the battery. The action of the cutout may be tested 
as follows: 

First turn off all the lamps; make sure that the specific gravity 
of each cell of the battery is at least 1.250 and that the dynamo 1s 
giving its normal output. If the battery is run down, it must be 
charged, or a “‘renter’’ put in its place. That means that an 
Ambu test for Engine Running, Lamps Off, should give an ‘‘N’’ 
reading. Have the Ambu ammeter attached at the battery as 
for the regular Ambu tests. With the engine running, gradually 
close the throttle until the engine runs slow enough to allow the 
cutout to remain open. When the cutout is open, the ammeter 
pointer will be over the ‘‘O”’ line. Now gradually increase the 
engine speed and watch the ammeter pointer. At some speed 
between 5 and 15 miles per hour, the pointer will swing to the 
right or left of the ‘‘O”’ line, showing that the cutout has closed. 

If the pointer first swings to the left of the ‘‘O’’ line and then 
with increasing engine speed moves to the right of the ‘‘O”’ line, 
the cutout is closing too soon. This condition may be remedied 
by increasing the air gap between the movable cutout arm and thie 
electromagnet, or by increasing the spring tension. Increasing 
the spring tension will also cause the cutout to open at a higher 
engine speed than before, and in making this adjustment care 
should be taken that the action of the cutout in opening is as 
described below. 

If the pointer first swings to the right of the ‘‘O’’ line, the 
contacts are not closing at too low a speed, but may still be clos- 
ing at too high an engine speed. Bring the engine to its lowest 
speed and then gradually open the throttle. When the peinter 
moves to the right of the ‘‘O”’ line, hold the engine speed con- 
stant at that point for an instant. Then with a further increase of 
engine speed, the pointer should move farther away from the 
‘*O’’ line. Increase the engine speed until the charging curreni 
stops rising. Note if this maximum is correct. If not, use the 
Ambu trouble shooter. If the pointer moves so as to indicate 
the normal charging current as soon as the cutout closes, or if 
only two or three amperes more charging current are obtained 
with increased engine speed, it indicates that the cutout is clos- | 
‘ng at. too high a speed. This condition may be remedied by 


ANALYSIS OF CONDITION Of BATTERY 171 


either decreasing the air gap or decreasing the spring tension. 
In decreasing the spring tension, check the action of the cutout 
in opening, as described below, in order that the discharge current 
necessary to allow the spring to open the cutout may not be too 
great. ) 

Check the action of the cutout in opening; start with the cutout 
closed and then gradually decrease the engine speed. The pointer 
will move toward the ‘‘O’’ line and then will move to the left of 
this line. The amount of the motion to the left should not exceed 
two or three amperes and the pointer should remain on this side 
of the line for only a very brief instant and should then return 
to the ‘‘O’’ line, showing that the eutout has opened. If the 
cutout opens before the pointer passes to the left of the ‘‘O’’ line, 
the spring tension should be decreased. If the pointer moves to 
the left of the ‘‘O’’ line so as to indicate a discharge current of 
more than 4 amperes, or if the pointer remains on the left of 
the ‘‘O”’ line for more than an instant, the spring tension should 
be increased. 

It sometimes happens that a cutout will not open as the engine 
is stopped and such a condition should be remedied at once by 
making the contact points clean and smooth, and by increasing 
the spring tension. When the cutout acts in this way and the 
condition is not remedied, the battery will discharge into the 
generator until it is run down. Such a condition often exists 
without the knowledge of the car owner and is the reason for 
much mysterious battery trouble, in which the battery appar- 
ently runs down without any cause being discovered. Such con- 
ditions are often hard to discover because in connecting a testing 
instrument at the battery, the cutout will open as soon as the 
battery circuit is broken and no discharge of current will be 
indicated on the meter. It is therefore necessary in testing any 
car to start the engine and then stop it and notice if any dis- 
charge current is shown on the meter, thus indicating that the 
eutout has not opened. | 

If you have no Ambu Trouble Shooter, use an ammeter which 
has the ‘‘O”’ in the center of the scale and which reads to about 
2) amperes both ways. This ammeter should be connected in 
Series with one cable of the battery. This is done by removing 


172 THE AUTOMOBILE STORAGE BATTERY 


one of the main cables from the battery, and connecting this — 
cable to one of the terminals on the ammeter. Connect the other 
ammeter terminal to the battery post from which the main cable 
was removed. 

Most cars now use battery ignition systems, and it is necessary 
to use dry cells or an extra storage battery to furnish the ignition 
current while making the test. If you have Ambu, make the con- 
nections which are described in the Ambu Instruction Book, and 
then test the cutout as explained above. 


BATTERY TROUBLE CHART NO. 1. 
LOW GRAVITY OR LOW VOLTAGE. 


A. LOOK FOR THE FOLLOWING TROUBLES: 

1. Loose or dirty terminals or connectors. 

2. Broken terminals or connectors. 

3. Loose plugs causing flooding. 

4. Corroded terminals caused by acid on top of battery due to 
overfilling or flooding. 

5. Copper wires attached to battery posts. Remove wires and 
attach to battery cables at least one foot from battery terminals. 

6. Acid or moisture on top of battery, causing current leakage. 

7. Tools or wire causing short circuits. 

8. Short circuits or grounds in wiring. Use ‘‘AMBU’’ Trouble 
Shooter. 

9. Three wire lighting system with unequally divided load, 
discharging two halves of battery at different rates. Redistribute 
load. 

10. Muitiple section battery charged with two or more sections 
in parallel. Cable terminals and connections must all be clean 
and tight. 

11. Check action of cutout relay. See page 169. 

12. Polarity of dynamo reversed, or battery connections re- 
versed. 

13. Excessive lamp current. Use ‘‘AMBU”’ Trouble Shooter. — 

14. Dynamo not charging battery. Use ‘‘AMBU’’ Trouble | 
Shooter. 


ANALYSIS OF CONDITION OF BATTERY 173 


15. Dynamo charging battery at too low arate. Use ‘‘AMBU’’ 
Trouble Shooter. 


B, ASK THE DRIVER: 
If water has been added once every week. 
If distilled water only has been used. 
If too much water is added. 
If electrolyte has been spilled and replaced by water. 
If any alcohol or anti-freeze mixture has been added. 

6. If electrolyte is always returned to ccrrect cell after hy- 
drometer readings. 

1. If impure acid or electrolyte has been used. 

8. Has battery been dropped? 

9, Has battery been idle, or stored without regular charging 
for several months? 

10. Has specific gravity been low for a considerable time? 
There is, therefore, sulphation present. 

11. How old is the battery? If a battery has been used more 
than fifteen months, it is best to put in a new one. 

i2. Is car used in night time more than the day time? Con- 
siderable night driving does not allow battery to remain charged. 

13. Is starter used frequently ? 

14. Has starter been used frequently, merely to demonstrate it? 

15. How fast is ear driven on an average? Speed should be at 
least 15 m.p.h. Battery is not charged at low speed. 

16. How long do you spin the engine with the starting motor? 
Should not exceed one half minute. 

17. If it is winter, caution driver to keep battery charged, even _ 
if battery must occasionally be removed from ear to do so. 


gu ye go PO 


C. IF BATTERY HAS BEEN REPAIRED: 

The trouble may be due to 

1. Negative exposed to air. 

2. Common wood used in place of separators. : 

3. Grooved sides of separators put toward negative plates in- 
stead of positive. 

4. A separator may have been left out. 

d. Positives used that should have been discarded. 


1i4 THE AUTOMOBILE STORAGE BATTERY 


6. Bulged negatives used. 
7. Poor connections made. 


D. BATTERY TROUBLE WHICH MAY EXIST: 
. Sulphated Plates. 

. Buckled Plates. 

. Internal Corrosion. 

. Shedding of Active Material. 
. Internal Short Circuits. 

. Cracked Jars. 

. Hardened Negatives. 

. Clogged Separators. 

. Battery frozen. 

10. Negatives reversed. 

11. Disintegrated positives. 

12. Crystallized positives. : ‘ 


OoaoN HO OR WG DN eH 


BATTERY TROUBLE CHART NO. 2. ° 
HIGH GRAVITY. 


A. PROBABLE CAUSES: 
1. Raw acid added instead of water. 
2. Electrolyte added instead of water. | 
3. Electrolyte replaced in wrong cell after testing specific 
gravity. | 


B. BATTERY TROUBLES WHICH MAY EXIST: 
1. Sulphated Plates. 
2. Burned Separators. 
3. Internal Corrosion. 


BATTERY TROUBLE CHART NO. 3. 


LOW LEVEL OF ELECTROLYTE. 


A. PROBABLE CAUSES: 
1.. Water not added. 
2. Electrolyte replaced in wrong cell after testing specific — 
gravity. : | 


ANALYSIS OF CONDITION OF BATTERY 175 


3. Battery dropped. 
4, Battery loose in box. 
0. Battery located in hot place, such as near the exhaust pipe. 


6. Battery overeharged due to long daylight runs, with little 
use of lamps. 


B. BATTERY TROUBLES WHICH MAY EXIST: 
1. Sulphated plates. 
2. Cracked Jars. 
3. Burned separators. 
4. Shedding of active materials. 


BATTERY TROUBLE CHART NO. 4. 
BATTERY OVERHEATS. 


A. PROBABLE CAUSES: 
. Battery located in hot place on car. 
. Water not added regularly. 
. Impure water used. 
. Electrolyte dirty. 
. Impure acid used. 
. Aleohol or Anti-Freeze liquid : added. 
. Sulphated battery charged at too high a rate. 
. Common wood used for separators. 
9. Battery overcharged by long daylight runs. 
10. Battery charged at too high a rate due to excessive gen- 
erator output. 


aon Oo fr & NH Fe 


B. BATTERY TROUBLES WHICH MAY EXIST: 
1, Sulphated plates. 
2. Softened or broken jars. 
8. Cracked, burned, or broken separators. 
4. Buckled plates. 
5. Active material has dropped out. 
6. Separators clogged. 


176 THE AUTOMOBILE STORAGE BATTERY 
OTHER TROUBLES. 


5. SPECIFIC GRAVITY WILL NOT RISE ON CHARGE. 


A. PROBABLE CAUSES: 
1. Battery badly sulphated. 
2. Not enough acid in electrolyte. 
3. Sediment in bottom of jars. 


B. REMEDIES: (Numbered to correspond with causes given 
above). 

1. Long charge at 3 to 5 ampere rate. 

2. Charge until specific gravity is constant for several hours. 
Then draw off some electrolyte and add 1.400 electrolyte. Charge 
again, and repeat until specific gravity is 1.280-1.300. 

3. Open Battery. See page 187. 


6, BATTERY WILL NOT TAKE CHARGE. 


A. PROBABLE CAUSES: 
1. Badly sulphated, or crystallized plates. 
2. Terminals or top connectors corroded, dirty, or loose. 
3. Open circuit inside of battery. 


B, REMEDIES: (Numbered to correspond with causes given 
above). 
1. Open battery. See page 187. | 
2. Remove green deposit, tighten and clean terminals, reburn 
top connectors. 
3. Open battery. See page 187. 


7. ELECTROLYTE LEAKING AT TOP. 


A. PROBABLE CAUSES: 
1. Too much water added. 
2. Battery loose in case. . 
3. Battery poorly sealed, causing a ‘‘slopper.’’ 
4. Filling plugs loose. 


ANALYSIS OF CONDITION OF BATTERY 177 


B. REMEDIES: (Numbered to correspond with causes given 
above). 
1. Add correct amount of water. 
2. Fasten battery in case. 
3. Reseal battery. See page 187. 
4. Tighten filling plugs. 


8. BATTERY BOX ROTTED. 


A. PROBABLE CAUSES: 
1. All the causes given in preceding chart. 
2. Broken jars. 
3. Electrolyte spilled in testing specific gravity. 


B. REMEDIES: (Numbered to correspond with causes given 
above). 
1. All the remedies given in preceding chart. 
2. New Jars—Open battery. See page 187. 


9, CORRODED TERMINALS. 


A, PROBABLE CAUSES: 
1. All the causes given in No. 7 above. 
2. Connecting copper wire directly to battery terminals. 
3. Electrolyte spilled in testing specific gravity. 


B, REMEDIES: (Numbered to correspond with causes given 
above). : 
1. All the remedies given in No. 7. 
2. Connect wires to battery cables at least one foot from battery. 
3. Wipe off electrolyte spilled in testing specific gravity. Re- 
move green deposit. 


10. BATTERY DISCHARGES RAPIDLY. 


A. PROBABLE CAUSES: 
1, Short circuits or grounds in wiring. (Battery Idle.) 
9. Short circuit in battery. (Battery Idle.) 


178 THE AUTOMOBILE STORAGE BATTERY 


3. Battery old, with most of active material dropped from grids, 
(Battery in Use.) 


B. REMEDIES: (Numbered to correspond with causes given 
above). 
1. Locate short circuits or grounds in wiring and remove. Use 
the *‘ Ambu Trouble Shooter.’’ 
2. Open battery and clear shorts. See page 187. 
3. Open battery and install new plates. See page 187. 


11. BATTERY FROZEN. 


A. PROBABLE CAUSE: 
1, Allowed to stand in discharged condition in cold place. 


B, REMEDY: 
1. Try charging at 3 ampere rate for a week. Most likely bat- 
tery must be opened and new plates and separators put in. 


12, LIGHTS DIM. 


A. PROBABLE CAUSES: 

. Battery partly discharged, due to insufficient charge. 

. Dead cell in battery. 

. Dirty, corroded, or loose terminals and top connectors. 
. Dynamo not delivering sufficient charging current. 

. Car used mostly at night with lights burning. 


OV He Oo LO 


B. REMEDIES: (Numbered to correspond with causes given 

above). 

1. Remove battery and charge on charge bench. 

2. Open battery. See page 187. 

3. Clean and tighten terminals. Reburn top connectors. 

4. Use ‘‘Ambu Trouble Shooter.”’ 

5. Change driving conditions, or charge battery about once a | 
month while removed from car. | 


ANALYSIS OF CONDITION OF BATTERY 179 
SUMMARY OF WORK TO BE DONE ON BATTERY. 


1. When may a battery be left on the car? 

(a) When you find that the specific gravity of all cells is 1.250 
or more, the voltage of each cell is at least 2, the voltage does 
not drop when the lights are turned on, the starter action is 
satisfactory, there are no loose terminals or connectors, the seal- 
ing compound is not broken or cracked so as to cause a ‘‘slopper,’’ 
the electrolyte covers the plates, the box is not rotted by acid, and 
there are no broken jars. 

(b) Conditions given in (a) will exist only if battery has been 
well taken care of, and some trouble has suddenly and recently 
arisen, such as caused by a break-in one of the battery cables, 
loosening of a cable connection at the battery or in the line to 
the starting motor, or in fact, any starter, generator, or lighting 
trouble which has not caused a battery to lose more than half 
of its charge and has not interfered with the charging circuit or 
current. | | 

(ec) If removing of corrosion, cleaning or tightening of ter- 
minals at battery will make the starting, charging, and lighting 
systems operate satisfactorily. 

(d) If battery is more than half charged, due to the conditions 
given in (b) and (c), and the driver promises to use his starter 
and lights sparingly until battery is fully charged. 


2. When should a battery be removed from car? 

(a) When you find broken sealing compound, causing a 
‘“slopper.’’ 

(b) When you find top connectors and terminals loose, cor- 
roded, or poorly burned on. 

(c) ‘When you find box badly rotted by acid, or otherwise de- 
fective. 

(d) When you find a cracked jar, indicated by low electrolyte, 
or find that electrolyte level falls below the tops of the plates 
soon after adding water. 

(e) When you find a dead cell, indicated by very low or no 
voltage. 

(f) When specific gravity of electrolyte is less than 1.250. 


180 THE AUTOMOBILE STORAGE BATTERY 


(g) When battery voltage drops to about 1.8 or less per cell 
when lamps are turned on. Lamps will then burn dimly. 

(h) When you find that electrolyte is below tops of plates, and 
it requires considerable water to bring it up to the correct height. 

(i) When battery overheats on charge, or discharge, although 
battery is not located in hot place, charging rate is not too high, 
and lamp and accessories load is normal. 

(j) When battery is more than 15 months’ old, and action not 
satisfactory. 

(k) When battery has low capacity, as shown by rapid loss of 
charge after being fully charged. 


Fig. 98. A Blacksmith Tried His Hand on This Battery 


(1) When a blacksmith or plumber has tried his hand at re- 
building the battery, or the car owner has attempted to save 
money by doing his own repair work. Such a battery is shown 
in Figure 93. 

(m) When the ends of the case are bulged out, indicating a 
frozen battery. 


3. When is it unnecessary to open up a battery? 

(a) When the conditions given in paragraphs (a), (b), (f), 
(g), (h), and (i), in section 2, above, can be remedied by outside | 
repairs, or by charging; (a) and (b) require repairs, and (f), (g), 
(h), and (i) require charging. If the charging will not cause the 


ANALYSIS OF CONDITION OF BATTERY 181 


specific gravity to come up to 1.280-1.300, it will be necessary to 
open the battery. See page 187. 


4, When must a battery be opened? 

(a) When the conditions given in section 2, paragraphs (a), 
(b), (£), (g), (h), and (i) cannot be remedied by charging or 
repairs that do not require the removal of the sealing compound. 

(b) When you find the conditions given in section 2, paragraphs 


(c), (d), (e), (3), (k), (1), and (m). 


CHAPTER 16. 
WORK ON THE BATTERY. 
Charging Batteries Before Rebuilding. 


Battery charging may in general be divided into two classifica- 
tions: 

1. Charging while on the ear, by the generator installed on 
the car. 

2. Charging battery when removed from the ear. 


1. With the battery on the car, the driving conditions deter- 
mine to a great extent the condition of charge, and the garage- 
man should watch them closely. The battery is alternately 
charged and discharged. The discharge takes place when the 
starter is used, or current is furnished to the lights, horn, igni- 
tion, ete. 

The battery furnishes these currents whenever the car is not 
running, or running at such a low speed that the dynamo does not 
charge the battery. Most generators are designed so that their 
outputs can be changed in order to keep the battery charged 
under the driving conditions of the particular car upon which 
the generator is placed. When ears leave the factory, the gen- 
erators are set to produce a current which will keep the battery 
charged under average driving conditions. This current should 
never be changed unless a battery does not receive enough charge 
due to unusual driving conditions, or receives too high a charge, 
as indicated by high temperatures (above 105°F), or abnormal 
gassing. 

It is important to check the action of the cutout in closing and 
opening the charging circuit. (See page 169.) The cutout should 
close as soon as the generator voltage is slightly greater than 

182 


WORK ON THE BATTERY 183 


that of the battery, and should open the circuit as soon as the 
generator voltage is slightly less than that of the battery. 

The temperature of the battery on the car must be watched 
closely. If a thermometer indicates that the temperature of the 
electrolyte is above 105°, and the connectors on top of the bat- 
tery feel hot, the charging rate of the dynamo must be decreased. 
If the charging rate cannot be changed, the lamps should be 
burned, day or night, whenever the car is running. This will cut 
down the charging current delivered to the battery and prevent 
overheating. 

If the specific gravity of the electrolyte is always below 1.250, 
due to unusual driving conditions, the output of the generator 
must be increased so as to keep the battery charged, or the lights 
should be used sparingly. 

2. With the battery off the car, the charge and discharge can 
be regulated by the repairman. There are many things to be 
considered in such charging. 

(a) If a battery needs a charge on: account of generator not 
having a sufficient output, or on account of unusual driving con- 
ditions, or neglect, give the battery a charge. Such a charge 18 
necessary : 

When the lamps burn dimly (with engine not running). 

When voltage per cell has fallen below 1.80 (with lamps 
burning). 

When electrolyte has fallen below the tops of the plates and 
battery is not giving satisfactory service. Water should first be 
added to bring electrolyte up to the correct height. 

Sometimes a battery will be completely discharged, as shown 
by dim lights and voltage below 1.8 per cell, but the hy- 
drometer reading will be 1.200 or above. This shows that acid 
has been added to the discharged battery instead of water. Give 
battery a full charge at once, and then reduce specific gravity 
to 1.270-1.300 by removing some electrolyte and adding water. 
Cells should be gassing while this is done, and the specific gravity 
reading should not be taken until an hour after adding water. 
The time required to charge such a battery depends upon the 
extent to which the battery has been damaged by the acid. If a 
considerable amount of acid has been added, the plates may be 


184 THE AUTOMOBILE STORAGE BATTERY 


badly sulphated, and require a long charge, or the separators may 
be rotted, making it necessary to open the battery. See page 137. 
The normal charging current to be used is that stamped on the 
nameplate usually found on the battery. 

Most manufacturers give a ‘‘starting’’ rate and a ‘‘finishing’’ 
rate. Charge the battery at the ‘‘starting’’ rate until the cells 
are gassing freely, and then reduce the current to the “‘finishing’”’ 
rate. Some manufacturers give only one charging rate, and in 
this case charge the battery at the rate given until each cell is 
gassing freely, and the specific gravity does not rise for five hours. 
The voltage of a charged battery is from 2.5 to 2.7, measured 
while the charging current is still passing through the battery. 

If the battery nameplate does not give the charging rate, start 
charging with a current which is equal to 1/8 of the ampere hour 
capacity of the battery. Charge at this rate for one hour, and 
then finish with a current which is equal to 1/20 of the ampere 
hour capacity of the battery. 

With most batteries, the filling plugs should be removed while 
eharging. When charging Exide batteries, however, there is a 
tendency to flood when the plugs are out. Many batterymen are 
not aware that a simple quarter turn of the movable hard rubber 
collar seen inside the well after the plug is removed will put it in 
the same position it occupies when the plug is in place, and will 
prevent flooding when the plug is removed. The reason for this is 
that when the plug is removed, this movable rubber collar closes 
the two vent holes in the cover. A quarter turn of the collar will 
move it from over the vent holes, allowing the accumulated gases 
to escape, and thus preventing flooding. The special design of 
this cover, as described on page 98 makes this necessary. Exide 
plugs may be removed to see if cells are gassing, but should be 
replaced immediately unless the collar is turned as described 
above. It is a good thing to make a Cadmium test (see page 266) 
on each battery while it is charging. If either positive or nega- 
tive plates show a decided loss of capacity, put in new plates. 

(b) If the specifie gravity of the electrolyte in a battery is 
around 1.150, the battery is completely discharged, and should 
be given a complete charge. Such a battery is very likely sul- 
~hated to a considerable extent, and it may require from one day 


WORK ON THE BATTERY 185 


to several weeks of continuous charging to bring it back to its 
full strength. Usually the charging current for a sulphated 
battery should be not more than five amperes. The current is 
governed by two things—(1) temperature, and (2) gassing. 

(1) Temperature. Have a thermometer on hand and measure 
the temperature of the electrolyte in each cell once every hour. 
If the temperature rises above 105°F, reduce the charging current 
so that the temperature drops to at least 90°F. 

(2) Gassing. A sulphated battery will begin to gas unless a 
low charging current is used. If any cell gasses, reduce the cur- 
rent immediately, as long continued gassing will cause excessive 
shedding. | 

If the temperature of the electrolyte does not rise above 105°F, 
and if the cells do not gas, the current may be increased. Never 
use a current that will cause a higher temperature or bring about 
gassing long before the end of the charge. Hf the specific gravity 
rises to 1.280-1.300 within 24 hours, the battery was not badly 
sulphated. If the rise in specific gravity is slower, continue the 
charge until there is no further rise for several days. If the 
gravity is then 1.280-1.300, the battery is rejuvenated. If the 
gravity will not come up to normal, it will be necessary to dis- 
charge the battery and then charge it again. It may be necessary 
to repeat this cycle of charge and discharge several times, before 
the plates are in a healthy condition. To discharge the battery, 
connect it to the Discharge Board (see page 133) and adjust the 
switches so as to draw from the battery a current whose value in 
amperes does not exceed one-tenth of the ampere capacity of the 
battery. Thus for an 100 ampere hour battery, the current should 
be 10 amperes. Discharge the battery until the voltage of each 
eell has dropped to 1.6 or 1.7. This voltage should be measured 
while the discharge current is still flowing. Then charge the bat- 
tery again, and discharge it, repeating the charge and discharge 
several times. This should remove most of the sulphate. 

When you discharge such a battery notice how long it takes 
for the voltage to drop to 1.6 per cell. Multiply this time by the 
discharge current, and if this product is very much less than the 
normal ampere-hour capacity of the battery, the plates have been 


186 THE AUTOMOBILE STORAGE BATTERY 


too severely damaged to be of further use, and the battery should © 


be opened. See page 187. 


(ec) If the temperature of one or all the cells in a battery rises | 


rapidly when the battery is put on charge, and if the specific 


gravity does not rise to at least 1.250, there is trouble in the bat- | 


tery, and it should be opened. See page 187. 

(d) If you are charging a battery at the normal rate, and the 
temperature does not rise above 109°F at any time, and if gassing 
begins before the specific gravity rises to 1.280-1.300, and the 
specific gravity will not rise to at least 1.280, it is probable that 
electrolyte has been spilled from flooding due to overfilling, or 
slopping, and has been replaced by water. In this case, draw off 
some of the electrolyte and replace it with electrolyte having a 
specific gravity of 1.400. This should be done while the cells are 
gassing. One hour after adding the electrolyte, measure the spe- 
cific gravity of each cell. If this is below 1.280-1.300, draw off 
more electrolyte and add 1.400 electrolyte. If the specific gravity 
is above 1.300, draw off electrolyte and add distilled water. In 
this way balance the electrolyte until it has the proper specilic 
gravity. | : 

If you now have time, put the battery on the discharge board 
and discharge at a current equal to about one-fifth of its ampere 
hour capacity. Multiply the current by the time required to cause 
the voltage per cell to drop to 1.6 or 1.7, and if this product is 
nearly equal to the normal ampere hour capacity, the battery will 
give good service. Then charge the battery at the normal rate, 
and it is ready for use. 

(e) If the specific gravity of a battery on charge rises above 
1.300, either acid or electrolyte have been added instead of water. 
Remove some of the electrolyte and add distilléd water in its 
place. When the cells are gassing, and the specific gravity does 
not rise in several hours, the electrolyte should have a specific 
gravity of 1.280-1.300, and if necessary, electrolyte should be 
drawn off and replaced with distilled water, or 1.400 electrolyte, 
depending on whether the specific gravity of the electrolyte in 
the battery is above or below 1.280-1.300. 

(f) It is generally considered necessary to give the battery an 
overcharge about once a month. An overcharge means that the 


’ WORK ON THE BATTERY 187 


normal charge rate is continued until the specifie gravity shows 
no further rise for three hours and at the end of this time the 
cells should be gassing freely. 

If a battery is kept properly charged, that is, with the specific 
gravity at 1.275 or above, an overcharge may do harm rather than 
good. The charge should never be continued to a point at which 
the voltage for each cell raises above 2.5. 


REBUILDING BATTERIES. 
To Open a Battery. 


This relates to batteries with burned-on connecting straps and 
terminals, and with compound poured on top of lower covers for 


Fig, 94. Before Rebuilding Fig. 95. After Rebullding 


sealing. Figure 94 shows the battery before rebuilding, and 
Figure 95 after rgbuilding. 

First, set the battery an the bench. See that the vent plugs are 
screwed in tightly. Then remove any dirt or grease from the top, 
sides, and bottom of battery. If the dirt and grease is thick, 
temove it with a putty knife. Then put the battery in the sink 

' and let the water run over it, using a stiff bristle brush to clean 
it. If you have no running water, put battery in a tub and clean 
it with.the brush. A large 4-inch paint brush is very satisfactory 
for this work, and it will last a year or more if well taken care of. 
If the battery is too greasy to be cleaned in this way, use a rag 


188 THE AUTOMOBILE STORAGE BATTERY 


Fig. 96, Drilling Posts and Top Connectors, with Battery in Special Box 


Fig. 97. Drilling Posts and Top Connectors 


WORK ON THE BATTERY 189 


dipped in gasoline. The object is to clean the battery thoroughly. 
When you have removed all tlte dirt, set the battery on the floor 
near your work bench, or in a shallow box about 4 to 6 inches 
high and 2 to 214 feet square, as shown in Figure 96. 

The next operation is to remove the connecting straps and ter- 
minals, You will need for this a large brace with a heavy chuck, 
a drill the same size as the post (the part that goes down into the 
battery), a large screw driver, center punch, and hammer. 

With the center punch, mark 
the exact center of the top of 
the post and connector. Then 
drill down straight about half 
way through the straps and ter- 
minals, as shown in Figure 97. 

Now pry off the connectors 
with the screw driver, as shown 
in Figure 98. A convenient tool 
to be used here to avoid damag- 
ing the top of the box with the 
serew driver is a length of one —*Fé- 98. Prylng of Connectors with 
inch angle iron, which is placed 
on the top edge of the box to protect it from the screw driver. 

If any connector is still tight, and you cannot pry it off, with a 
reasonable effort, bor2 down a little deeper, and it will come off 
easily, provided that the hole which you are drilling is exactly 
over the center of the post and as large as the post. There are 
five things to remember in drilling the connectors and posts: 

1. Be sure that the hole is exactly over 

the center of the post. 
2. Do not drill too deep. Make each 
hole just deep enough so that the con- 
nector will come off easily. Figure 99 
shows a cross section of a post and con- 
nector drilled to the proper depth. Notice 
that you need not drill down the whole 
Mig. 99 depth of the connector, because the bot- 

tom part is not burned to the post. 

8. Be sure that the drill makes the right sized hole to permit 


190 THE AUTOMOBILE STORAGE BATTERY 


the connectors and terminals to be removed easily when drilled 
half way through. An electric drill will do the work much faster 
‘ than a hand brace. 

4. Protect the edge of the battery box when you pry up the 
connectors with a screw driver. The angle iron is best for this 
purpose. 

5. Remove your drill after the hole is well started and see 
whether the hole is in the center of the post. Should you find 


Fig. 100, Straightening Hole Which was Started Off Center 


that it is off center, tilt the brace as shown in Figure 100, and 

with the end of the drill pointing toward the center of the post as 

you drill, gradually straighten the brace. This will bring the hole 
over the center of the post. 

y Having removed the connectors, take a whisk broom and sweep 
all the lead drillings from the top of the battery into a box kept 
for lead drillings only, Figure 101, or into the shallow box shown 
in Figure 96. When this box is full, melt the drillings in a large 
ladle, and pour off in the burning lead mold. 


WORK ON THE BATTERY 191 


The next step is to heat and remove the sealing compound s0 
that the covers may be removed. The compound must be heated 
to a temperature of about 200° 
Fahrenheit. Before you bring 
a flame near the battery, re- 
move the filler plugs and blow 
out any gas which may have 
collected above the plates with 
a hand bellows, Figure 102, or 
with compressed air. If you 
fail to do this, the flame may 
cause these gases to explode, 
with possible serious injury to 
yourself, 

The ease with which the com- 
pound is softened and removed 
depends entirely upon having 
the proper amount of heat, the 
proper length of time in apply- 

Fig. 101. Sweeping Lead Drillings ing it, and the way it is applied. 

Into Box The purpose is to heat the cov- 
ers and compound gradually, and not have too hot a flame, as a 
hot flame will burn’the hard rubber tops and wells, and ruin the 
threads in the wells. The compound must be heated uniformly 
to a temperature of about 200° Fahrenheit down to the bottom of 
the lower covers, in order to be able to remove it easily. 

The methods of heating the compound are: 

1. The common gasoline blow torch. This gives a very hot 
flame, and great care must be taken not to hold the flame on one 
spot for any length of time, otherwise the rubber tops, wells and 
threads in the wells will be ruined. If you use this torch, be sure 
that you have one that gives a large spreading yellowish flame, 
Figure 103. A concentrated, short blue tip flame is unsuitable for. 
this work. 

2. Natural or manufactured gas, mixed with air. This has al- 
ready been described. (See page 154.) Where such gas is availa- 
ble, this is a very convenient method to use. The flame is much 


192 THE AUTOMOBILE STORAGE BATTERY 


softer than that of the gasoline torch, and may be instantly ad- 
justed to any size by the thumb and forefinger of the hand holding 
the burner. Any of the flames described under ‘‘Lead Burning,” 
page 151, may be used. 

3. Figure 104 shows a four compartment sheet steel or iron box 
having two gas burners running the full length under a sheet iron 
plate extending the full length of the box, midway between the 
top and bottom. About one inch above this iron plate is a shelf 
of %4 inch to % inch transite board, which is reinforced under- 


Fig. 102. Blowing Gas out Fig. 108. Heating Compound 
of Battery with Hand Bellows with Torch 


neath by several angle iron supports. Two sliding doors divide 
one side of the box into halves. The doors slide up and down, as 
shown. 

When you wish to heat the sealing compound in opening a bat- 
tery, place the battery on the bottom shelf. When you wish to 
heat the bottom of the battery for removing a jar, place battery | 
on upper shelf. The temperature ean be regulated by turning the | 
flame up or down. It is a good plan to place a thermometer on 
top of the battery and not allow the temperature to rise above 
212° Fahrenheit. 


WORK ON THE BATTERY 198 


4, The Battery Steamer. This has already been described. See 
page 140. | 

You will need four screw drivers of the following dimensions 
for removing the compound: two with ten-inch blades, one with 


FOUR COMPARTMENT GAS HEATER 


Fig. 104 


an eight-inch blade ground rather narrow, and one with a six-inch 
blade. A one-eighth inch wood chisel is also useful for this pur- 
pose. Place battery on end of low work bench, Figure 55. With 
the compound properly softened, no matter what method you have 
used to soften it, heat the point of your large screw driver slightly. 


194 THE AUTOMOBILE STORAGE BATTERY 


Place tip of screw driver in one of the spaces between successive 
cell covers at the farther side of the battery, and hold it at an 


angle which will fit the beveled edge of the 
cevers. Press down on the handle and 
draw the screw driver toward you, using 
enough pressure to clean out all the com- 
pound in this space as you draw the screw 
driver toward you. In this way, remove 
the compound from all the spaces between 
cell covers, Figure 105. and also all around 
the edge of the case. It is easily and 
quickly done, and saves time in cleaning 
covers later on. 


Now, with a long screw driver in your" 


right hand, and the angle iron on the edge 


Fig. -105: Cleaning 
out Cracks ‘with Screw 
Driver 


of the ease, slip the point of the screw driver under a cover, as in 
Figure 106. The covers must be fairly limp, or you will break 


Fig. 106. Removing Top Covers with Screw Driver Resting on Angle-Iron 


them. They must also be well warmed in order to be.able to sep- 
arate them easily from the compound under them. ‘Push the 
screw driver point close to the posts, and gradually through to the 


WORK ON THE BATTERY 195 


other side, and carefully raise cover from Posts. In this way 
remove all the covers. 


If you do not use the angle iron to 
protect the edge of the case, keep the 
edge free from bruise marks caused by 
the screw driver by lifting the covers 
off with the screw drivers without 
touching the edges of the case. 

With the tops off, heat the point of 
the large screw driver pretty hot, and 
run it around each well, Figure 107, 
cutting the compound from them. If 
the wells are removable, take them 
out. Now sink point of large hot screw 
driver into the compound in the right 
hand corner of case next to you. Push 
the screw driver across that end of the 
ease, Figure 108, raising compound off 
the top of jar and the end of the ease. 
Follow this by pushing. screw driver - 

Fig. 107. Digging Com- along opposite side of case and tops of 

mith Hot Berew Dever jars. Then sink screw driver in com- 

pound at the corner at which you be- 
gan; and in a similar way remove compound from tops of jars and 
inside of case on the side next to you, the left hand end, and top 
edges of jars between cells, Figure 109. Gather up the loose 
pieces of compound and put the compound box under the tool 
scraper on your work bench. ._Remember that the end of the screw 
driver must be warm at all times, but not sizzling hot. Clean the 
screw driver on the tool scraper whenever necessary to keep the 
point clean. 

Now, sink the warm point of the large screw driver in the com- 
pound at the inside corner of the jar to your right, and push along 
the inside of the jar to the opposite side. Follow up in this way 
all around the inside of the jar, clear down to the top of the lower 
cover, Figure 110. If the compound is not warm enough to do 
this easily, heat it a little with the flame. In this way remove all] 


196 THE AUTOMOBILE STORAGE BATTERY 


the compound systematically from top of the lower cover, and the 
inside well of the jar of every cell. 

Try to make every motion of screw driver cut out a mass of 
compound fully as wide as the screw driver point. In opening 
small batteries, you must use a smaller screw driver, but always 
use as wide a screw driver as possible to save time. 

Gather up the loose compound and put in compound box under 
tool seraper. If the lower covers and tops of jars have become 


Fig. 109. Removing Com- 

pound from Edge of Case 

Fig. 108. Cleaning Compound from and Tops of Jars with Hot 
‘Top Edge of Jars at End of Case Screw Driver 


hard, play the flame over them until they are pliable, but take 
care not to burn them. Then run a hot putty knife around the 
edges of the covers, so as to remove the compound from the crack 
between the covers and jars. Using a pair of crooked-nose pliers, 
lift out the elements from each jar, as in Figure 111, and rest on 
the edge of the case to drain. If the covers are pliable, remove 
them as in Figure 112. 

Now is a good time to clean all the top and lower covers and 
wells, and put in a properly labeled box as described on page 139. 


. WORK ON:THE BATTERY 197 


Fig 110. Digging Compound from Covers 


Fig. 111. Lifting Elements Out of Jars, and Resting on Edge of Case to Drain. 
Note that Cell on the Left Has been two-thirds Dry 


198 THE AUTOMOBILE STORAGE BATTERY 


° Fig. 112. Taking Of Covers with Two Screw Drivers 


‘What Must Be Done? 


The battery is now open, and in a condition to be examined and 
judgment pronounced upon it. The question now arises, ‘‘What 
must be done with it.’’ In deciding upon this, be honest with 
your customer, put yourself in his place, and do just what you 
would like to have him do if he were the repairman and you the 
ear owner. The best battery men occasionally make mistakes in 
their diagnosis of the battery’s condition, and the repairs neces- 
sary. Experience is the best teacher in this respect, and you will 
in time learn to analyze the condition of a battery quickly. 

You may have some trouble in deciding what must be done 
with the battery,—whether you should merely free any short- 
circuits, and charge it, or put it through several charges and dis- 
charges, or whether you must cut off some of the plates and re- 
place with good ones. 

It is absolutely necessary for you to have a standard method 
in working on the battery plates. You must divide your work 
into a number of definite steps, and always perform these steps, 
and in the same order each time. If you have a different method 


WORK ON THE BATTERY 199 


of procedure for every battery, you will never be successful. The 
preliminary work on the plates should be divided into the follow- 
ing steps: 

1. Examine plates to determine whether they can be used 
again. Rules for determining when to discard or use old plates 
are given below. 

2. If all plates of both positive and negative groups are to be 
discarded, cut off the old ones and burn new ones on the plate 
strap. 


Fig. 113. Group on Block for Examination 


3. If you find that only some of the plates are to be discarded, 
or if you are not certain as to the condition of the plates, free any 
short cireuits which may exist, and give the battery a preliminary 
charge, as described later, before you do any work on the plates. 
Plates that are fully charged are in the best possible condition 
for handling, and you should make it an iron-clad rule that if 
some of the plates can be used again-always to charge a battery 
before you work on the plates, no matter what is to be done to 
them. Very few batteries will come to your shop in a fully 
charged condition, and an exhausted battery is not in a good 
condition to be worked on. Charge the whole battery even though 
only one cell is in a very bad condition. 

To make the examination of the plates, proceed as follows: 


200 THE AUTOMOBILE STORAGE BATTERY 


Place a group on block of wood as shown in Figure 113. With 
@ putty knife or screw driver, carefully pry the plates apart so 
that you can look down between them and make a fair preliminary 
examination. Whenever possible, make your examination on the 
plates without separating the groups or removing the old sep- 
arators. This should be done because: 

(a) Very often the active material is bulged, hard, and sul- 
phated, and if you pull out the old separators and put in new 
ones before charging, the element spreads out so at the bottom 
that it cannot be put back into the jars without first pressing in 
a vise or plate press. 

(b) If you put in new separators before giving the battery the 
preliminary charge, the new separators will become clogged up 
with any impurities which may be on the plates, and will prob- 
ably be cracked by forcing them between the bulged and sul- 
phated plates. 

If, however, you are not ab- 
solutely certain as to the condi- 
tion of the plates, draw out a 
few separators. Removing a 
few separators will permit you 
to separate the groups before 
removing the rest of the sep- | 
arators. To separate the groups. 
grasp a post in each hand, as in 
Figure 114, and work them 

Fig. 114. Separating The Groups back and forth, being careful 

not to injure the posts, or break 
off any plates. With the groups separated, the remaining sep- 
arators will either fall out or may be easily pushed out with @ 
putty knife. Ordinarily, the groups may be separated in this war 
if the elements have thirteen plates or less. 

The natural thing to do at this point is to decide what must be 
done to the plates, and we therefore give a number of rules ti 
help you to determine which are to be junked, and which are to 
be used again. Study these rules carefully, and have them fisel 
firmly in your mind so that you can tell instantly what must le 
done with the plates. 


WORK ON THE BATTERY 201 
‘When to Put In New Plates. 


1, If one or more jars are cracked and leak, and positive plates 
have been ruined by freezing, as shown in Figure 115, and if upon 
drawing out the separators, and separating the positive and neg- 
ative groups the active material drops out of the grids, the only 
way to put the battery in a good condition is to cut off the positive 
plates and burn in good ones. 


Fig. 115. Positives from a Frozen Vehicle Cell. Note Active Material Sticking to 

the Rubber Separator 

Make a careful estimate of 

(a) Cost of new jars. 

(b) Cost of new plates. 

(e) Cost of new case if needed. 

(d) Cost of labor required. 

Call up the owner, tell him what the total cost will be, and if 
he has no objections, go ahead with the job. If he is not entirely 
satisfied with your price, try to get him to come to your shop. 
Then show him the battery, explain its condition, tell him just 


202 THE AUTOMOBILE STORAGE BATTERY 


what must be done with it, and explain how you made your esti- 
mate of the cost of the whole job. If you do this, there will 
never be any misunderstanding as to cost. Tell him the cost of a 
new battery, and let him decide if he wants one. If the cost of 
repairing is within five dollars of the price of a new battery, ad- 


Fig. 116. Diseased Negatives. The Large Ones only Eight Months Old. Active 
. Material Blistered, Soft, and Granulated 
vise him to buy a new one, but allow him to make the decision 
himself. He will then have no cause for complaint. 
2. If the battery is from two to three years old, and the active 
material on the negative plates is bulged, more or less granulated 
(grainy appearance), figure 116, and somewhat disintegrated ; if 


Fig. 117. Weak and Cracked Positives 


the positive plates are weak and brittle around the edges, and 
several are cracked, figure 117, and have lost a considerable 
amount of paste; and if the case has been rotted by the acid, the 
battery should be junked. 

Whenever the active material on the positive plates has shed 


WORK ON THE BATTERY 203 


so that it has filled the bottom of the jar until it touches the 
plates, put in a new set of plates. 

Call up the owner, and tell him he needs a new battery. If 
he does not seem pleased, ask him to come to your shop. Then 
show him his battery, and explain its condition. If you are 


Fig. 118. Buckled Plates. Do not use such Plates again 


Fig. 119. Badly Buckled Plates 


courteous and patient, you will sell him a new battery. Other- 
wise he will never return. 

3. If the positive paste is hard, cracked, and shiny, it is 
badly crystallized and will no longer give good service, new 
positive plates should be installed. Such a condition is usually 


204 THE AUTOMOBILE STORAGE BATTERY 


caused by charging while the electrolyte is below the tops of the 
plates. 

4. If the positive plates are badly distorted from buckling, 
as in figures 118 and 119, they will cut through new separators, 
if put into commission again, in from two to six months. 

5. A battery which has been dry and badly sulphated at some 
past period of its life will have the dry portions covered with a 
white sulphate, the acid line being clearly distinguishable by this 


Fig. 120. Corroded, Bulged and Sulnhated Negatives. Disintegrated, Rotted 
. Positives 


white color, as shown at A and B in figure 113. The positives 
will be warped and its active material badly blistered or fallen 
out. The parts of the separators above the electrolyte will have 
been deteriorated, and new separators should be put in. Cor 
roded and sulphated grids should be looked for carefully, as in 
figure 120. In corroded grids, the pastes cannot make good con 
tact. with the grids, and the capacity will be lowered in propor- 
tion to the extent of the corrosion. No amount of charging vill | 
remove all of the corrosion, as some of the deposit is insoluble, it- 
sulating the grids from the active material, and making it difficult 


WORK ON THE BATTERY 205 


for a charging current to pass through. Such a battery will 
become very hot, even with a charging rate below normal. 

Corroded batteries are always sluggish, and very little can be 
done to help them; discard them if possible, as they are trouble 
breeders. It is needless to say that both positives and negatives 
are subject to corrosion. 


Fig. 121. Disintegrated Positives 


Fig. 122. Side, Bottom, and End View of Elements Taken from Traveling Sales- 
man’s Car who Made Long Daylight Tours 

If you want to try to bring such plates back to life, try charg- 
ing at a low rate of about three amperes. The length of time 
tequired may be several weeks or more. Be careful not to allow 
temperature to rise above 105°. When the specific gravity will 
no longer rise, connect the battery to the discharge board and 
discharge to 1.8 volts per cell with current still flowing, using a 
current equal to about one-eighth to one-tenth of the ampere hour 


= 
206 THE AUTOMOBILE STORAGE BATTERY 


capacity. Do this charging and discharging before reassembling. 
Lower the elements into the jars and connect the posts together,— 
positive to negative,—as described on page 213. 

6. Rotten and disintegrated positive plates, figures 120 and 
121, must be replaced with new plates. The plates have fallen to 
pieces or break at the slightest pressure. Disintegrated plates 
are an indication of impurities or overcharging, providing the bat- 
tery is not old enough to cause disintegration normally,—say about 
fifteen months. The lead grid is converted into peroxide of lead 
and becomes soft. As a result, there is nothing to support the 
paste, and it falls out. Better put in new negatives also. 

7. Overcharged batteries have burned and earbonized separa- 
tors, turning them black and rotting them; the negative paste 
is kept in a soft condition, and gradually. drops from the grids 
on account of the jolting of the car on the road. Figure 122 
shows plainly the result of overcharging. and overheating. This 
battery was only three months old when it went dead. The 
owner was a traveling’ man who made long trips of.one hundred 
or two hundred miles several times a week. He did not use the 
starter often during the day, and did not drive at night, and the 
battery was consequently overcharged. Notice from the illus- 
tration: 

(a) What happens to one cell, happens to all, differing only a 
little in degree. 

. (b) Carbonized, rotten separators. 

(c) Buckled plates cutting through rotten separators. 

(d) Softened active material in negative plates, and dropping 
out of grid. 

8. Dry, hard, and white, long discharged, and badly sulphated 
plates, figures 113 and 120, are practically ruined, though if the 
trouble is not of long standing, the plates may be revived some- 
what by a long charge at a very low rate, and then discharging 
at a current equal to about one-eighth to one-tenth of the ampere 
hour capacity of the battery at the discharge board. Charge and 
discharge a battery a number of times, and you may be able to 
put a little ‘‘pep’’ into it. In charging sulphated positive plates, 
use aS much current as possible, without allowing gassing before 


- 
WORK ON THE BATTERY 207 


the end of the charge, or a temperature of the electrolyte above 
105°F. 

9. When positive paste has become softened considerably. 

10. If a battery case is not held down firmly, or if the ele- 
ments are loose in the jars, the plates will jump around when 


Fig. 123, Element From a “Sloper.” Element was Loose in Jar, and Jolting of 
Car Caused Active Material to Fall From Grids 


the car is in motion. This will break the sealing compound on top 
of the battery, and cause the battery to be a slopper. The active 
materials will be shaken out of the grids, as shown in figure 123, 
New plates are required. 


208 THE AUTOMOBILE STORAGE BATTERY 
When the Old Plates May be Used Again. 


11. If one or more plates are broken from the plate connecting 
straps, or the joint between any strap and the plate is pocrly 
made. If plates are in good condition, reburn the plate lugs 
to the straps. 

12. Straight rebuild. If the general condition of the battery 
is good, ie., if no jars are cracked, the plates straight and not 
warped, no paste shed, no white sulphate on either plates, the 
active materials not bulged out, the grids not brittle, paste 
adhering to and firmly touching the grids, the positive paste of 
a chocolate brown color and fairly hard (as determined by 


Fig. 124. Badly Bulged Negatives, Such Plates Need Pressing 


scratching with blade of a pocket knife), the negative paste light 
gray in color and softer than the positive paste, and the plates not 
too thin, make a straight rebuild. To do this, remove any sedi- 
ment from the bottom of the jar, clean the parts, insert new sep- 
arators, and reassemble as directed later. 

13. Badly bulged negative plates, figure 124, cause lack of 
capacity because the-paste is loose, and does not make good con- 
tact with the grids. If the paste is not badly granulated (having 
a grainy appearance), the plates can be used again. 

14, Positives which are only slightly warped or buckled may 
be used again. 

15. When the only trouble found is a slight amount of shed- 
ding. Positive paste must be of a chocolate brown color and 
fairly hard. Negatives must be a light gray. 


WORK ON THE BATTERY 209 


16. When the plates are in a good condition, but one. or more 
separators have been worn or cut through. 


Separators, 


It is the safest plan to put in new separators whenever a bat- 
tery is opened, and the groups separated. Separators are the 
weakest part of the battery, and it is absolutely essential that all 
their pores be fully open so as to allow free passing of electro- 


Fig. 125. Separators worn thin and cut through on edges by Buckled Plates. Holes 
‘worn through by Bulged Active Material. Center puir shows Cell was dry two thirds 
of the way down 
lyte through them. Some of the conditions requiring new sep- 
arators are: ° 

1. Whenever the pores are closed by any foreign matter what- 
soever. Put in new separators whether you can figure out the 
cause of the trouble or not. The separator shown in figure 113 
is sulphated clear through above the line B. The separator shown 
in figure 115 should not be used again. 

2. When the separators have been cut or ‘‘chiseled off’? by 
the edge of a buckled plate, figure 125. 


210 THE AUTOMOBILE STORAGE BATTERY 


3. When a buckling plate or plate with bulged active material 
breaks through the separator, figure 125. 

4, When a battery has been used while the level of the elec- 
trolyte has been below the tops of the plates, or the battery has 
been used in a discharged condition, and lead sulphate has de- 
posited on the separators, figure 113. 

5. When a battery has been 
over-heated by overcharging or 
other causes, and the hot acid has 
rotted, burned and carbonized the 
separators, figure 126. . 

6. When a battery has been 
damaged by the addition of acid 
and the separators have been 
rotted, figure 126. 

When you have put in new sep- 
arators, and put the battery on 
charge, the specific gravity of the 
electrolyte may go down at first, 
instead of rising. This is because 
the separators may absorb some of 
the acid. If the battery was dis- 
charged when you put in the new 
separators, the lowering of the 
specific gravity might not take 

Fig. 126. Rotted Separators place, but in most cases the 
specific gravity will go down,.or 
not change at all. 

Separators kept in stock must be placed in a jar and kept 
moist with water to which a slight amount of sulphurie acid 
has been added. Never allow them to be dry, as this makes 
them very brittle and hard to handle. 

A tight lead lined box may be used for storing separators. 
Instead of covering them with water, a pad of ducking placed in 
the box and kept wet will keep the separators in first class con- 
dition for months. The separators must be packed closely and 1 
compactly. In dry, hot weather, sprinkle the separators occa- 
sionally with distilled water. 


WORK ON THE BATTERY 211 
Find the Cause of Every Trouble. 


The above conditions must be studied carefully and be clearly. 
tabulated in your mind to be able to tell what to put into com- 
mission again and what to discard as junk. It will take time to 
learn how to discriminate, but keep at it persistently and per- 
severe, and as you pass judgment on this battery and that bat- 
tery, ask yourself such questions as: What put this battery in this 
condition? Why are the negative plates granulated? Why are 
the positive plates buckled? What caused the positive 
plates to disintegrate? Why are the separators black? 
Why is the case rotten when less than a year old? ‘Why 
did the sealing compound crack on top and cause the electro- 
lyte to slop? Why did one of the terminal connectors get loose 
and make a slopper? Who is to blame for it, the car manufac- 
turer, the manufacturer of the battery, or the owner of the car? 
Why did this battery have to be taken off the car, opened up and 
rebuilt at 5 months old, when the battery taken off a car just the 
day before had been on for 30 months and never had been charged 
off the car but once? There is a reason; find it. Locate the cause 
of the trouble if possible, remove the cause; your customer will 
appreciate it and tell his friends about it, and this will mean more 
business for you. 

From these conditions, you see that most of the trouble i is with 
the positives: 

(a) Because the positive active material does not stick together 
well, but drops off, or sheds easily. 

(b) Because the positives warp or buckle, this causing most of 
the battery troubles. 

(c) Because the positive plate is weaker and is ruined by freez- 
ing. 

Freeing ‘‘Shorts.’’ 


If you have decided that some or all of the plates may be used 
again, the next thing to do is to separate any plates that are 
touching, and put the battery on charge. It may be necessary to 
put in new separators in place of the defective ones. Examine the 
separators carefully. Whenever you find the pores of the sep- 


212 THE AUTOMOBILE STORAGE BATTERY 


arators clogged up from any cause whatsoever, put in new sep- 
arators before charging. 

1. Sometimes the negative plates are bulged or blistered 
badly and have worn clear through the separators, figure 125, and 
touch the positives. In cases of this kind, to save time and 
trouble, separate the groups, press the negatives lightly with 
transite boards between them, as described later, assemble the 
element with new separators, and it is ready for charging. 

2. There is another case where the groups must be separated 
and new separators inserted before they will take a charge, and 
that is where the battery has suffered from lack of water and 
has sulphated clear through the separators, figure 114. The sep- 
arators will be covered with white sulphate. Chemical action is 
very sluggish in such cases. 

If you find that the separa- 
tor pores are still open, leave 
the separators in place and pro- 
ceed to separate the plates that 
are touching. How? That de- 
pends on what insulating ma- 
terial you have available that is 
thin enough. If nothing else is 
available, take a piece of new 
dry separator about 3% inch to 
Y% inch square, or a piece of 
pasteboard the same size. Use 
a screw driver or putty knife 
to separate the plates far 
enough to insert the little piece 
of insulation as in figure 127. 

Free all the shorts in this way, 

unless you have some old, per- 

forated, hard, sheet rubber 

available from Vesta, Exide or Fig, 127. Freeing Shorts 

vehicle batteries. In this case, 

break off some narrow strips 34 inch wide or less, put two together | 
and repeat the operation as above, using the rubber strips instead 
of the pieces of separator. Insert down 1 inch or so and bend 


WORK ON THE BATTERY 213 


over and break off; then repeat with the rest of the shorts until 
all plates have hard rubber between them. Occasionally the 
upper edges of the plates are shorted out, in which case they 
must be treated the same way. 


Charging. 

When you have in this way 
freed all the ‘‘shorts’”’ in the 
elements place the elements 
back in the jars in the same 
Position as they were when 
you opened the battery, and 
add enough distilled water to 
the electrolyte to cover the 
plates to a depth of one-half 
inch. The next operation is to 
put the battery on charge. 
Grasp each post in the jaws of 
a pair of gas pliers and work 


the pliers back and forth, fig- Fig,.128. Cleaning Scale From Posts 
ure 128, so as to remove the porarity for Charging 


seale and allow the connecting 

straps to make good contact. Now take a knife and cut off the 
rough edges left in the connecting straps by the drill. Taper the 
edge, if necessary to go on 
post. Turn the connectors up- 
side down and pound gently in 
position, figure 129, to make a 
good connection. This being 
properly done, the battery is 
ready for charging. Check up 
the connections to be sure they 


229. Tapping Connectors in are correct. 
muse srnpertiny cums =—«-sNow put the battery on 


and Shorts Removed charge, and charge at about 


one-third of the starting charge rate in amperes. Do not allow 
the temperature of any cell to rise above 106°F. Continue the 


214 THE AUTOMOBILE STORAGE BATTERY 


charge until the electrolyte clears up, and its specific gravity tests 
1.280-1.300, and the plates have a normal color. Fully charged 
positive plates have a chocolate brown color, and fully charged 
negative plates have a light gray color. Do not take the battery 
off charge until you have obtained these results, although it may 
be necessary to continue the charge for two, three, four, or five 
days. The battery must stay on charge until you have the 
desired conditions. If one cell does not charge,—that is, if its 
specific gravity does not rise,—you have probably not freed all 
the shorts, and must take the element out of the jar again and 
carefully inspect it for more shorts. 

Right here is where one of the most important questions may 
be asked about rebuilding batteries. Why must you free the 
shorts and put the battery on charge? Why not save time by 
putting in all new separators, sealing the battery, burning on the 
top connectors, and then putting it on charge? If you have ever 
treated a battery in this way, what results did you get? Why 
did you have a badly unbalanced gravity of electrolyte? How 
could you know what specific gravity electrolyte to put in each 
cell? Perhaps one was charged, one only half charged, and the 
other dead. Suppose the dead cell had impurities in it. How 
could you get rid of them? Suppose the battery showed poor 
capacity on test, what would you do? 

The battery is put on charge because you cannot, do an A No. 1 
job of repairing in any other way. The chemical actions caused 
by the charging current passing through the cells for a long 
time have: : 

(a) Removed all possible impurities, with the exception of 
iron, which is sometimes permanent. 

(b) Worked the active materials and put them in a healthy 
condition, just as exercise strengthens your body and improves 
your health. 


(c) Put all the plates in the same condition chemically, so that — 


all can be handled further in the same way. 

(d) Put the plates in the best possible condition to be worked 
on. The positive plates are as soft as they can be made to be. 
They can now be straightened more easily and with less danger 
of cracking. The negative plates are also as soft. The spongy 


WORK ON THE BATTERY 215 


lead is in the best condition to press firmly into the grids, as 
described later. 

Let it be impressed on your mind that the foregoing is one of 
the most important factors in the rebuilding of batteries. Your 
success in rebuilding old batteries depends much upon the 
thoroughness with which you follow these instructions. If you 
want to succeed, you must be careful and accurate. You cannot 
expect to have your rebuilt batteries efficient and deliver their 
proper amount of current if worked over in a careless, haphazard 
and know-not-why method. 

The minute you begin to use this Standard Method and follow 
instructions minutely, you emerge from the guess way, the know- 
not-why, indefinite way, groping from one operation to another. 
The auto battery business has arrived at a stage where the bat- 
tery owner demands better work and will find the man who knows 
how to do the work in the right way, not occasionally by the 
guess way, but can tell him how it should be done, and why it 
should be done, and show him by his finished work that he can 
do as good work as the factory, because he specializes on old bat- 
teries and takes time and pains with each job. Impress upon 
your mind the importance of doing every job the very best you 
possibly can by a Standard process. Make the rebuilt battery 
look as neat, and good as a new battery, so that you will not be 
ashamed to put your name on it. 


Washing and Pressing. 


To continue the actual work on the battery. The battery being 
fully charged,—the electrolyte clear, the plates of normal color, 
the specific gravity no longer rising,—remove it from the charg- 
ing bench and put it on the work bench. Draw each element and 
let drain as in figure 111. 

Here again the labelled boxes described on page 139 come in 
handy. Separate one group, remove the separators, and put one 
sroup in each end of box to keep clean. Separate another group, 
and nest the plates, figure 180, the negative with the negative, 
and positive with positive. Separate the third element and put 
groups in the boxes. You now have the plates in the best possible 
shape for handling. Take the boxes containing the plates to the 


216 THE AUTOMOBILE STORAGE BATTERY 


sink. Ilave a vise or press and the transite boards ready for use. 
If, for any reason, you are called away from your work at this 


Fig. 130. Nested Plates in Handy 
Box for Keeping Them Clean 


point to be gone for five min- 
utes, do not leave the fully 
charged negatives exposed to 
the air, as they will become 
very hot and will be injured. 
Cover them with water. A 
one-gallon stone or earthen- 
ware jar will hold the negative 
plates of a 100 ampere hour 
battery if you nest two of the 
groups. You may also put 
negatives back in jars from 
which they were taken, and 
fill with water. 


Now hold a negative group under the faucet, and let a strong 
stream of water run down over each plate so as to wash it 


thoroughly, and to remove 
any foreign matter from the 
plate surfaces. This is one 
of the ‘‘standard’’ opera- 
tions, and all negative groups 
must be handled in exactly 
the same way so as to get the 
same results in each case. 
After you have washed the 
first group, place it on edge 
on a clean board with the 
post down and pointing 
away from you, and the bot- 
tom of the group toward 
you. Now insert transite or 
hard wood boards which are 
slightly larger than the 


Fig. 131. Inserting Transite Boards 


Between Negatives, Preparatory to 
Pressing 


plates, and of the exact thickness required to fill the spaces be- 
tween plates, figure 131. For the standard 14 inch plates, the 


WORK ON THE BATTERY 217 


boards should be 9-32 inch thick. If you do not happen to have 
boards of this thickness, use two boards, each 1 inch thick and 
a plece of cardboard 1-32 inch thick. Never push the boards 
more than 14 inch above the tops of the plates, and be sure that 
they cover the entire plates. 

Obtain two blocks, each 144 to 2 inches thick, 6 inches wide, 
and 7 inches long. To the end of one of these, nail a piece 1 
inch thick, 6 inches long, and 6 inches wide, this latter piece to rest 
on the sliding jaw and inside of the vise, and the 6 by 7 piece 
against the Jaw farther from you. Place the negative group in the 
vise, and resting on the 6 by 6 piece at the bottom of the vise. 
Place the second 6 by 7 piece against the movable jaw of the vise. 
Be careful not to let either of the 6 by 7 blocks extend more than 
1% inch beyond the top of the plates, or you may break off some 
of them. 

Now screw up the vise as tightly as you can. While this 
group is in the vise, hold another negative group. under the 
faucet and wash it thoroughly, and place on a board as you did 
the first one. Take the first group out of the vise, and put it to 
the left of the group on the board. Take the transite boards 
out of the group removed from the vise, and put them in the 
second group. Now put the second group in the vise. Put the 
first group in the box to protect it from injury. Repeat this 
operation for the third group of negatives, and you have the neg- 
atives in as good a condition as it is possible to get them. All 
three groups may be pressed at once in the Plate Press, as shown 
in figure 77. If you have done the job in a first class work- 
manlike manner, the negatives will pass inspection by the most 
expert battery man, and be pronounced O.K. Many negative 
groups treated by this process will be good after fifteen months 
to two years of service after reassembling, and will, at the end 
of that time, really justify a rebuild. Keep the negatives in a 
stoneware jar filled with water. Never expose fully charged 
negatives to air more than five minutes. 

The next step is to wash the positives. These should not be 
held under the faucet as were the negatives, as this would dis- 
lodge much of the active material. Dip the positives up and 
down a number of times in a jar of clean water to remove im- 


218 THE AUTOMOBILE STORAGE BATTERY 


purities and wash off foreign or loose materials from the surfaces 
of the plates. As you wash each positive group, replace it in the 
box to protect it from injury. 

The groups are now ready to be worked on. If you have 
decided to burn on several new plates, proceed as described below. 
The negatives which are to be used again require no further work, 
as the charging, washing, and pressing have put them in the best 
possible condition. Positives which are to be used again should 
now be straightened if they are warped or buckled. Positive 
plates, when fully charged, and just taken out of the cell, may 
be straightened somewhat by inserting between them transite 
boards the exact thickness of the distance between the plates, and 
pressing the group slowly in a vise or Plate Press for five minutes. 
Do not apply too much pressure. If the edges are still buckled, 
use a pair of thin, wide nosed pliers and straighten them, being 
very careful not to crack the edges. Do not straighten all the dis- 
tortion at any point at once, but move the pliers all along the 
edge, bending only a little at a time until the plate is straight. If 
you are careful,.and straighten all four edges, and not much 
paste has dropped from the grids, it may be possible to use the 
plates again. If the plates are only very slightly buckled, 
straighten them with pliers only, and put them back in commis- 
sion. 


Burning on Plates. 


When you put new plates into a battery, or find some of the 
plates broken from the connecting strap, it will be necessary to 
burn the plates to the strap. Frequently you will find plates 
which are otherwise in a good condition broken from the con- 
necting straps. This is most likely to happen when the plates 
have been cast on to the connecting strap. instead of being 
burned on. These plates must be burned on. 

New plates are frequently necessary. From pages 201 to 207 
you see that new plates are required under the following con- 
ditions: 

(a) Positives. Ruined by freezing; weak and brittle from age, 
with large part of active material shed; hard, cracked, and 


WORK ON THE BATTERY 219 


shiny active material; badly buckled; charged while dry; rotten 
and disintegrated by impurities; ruined by overcharging; badly 
sulphated because allowed to stand idle, or used while dis- 
charged; softened active material. 

(b) Negatives. Active material granulated, bulged, and dis- 
integrated; charged while dry; positives disintegrated’ by im- 
purities; ruined by overcharging; badly sulphated because 
allowed to stand idle, or used while discharged, or active ma- 
terial dropped from grids. 


Fig. 182. Burning. Rack 


When making plate renewals, never install plates of different 
design or age in the same group. Always use plates of the type 
intended for the battery. The positive group need not be of the 
same age as the negatives, however, but all the plates of one group 
should be of the same age and type. 

The following directions will explain every step in burning 
plates to the straps. The battery should first be fully charged, 
as already explained. If all the plates in a group are to be dis- 
carded, clamp the post in a vise, being careful not to crack the 
hard rubber shell if one is on it, or to damage the threads on posts 
such as the Exide, or to draw up the vise so tightly as to crush 
the post. Then saw off all the old plates with a hack saw, close 


220 THE AUTOMOBILE STORAGE BATTERY 


to the post as shown in figure 132 at A. This separates the entire 
group of plates from the post in one short operation. This method 
is much better than the old one of sawing the plates off below 
the connecting strap, and sawing or punching the old plate ends 
out of the strap. 

Now set the new plates in the rack, figure 132, and set the ad- 
justable guide bar so that the tops of the lugs on the plates extend 
above it a distance equal to the thickness of that part of the plate 
strap which is still attached to the post. With the plate lugs in the 
slots of the guide bar, put the bar shown at B in figure 132 in 


Fig. 133. Sawing Slot in Plate Connecting Strap 


place and fasten it with two loops of wire as shown. Tie some 
asbestos around the post, and put in position as shown, one edge 
resting on the bar B, and the other held up by two wooden 
wedges. Next place the U-shaped piece of iron around the ends of 
the plate lugs, and the post, as shown at C in figure 132. This 
prevents the melted lead from running off. Clean the surfaces 
of the lugs and edge of the part of the old connecting strap still 
attached to the post. 

Now apply your lead burning flame, and heat up the ends 
of the plate lugs and the edge of the part of the strap 
attached to the post, until they begin to melt. Then melt in 


WORK ON THE BATTERY 221 


burning lead until the tops of the plate lugs are just- covered. 
This will give you a perfect joint between the post and the plates, 
and will require much less time than if you had sawed off all the 
plates below the connecting strap, and had sawed out the ends of 
the plate lugs. 

If one or two of the outside plates only are to be renewed, 
saw these off just below the connecting strap. If one or more of 
the inner plates are to be removed from the group, grasp the 
plate lug near the connecting strap with a pair of long and rather 
flat nosed pliers. Bend the plate back and forth with the pliers 


Fig. 134, Slotted Saw, a group with two Plates removed, and Slots in Connecting 
Strap for New Plates. 
until it breaks off. Battery manufacturers make and sell special 
plate punches for removing individual plates, and these may be 
used instead of slotting with a saw. 

Waving removed the defective plates, saw slots in the strap, fig- 
ure 133, exactly in the same place where the old lug was burned 
in. Make the slot of the proper depth for the lug of the new 
plate. Figure 134 shows the slotting saw, the group in the vise, 
and the defective plates to one side. Two regular slotting saws 
are placed in an ordinary hack saw frame so as to saw the full 
width of the slot, 14 inch, in one operation. 

Figure 135 shows the method of lengthening a plate lug. It 
will be necessary to Jengthen the lugs on plates which have been 


222 THE AUTOMOBILE STORAGE BATTERY 


broken from the strap, but which are otherwise in a good con- 
dition, and are to be used again. For a guide use a piece of 1% inch 
thick strap iron, 34 to 1 inch wide. Cut notches in this iron hav- 
ing the same width as the plate lug which is to be lengthened, 
and put the iron and the plate on a sheet of asbestos, figure 135. 
Melt the lead in the notch until the desired length is obtained. 
Mount the group and the new plate in the burning rack, similar 
to the way shown in figure 132, with the lug of the new plates 


Fig. 135. Extending Lug on Plate 


fitting in the slots which you sawed in the connecting strap. Clean 
all the surfaces which are to be melted together, and melt in the 
burning lead as previously described. 


Reassembling the Elements. 


Take a negative group and put it on edge on a board, with post 
away from you, and lower edge toward you. Examine the ‘‘hold 
down’? blocks, figure 3; if one side has been worn slightly 
by the separators but the block is otherwise in a good condition, 
turn it over, and place worn side toward the top; if any hold down 
is soft and rotten, replace it with a new one. Always make sure 


WORK ON THE BATTERY 223 


Fig. 186. Putting In New Separators 


Fig. 187. Trying on a Top Cover 


224 THE AUTOMOBILE STORAGE BATTERY 


that the hold downs are in good condition, and are securely 
fastened. . 

Take a positive and a negative group and place in position as 
in figure 136. The groups are now ready for the separators. Take 
six separators in your left hand and bend as shown in figure 136. 
Take one with your right hand and slip it into position from the 
bottom in the middle of the group, with the grooved side toward 
the positive plate, as in figure 136. Take another separator from 
your left hand and slip it into position on the opposite side of the 
positive against which your first separator was placed. In this 
way, put in the six separators which you are holding in your left 
hand, with the grooved side toward the positives, working out- 
ward in both directions from the center. 

Now grasp the element in both hands, and set it right side up 
on the block, giving it a slight jar to bring the bottoms of the 
plates and separators on a level. 

SS Next take a top cover, and try it 
on the posts, figure 137. Pull the 
groups apart slightly, if necessary, 
before inserting any more separators, 
so that the top fits exactly over the 
posts, figure 138. See that the sep- 
arators extend the same distance be- 
yond each side of the plates. You 
may take a stick, about 10 inches long. 
114 inches wide, and % inch thick, 
and tap the separators gently, figure 
189, to even them up. If you put in too 
many separators before trying on the 
cover, the plates may become so tight 
that you may not be able to shift them 
to make the cover fit the posts or you 


Tie 38. Getting Poss may not be able to shift the separators 
pare eonetators are” in to their proper positions. It is there- 
Place fore best to put in only enough separ- 


ators to hold the groups together and so they can be handled and 
yet remain in their proper position when set up on block. 


WORK ON THE BATTERY 


Fig, 139. Tapping the Separators 
Gently ‘to Make Them Even on 
Both Sides of Plates 


225 


With the element reassem- 
bled, and the remaining separ- 
ators in their proper positions, 
see that all the plates are level 
on bottom, and no foreign mat- 
ter sticking to them. Place the 
element in box to keep clean. 
Reassemble the other elements 
in exactly the same way, and 
put them in the box. The ele- 
ments are now ready to be put 
in the jars. 


Repairing the Case. 


Empty the old acid from the jars, take the case to the sink (or 
tub), and wash out all the sediment, figure 140. With the pipe 
shown in figure 54, you have both hands free to hold the case, 
as the water is controlled by a foot operated spring cock. 


If the case needs repairing, 
now is the time to do it. If the 
ease is rotten at top, patch it 
with good wood. If the top and 
bottom are so rotten that consid- 
erable time will be required to 
repair it, advise the owner to buy 
a new case. Nine times out of 
ten, he will do just as you advise, 
if you are honest with him. 
Sometimes the top of the case 
ean be greatly improved by 
straightening the side edges with 
a small smoothing plane, and 
sometimes a 14 inch strip or more 
fitted all along the edge is neces- 
sary for a good job. 


Fig, 140. Washing Sediment from Jars, 
‘Water Supply Controlled by Foot 
Operated Valve or Cock 


Handles that have been pulled, rotted, or corroded off make 
disagreeable repair jobs, but a satisfactory job can be done un- 


226 THE AUTOMOBILE STORAGE BATTERY 


less the end of the case has been pulled off or rotted. Sometimes 
the handle will hold in place until the battery is worn out by 
old age if three or four extra holes are bored and countersunk 
in the handle where the wood is solid, and common wood screws, 
size 12, 44 or 5% inch long, used to fasten the handle in place. 
Sometimes it will be necessary to put in one half of a new end, 
the handle being fastened to the new piece with brass bolts and 
nuts before it is put into place. Sometimes you can do a good 
job by using a plate of sheet iron 1-16 inch thick, and 4 inches 
wide, and as long as the end of the case is wide. Rivet the handle 
to this plate with stove-pipe, or copper rivets, and then fasten the 
plate to.the case with No. 12 wood screws, 1% inch long. | 

If the old case is good enough to use again, soak it in a solution 
of baking soda in water to neutralize any acid which may have 
been spilled on or which may be spilled on it later. After soak- 
ing the case, rinse it in water, and allow it to dry thoroughly. 
Then paint the case carefully with hot asphaltum paint. | 


Putting in New Jars. 


When you have washed out the jars, examine them carefully 
under a good light. If you find any erack or hole, no matter how 
small it is, remove the old jar and put in a new one. In order 
to remove a jar, it is necessary to soften the sealing compound, 
and the heat may be applied in several ways: 

1. Place ease in the four compartment heater described on 
page 193. : 

2. Fill the jar with boiling water if they will hold water, cover 
up and allow it to stand for at least fifteen minutes. . 

3. Use the Battery Steamer described on page 140. 

If only one jar is to be removed, put the steam hose directly 
in the jar. Cover the top of the jar with rags or paper to hold 
in the steam. Steam for half an hour. 

If all the jars are to be removed, put the case containing the 
jars into the steam box and turn on the steam. Keep steam flow- 
‘ing for one-half hour or more. | 

When you have softened the compound by one of the above 
methods, grasp the Jar with two pairs of pliers and pull it straight | 


WORK ON THE BATTERY 227 


up. If the jar will not lift out easily, heat an old small cross 
cut or compass saw blade hot with a blow torch, run the blade 
down on each side and end of the jar so as to cut away the com- 
‘pound. Then loosen the compound under the bottom of the jar 
by one of the three methods described above. 

After removing the Jar, inspect the inside of the case and re- 
move anything which may make it difficult to put in a new jar. 

Now heat the new jar with a blow torch, 
being careful not to burn it. A good thing 
to use here is a block of wood which fits 
the inside of the jar somewhat snugly, fig- 
ure 141. This will prevent the jar from 
being broken when it is put in the case. 
Instead of this, the assembled elements 


may be put in the jar to prevent it from 


Fig. 141. Wooden Block to 1 
1 on breaking. 


Pour about one inch of hot compound 
in the space which the new jar is to occupy. Push the heated 
jar down into place. Be sure that the top of the new jar is 
level with the other jars in the case. Otherwise you will have 
trouble in burning on the connectors, and your finished battery 
will look as if a novice had done the job. 


Putting Elements in Jars. 


With the ease ready, look for the ‘‘+,’’ ‘‘P’’ or ‘“POS”’ mark 
on it. Place the case so that this mark is toward you. Put an 
element in the jar nearest the mark, with the positive post 
toward you, next to the mark. Put an element in the next jar 
so that the negative post is toward you. Put an element in the 
next jar so that the positive post is toward you, and so on. The 
elements are correctly placed when each connecting strap con- 
 neets a positive to a negative post. If the case has no mark on 
it, reassemble exactly according to the diagram you made on the 
tag before ‘you opened the battery. 

It is well to play the flame over the tops of the jars to soften 
them somewhat, so that there will be no danger of breaking a 
jar when you put in the elements. If an element fits loosely 


228 THE AUTOMOBILE STORAGE BATTERY 


in the jar, it must be tightened. The best way to do this is to put 
one or more separators on one or both sides of the element before 
putting it in the jar, figure 142. 

If you leave the elements loose 

in the jars, the jolting of the car 

will soon crack the sealing com- 

pound, and you will have a 

“‘slopper’’ on your hands. 


Filling Jars with Electrolyte. 


With all the elements in place 
in the jars, the next step is to 
fill the jars with electrolyte. It 
has been found from hundreds 
of battery jobs that it is best to 
fill the jars with electrolyte be- 
fore the covers are put on, or the 
top connectors burned in. There 
are several reasons for this: 7 Pacing a Separator an Outside 

(a) Remember that those plates S*#*t!ve 
which are to be used again are fully charged. If the negatives 
are now exposed to the air while putting on covers and burning 
in the top connectors, they will become very hot and may be 
ruined. 

(b) In setting new jars or changing from an old case to a new 
one, the hot compound, which was poured in the space to be oc- 
eupied by the new jar, may foam up when the heated jar is 
pushed down into place and run over the top of the jar. If there 
is no electrolyte in the jar, the compound runs down over the 
plates and can be removed only with difficulty. On the other hand. 
if the jar has been filled with electrolyte, any compound which 
runs over the top of the jar cools as soon as it strikes the electro- 
lyte, and floats on the surface of the electrolyte, and is easily 
removed. This also happens sometimes in pouring compound on 
top covers. With electrolyte in the jars, sealing compound can 
generally be fished out. 

(e) When lead burning without electrolyte in the jars, the com- 


“WORK ON THE BATTERY 229 


pound around the posts often melts and runs out on top of ‘covers. 
The electrolyte helps in keeping the post cool and prevents 
the melting of the sealing compound. 

A two-quart earthenware, glass, or crockery pitcher should 
be used in handling the electrolyte. If you have a lead funnel, 
use it, So as not to spill any acid on the case, jars, or posts. Pour 
in the new electrolyte until it covers the plates to a depth of 3% 
inch, 

If you have followed the directions carefully, and have there- 
fore freed all the shorts, have thoroughly charged the plates 
before separating the groups, have washed and pressed the neg- 
ative groups, have washed the positives, have then added any new 
plates which were needed, and have put in new separators, use 
1,400 specific gravity electrolyte. This is necessary because wash- 
ing the plates removed some of the acid, and the new separators 
will absorb enough acid so that the specific gravity after charg- 
ing will be about 1.280-1.300. 

The final specific gravity must be 1.280-1.300. In measuring 
the specific gravity the temperature must be about 70°F, or else 
corrections must be made. For every three degrees above 70°, 
add one point (.001) to the reading you obtain on the hydrometer. 
For every three degrees under 70°, subtract one point (.001) from 
the reading you obtain on the hydrometer. For instance,-if you 
read a specific gravity of 1.275, and find that the temperature of 


82—70 
the eleetrolyte is 82°F, add (— 3-4) four points (1.275.004), 


which gives 1.279, which is what the specific gravity of the elec- 
trolyte would be if its temperature were lowered to 70°. The 
reason this is done is that when we speak of an electrolyte of a 
certain specific gravity, say 1.280, we mean that this is its specific 
gravity when its temperature is 70°F. We must therefore make 
the temperature correction if the temperature of the electrolyte is 
much higher or lower than 70°F. 

Remember that you cannot charge a battery by adding acid to 
the cells. True, you may bring up the specific gravity, but specific 
gravity is a true indication of the condition of charge only when 
the exactly correct amount of acid is contained in the battery, 


230 THE AUTOMOBILE STORAGE BATTERY 


and if there is either too much or too little acid, the hydrometer 
readings are misleading. If the specific gravity of a cell refuses 
to come up to 1.280-1.300 after long continued charging, make 
a cadmium test (page 266) to see if plates are fully charged. 
If the test indicates that they are, add 1.400 electrolyte until the 
gravity of the cell reads 1.280-1.300. 


Putting on the Covers. 


After filling jars with electrolyte play the flame over the tops 
of the jars until the compound sticking to them is somewhat soft. 


Fig. 143, Heating Lower Covers Before Replacing on Battery 


Then, with a narrow putty knife, scrape off all the compound you 
can from inside of jar. Wipe off the rest with a rag saturated 
with gasoline. (Be careful with fire near gasoline.) It is also 
a good plan to scrape the inside edges with a knife, since the 
cleaner you make the edges, the better will the contact with 
the compound be. 

The next operation is a particular one, and must be done p7op- 
erly, or you will come to grief. Get the box labeled for the vat- 
tery you are working on, take the bottom and top covers, and 


WORK ON THE BATTERY 231 


clean them thoroughly. There are several ways to clean them. 
If you have gasoline at hand, dip brush in it and scrub off the 
compound. The covers may also be cleaned off with boiling water, 
but even after you have used the hot water, it will be necessary 
to wipe off the covers with gasoline. Another way to soften any 
compound which may be sticking to them, is to put the covers in 
the Battery Steamer and steam them for about fifteen minutes. 

With the covers clean, seat yourself at the work bench and lay 
the inside covers on a board beside you, and play the flame over 
them, as in figure 143, and warm them through. Be careful not to 
burn them. The covers will now be soft enough to place them in 
position on the cells without breaking them. The tops of the 
jars should also be warmed slightly before you put on the lower 
covers, to avoid cracking them. 

If the covers fit snugly all around the inside of the jars so that 
there is no crack which will allow the compound to run down on 
the elements, all is well and good. If, however, there are cracks 
large enough to put a small, thin putty knife in, you. must close 
them. If the cracks are due to the tops of the jars being bent out 
of shape, heat the tops until they are limp, (be careful not to 
burn them). ‘With a screw driver clean all around the outer 
edges of the Jars and inside edge of case. Now, with short, thin 
wedges of wood, (new dry separators generally answer the pur- 
pose), crowd down on the outside edges of the jar, until you have 
the upper edge of jars straight and even all around. If the 
cracks between cover and case still remain, calk them with asbes- 
tos packing, tow, or ordinary wrapping string. Do not use too 
much packing, just enough to close the cracks is sufficient. When 
this is done, see that the top of the case is perfectly level, so that 
when the compound is poured in, it will settle level all around 
the upper edge of the case. 


Sealing Compounds. 


There are many grades of compounds, and the kind to use must 
he determined by the type of battery to be sealed. There is no 
qeestion but that a poor grade used as carefully as possible will 
& m crack and produce a slopper. A battery carelesslv sealed 
W.th the best compound is no better. 


232 THE AUTOMOBILE STORAGE BATTERY 


The three imperative conditions for a permanent lasting job 
are: 

1, Use the best quality of the proper kind of compound for 
sealing the battery on hand. 

2. All surfaces that the compound comes in contact with must 
be free from acid and absolutely clean and dry. 

3. The sealing must be done conscientiously and all details 
properly attended to step by step, and all work done in a work- 
manlike manner. 

With respect to sealing, batteries may be divided into two gen- 
eral classes. First, the battery with a considerable bulk of seal- 
ing compound, the quantity depending principally on the amount 
of compound used around the edges of case to hold the elements 
in position and tight around the posts. This type of battery 
generally has a lower and an upper cover, the well being attached 
or detached, depending on the design. The compound is poured 
in a bulk on top of the lower cover and around the wells, and 
when it is hard, the top covers are put on. Now with this type 
most of the batteries you come in contact with have a thin hard 
rubber shell shrunk on the post where the compound comes in 
contact with it; this hard rubber shell usually has several shallow 
grooves around it which increase its holding power. This is good 
construction provided: everything else is normal and the work 
properly done with a good sticky compound. There are a few 
batteries with low down connecting straps close to top of covers, 
and the compound is poured all over the top of the straps. Some- 
times this type gives good service. 

The second general type consists of those batteries that have 
small cracks or spaces around the jars next to the covers and have 
a threaded post with nuts to screw down on covers to hold in 
position, or some special means of holding the covers in position. 
This type of battery is gaining in popularity, and when properly 
designed and built makes a very satisfactory battery. Of course, 
in rebuilding this kind of battery, just as in all kinds of repair 
work, if the job is worth doing at all, do it as well as you possibly 
ean. Have the edges coming in contact with the pitch or com- 
pound absolutely clean, have the covers fitting snugly all around 


WORK ON THE BATTERY 233 


the inside of jars before pouring ; have the pitch (or special com- 
pound for this kind of sealing) hot and thin, pour the cracks full 
and let cool, and when cold make a second pouring; when again 
cold, clean off level with top with putty knife if necessary. 

Pitch is sticky stuff. The best way to handle it is, when you 
receive it, to melt it and strain it through some window screen 
wire into a small, narrow, long box and keep it covered. The best 
tool to take some pitch out of box is a chisel made of a piece of 
old flat spring, or file. Heat one end red hot, and hammer to taper 
point, grind square and sharpen. Then as you need only a little 
pitch at a time, heat the sharp edge of the chisel and cut out only 
as much as you need. If you do not handle it in this way, you 
will get pitch all over yourself. 

When pitch burns on bottom of pan, clean it all off, throw it 
away, and put in fresh, or you will not be able to melt it thin 
enough, to do a good job. Pitch is sometimes used in sealing 
motoreyele batteries. 

Compound in bulk or in thin iron barrels can be cut into small 
pieces with a hatchet or hand ax. To cut 
off a piece in hot weather, strike: it a 
quick hard blow in the same place once 
or twice, and a piece will erack off. 


Sealing the Battery. 


Always start the fire under the com- 

Pound before you are ready to use it, 

and turn the fire lower after it has 

melted, so as not to have it too hot at the 

time of pouring. If you have a special 

long-nosed pouring ladle, fill it with com- 

Pound by dipping in the pot, or by pour- 

ing compound from a closed vessel. If 

you heat the compound in an iron kettle, jig, 444. pouring Compound on 

Dour it directly into pouring ladle, us- Top of Lower Covers 

ing just about enough for the first pouring. The compound should 

hot be too hot, as injury to the battery will result from its use. 
Pour compound on the lower covers, as in figure 144, Use enough 


234 TIE AUTOMOBILE STORAGE BATTERY 


to fill the case just over the tops of the jars. Then pour the rest 

of the compound back in compound vessel or kettle. Now take the 

sealing iron, which should be nearly red hot, and quickly run it all 

around the edge of the case and next to the outside of the jars, melt- 

ing the compound thin, driv- 

| ing off any possible moisture, 

and making a good joint between 

the compound and the outside 

edges of the jars, as in figure 145. 

To complete the job, and make as 

good a job as possible, take a 

small hot flame and run it around 

the edges of case, tops of jars, and 

around the posts until the com- 

pound runs and makes good con- 

tact all around. If you have an 

electric fan, let it blow on the com- 

pound a few minutes to cool it, 

as in figure 146. Then, with safe- 

ty, the compound used for the sec- 

Fig, 145; Using Very tot Sealing ond pouring may be hotter and 
thinner than the first. 

Fill the pouring ladle with com- 
pound which is thinner than that 
used in the first pouring, and pour 
within 1/16 inch of the top of the 
case, being careful to get in just 
enough, so that after it has cooled, 
the covers will press down exactly 
even with the top of the case. It 
will require some experience to do 
this, but you will soon learn just 
how much to use. 

As soon as you have finished 

Fig. 146. Cooling Hot Compound with . 
Electric Fan. pouring, use the flame as in figure 
147, and run it all around the 
edges of the case and around the posts, being very careful not to 
injure any of the wells. A small, hot-pointed flame is safer than 


WORK ON THE BATTERY 235 


a large, spreading flame for this purpose. Now turn on the fan 
again to cool the compound. 

While the compound is cooling, get 
the connecting straps and terminal 
connectors, put them in a two-quart 
granite stewpan, just barely cover 
with water, and sprinkle a table- 
spoon of baking soda over them. Set 
the stewpan over the fire and bring 
water to boiling point. Then pour 
the water on some spot on a bench 
or floor where the acid has been 
spilled. This helps to neutralize the 
acid and keep it from injuring the 
wood or cement. Rinse off the con- 
nectors and wipe them dry with a 

Tepe AL Taneang Campout oth OF Heat them to dry them, 
and Around Posts. op covers, which 
must be absolutely clean and dry, 
and spread a thin coat of vaseline over the top only, wiping off 
any vaseline from the beveled edges. Place these covers right 


Fig. 148. Pressing Down Top Covers to Make Them Level with Top of Case 


side up on a clean board and heat perfectly limp with a large, 
spreading blow torch flame. Never apply this flame to the under 


236 THE AUTOMOBILE STORAGE BATTERY 


side of the top covers. The purpose is to get the covers on top of 
the battery absolutely level, and exactly even with the top of the 
ease all around it, and to have them sticking firmly to the com- 
pound. There is not an operation in repairing and rebuilding 
batteries that requires greater care than this one, that will show 
so clearly just what kind of workman you are, or will count so 
much in appearance for a finished job. If you are careless with 
any of the detail, if just one bump appears on top, if one top is 
warped, if one cover sticks above top of case, try as you may, 
you never can cover it up, and show you are a first-class work- 
man. See that you have these four conditions, and you should 
not have any difficulty after a little experience: 

1. You must have just enough 
compound on top to allow the top 
covers to be pressed down exactly 
even with upper edge of case. 

2. The top covers must be ab- 
solutely clean and have a thin 
coat of vaseline over their top, 
but none on the bevel edge. 

3. A good sized spreading 
flame to heat quickly and evenly 
the tops to a perfectly limp con- 
dition without burning or scorch- 
ing them. 

4. Procure a piece of % inch 
board 1% inches wide and just 
long enough to go between 
handles of battery you are work- 
ing on, plane the edges straight. 
round the corners a little, and 
have the ends sawed square. 

Fig 149; Pressing Down ton Covers Around Soread a thin film of oil or 

vaseline all over it. Sometimes 

with small batteries you need a small piece of board %% inch 
thiek to go between narrow places. 

Quickly heat the covers and also heat the top surface of the com- 

pound until it is sticky so that the covers may be put down far 


WORK ON THE BATTERY 


enough and adhere firmly to it. 


237 


Place the covers in position.. Then 


press the covers down firmly with piece of oiled wood, as in figure 


148, applying the wood sidewise and 
lengthwise of case until the top of cover 
is exactly even with the top of the case. 
It may be necessary to use the wood on 
end around the wells and posts as in 
figure 149, to get that part of the cover 
level. If the compound comes up be- 
tween covers and around the edges of 
the case, and interferes with the use of 
the wood, clean it out with a screw- 
driver. You can then finish without 
smearing any compound on the covers. 

‘When you have removed the excess 
compound from the cracks around the 
edges of the covers with the screw- 


Fig. 150. Wiping Bottom of 
‘Spoon Filled with Sealing Com- 
pound 


driver, take a large iron spoon which has the end hent into a pouring 
lip, and dip up from % to % of a spoonful of melted compound 


(not too hot). 


Fig. 151. Pouring Compound from a Spoon Into 
Cracks Around Covers 


Wipe off the bottom of the spoon, figure 150, and 


pour a small stream of com- 
pound evenly in all the 
eracks around the edges of 
the covers until they are 
full, as in figure 151. Do 
not hold the spoon too high, 
and do not smear or drop 
any compound on top of 
battery or on the posts. No 
harm is done if a little runs 
over the outside of the case, 
except that it requires a. 
little time to clean it off. 
A small teapot may be used 
instead of the spoon. If 
you have the compound at 


the right temperature, and do not put in tao much at a time, you 
can obtain good results, but you should take care not to spill the 


compound over anything. 


238 THE AUTOMOBILE STORAGE BATTERY 


After the last compound has cooled,—this requires only a few 
minutes,—take » putty knife, and scrape off all the surplus com- 
pound, making it even with the top of the covers and cases, figure 
152. Be careful not to dig into a soft place in the compound with 
the putty knife. If you have done your work right, and have fol- 
lowed directions explicitly, you have scraped off the compound with 
one sweep of the putty knife over each crack, leaving the compound 
smooth and level. You will be surprised to see how finished the 
battery looks. 

Some workmen pour hot 
compound clear to the top of 
the case and then hurry to 
put on a cold, dirty, and 
many times a scorched and 
burned top. What happens? 

The underside of the cover, 

coming in contact with the 

hot compound, expands and 

lengthens out, curling the 

top surface beyond redemp- 

tion. As you push down one 

corner, another goes up, and rig. 152. Final Operation of Cleaning Of Com- 
it is impossible to make the . ill'Gase'an'Tep Covers NuN® 1 MIR 
covers level. : . 

In 1915, a batteryman in a large Kansas City shop, while put- 
ting cold, dirty covers on hot compound, and having great diffi- 
eulty in making all the corners stay down, was asked why he 
put covers on that way. The reply was, ‘‘because they stick.” 
In 1918, the men in that shop are trying to put the tops on 
level and are making an effort to do better work. Why? Simply 
because they are compelled to, to get work, as their competitors 
have thinking workmen who take more pains with their work 
and do better work, and as a result, get the business. If the men 
in the Kansas City shop do not use their heads and think any 
better in treating the inside of a battery than they do the covers, 
it is no wonder their repaired and rebuilt batteries do not give 
satisfaction. 


WORK ON THE BATTERY 239 
Burning in the Connecting Straps. 


With the covers in place, the next operation is to burn in the 
top connectors. Place the battery on the floor near the burning 
bench. With a % inch drill, 
clean off the tops of the posts 
with one or two turns of the 
brace, eutting off a clean, 
thin shaving, as in figure 
153, Now put battery on 
bench, or on the Battery 
Turntable. With a chisel, 34 
inch or more wide, cut the 
rough edges from the tops 
of the posts, as in figure 155. 

Now take a connecting strap 

which is dry and free from 

acid, and put it in a vise, as 

in figure 156. Clean it with 

a wire brush, then clean the 

openings with a knife. Fin- 

ish each end of the top of 

strap with a bastard file, as 

in figure 154. Place the 

straps in their proper posi- 

tions on the posts, and with ™* 153. Cleaning, ‘tons of Posts Preparatory 
a length of two by four 

wood, pound them snugly into position, as in figure 157. Be 
sure the connecting straps are level, and the terminal connectors 
in the same position as when you took the battery off the car. 
Always test the voltage of the battery to make sure that the 
total voltage is equal to two times the number of cells in the bat- 
tery, this showing that you have connected all the cells in series. 

The straps are now ready for burning. Before you bring any 
flame near the battery, remove the stoppers, and blow out any 
possible gas with an air hose or hand bellows, figure 102. Then 
put a long strip of asbestos, 144 inches wide, over the vent holes, 
figure 158, or put a 114 inch square of asbestos over each vent 


240 THE AUTOMOBILE STORAGE BATTERY 


hole. These serve to protect the wells from the flame, and alsq 
keep dirt out of the wells. | 

To make a perfect finish of 
the compound, turn on a strong 
flame of hydrogen (no air or ox- 
ygen), and quickly run all 
around the outer edges of the 
ease and between the covers, di- 
rectly on the compound. You 
Fig. 154. Rasping Terminals and Connect- must be extremely careful, how- 

ing Links Before Burning In ever, not to burn the covers. 

For burning in thé connecting straps you need strips of burn- 
ing lead about fifteen inches long, and from %4 to % inch diam- 
eter. This can be made of old plate straps, connecting straps, and 
terminal connectors. Melt these and run them off in forms. The 
Burning Lead mold is very useful for this purpose, see page 146. 

Figure 85 shows a hydrogen and oxygen burning outfit. A 
eareful study of the same will reveal to you any desired informa- 


Pig. 155. Chiseling Of Rough Edges from Tops of Posts Before Burning In 


tion you wish or need to know to fit one out for yourself that will 
do the work right if you follow directions, as follows: 

Before turning on either the higher hydrogen pressure or the 
oxygen pressure on regulating valves, see that the regulating 
valves are turned sufficiently to the left to register 0 when the 
higher hydrogen and oxygen pressures are turned on. You must 


__ 


WORK ON THE BATTERY 241 


ever turn the regulating valves to the left when the higher pres- 
ures are turned on. If, when the higher pressures are turned 
n, the regulating valves register 0, turn to the right slowly 


Fig. 156. Cleaning Connector Before Burning In 


Fig. 157. Leveling Top Connectors Before Burning In 


until the pointer registers 4 or 5 pounds while burning a job. 
Have ready some kind of a pilot light so that you can light the 
hydrogen without using a match each time. 

Turn on the hydrogen slowly, holding the tip to the pilot (the 


242 THE AUTOMOBILE STORAGE BATTERY 


point on the tip should be the medium sized one with a 1/32 inch 
hole). Turn on enough hydrogen to make a flame 2 to 6 inches 
long, depending on the size of a lug to be burned. Use your judg- 
ment and common sense about it; don’t try to burn a motorcycle 
battery lug with a large strong flame, or a heavy terminal with a 
little bit of a flame. When you have the proper sized flame for 
.the joint to be burned, turn on the oxygen slowly at the mixing 
or ‘‘Y’’ valve until the flame becomes a pointed hissing flame. 
Now try it on one of the joints to be burned and play the point 
of the flame around on top of post, holding it at the distance which | 
melts the lead the quickest. This can easily be determined by 


Fig, 158. First Stage of Burning Finished. Note Strip of Asbestos Over Filling 
Holes 
| 
raising the flame up and down slowly. You will note that there’ 
is a certain point of the flame which melts the lead more quickly 
than any other. Keep it at this distance, and as soon as the top 
of the post is melted, play the flame around and-around, melting 
in lead as fast as you can. Keep it melted all around on top of 
the post, building up as fast as you can with the melted burning 
lead. Continue playing your flame around and around, joining 
the melted burning lead with the melted inside edge of the post, 
puilding up until you have enough lead to raise the top of the 
post (not the whole top, of connector) evenly, 1/16 inch above 
the connector. Do not attempt to finish the top with this flame 
and do not let the flame touch the outside edge of connector. 
Burn in the rest of the posts in the same way. Figure 158 shows 
the first stage of the burning completed. Tura off the gas and 
oxygen. 


WORK ON THE BATTERY 243 


Take a wire brush and brush off the tops thoroughly, until they 
are all clean and bright,—then you are ready for the finishing. 
You need a soft flame, with less oxygen, just bordering on hissing 
for finishing. Begin directly over center of post just built up. 
Play the flame on one center until the built up post begins to 
melt ; now shake the flame outward back and forth until the outer 
edge of connector melts and the top portion of melted post unites 
and flows to outer edge. Quickly follow around ahead of flowing 
lead with point of flame until the melted lead has united with the 
outer edge all round, the object being to melt the whole top of 
the post only, not melting deep enough to have it break the outer 


Fig. 159. Second, and Final Stage of Burning Completed 


edge and run off, but to melt the whole top as quickly as possible 
so that it will flow level all over top of connector. Then instantly 
raise flame from it. All this must be done carefully and dexter- 
ously to do a first-class job, and you must keep the flame shaking 
around over the top and not hold it in any one place, so as not to 
melt too deep on outer edge or break the outside shell of con- 
nector, and allow the lead to run off. Learn to melt just a thin 
layer all over the top of connector, and then with a quick twist 
of the hand, draw the flame off at the heaviest part of the con- 
nector, and at the same time raise the hand. If you allow the 
flame to go over the melted lead when you raise it off, it will 
roughen it. Sometimes the whole mass becomes too hot and the 
top cannot be made smooth with the flame. Either wait until the 
connector cools, or soften the flame, or both. Finish all the tops 
with a soft flame. 


244 THE AUTOMOBILE STORAGE BATTERY 


Figure 159 shows the second stage of the burning finished. Do 
not spoil the job by brushing it; do such a good job that it will 
not be necessary to brush it. 

You should have a set of stencil 

letters about ¥% inch in size, fig- 

ure 160, and mark every bat- 

tery you rebuild or repair. 

Have your own private date to 

stamp on connectors, and also 

the factory date mark. Also 

stamp ‘‘POS’’ on positive ter- 

minal and ‘‘NEGQ’’ on negative 

terminal. Record the factory 

date, mark type’ of battery in 

a book, also your date mark and 

what was done to battery. By 

doing this, you will always be yig 160, stencils and Number_Stamps. 
able to settle disputes that may Hydrogen, and Oxygen Mixing Y Valve. 
arise, as you will know when  ** Left 

and what was done. 

To go one step farther, keep a record of condition of plates, 
and number of new. plates, if you have used any. . Grade the 
plates in three divisions, good, medium and doubtful. The 
‘doubtful’? division will grow smaller as you become experi- 
enced and learn by their appearance the ones to be discarded and 
not used in a rebuilt battery. There is no question that even the 
most experienced man will occasionally make a mistake in judg- 
ment, as there is no way of knowing what a battery has been 
subjected to during its life before it is brought to you. Stamp 
the POS and NEG marks on, then your initials; then your date 
of rebuilding and then date of leaving factory. 


Directions For Burning in Connecting Straps and Terminal Con- 
nectors With Soldering Irons. 


There may be some battery men who do not have a gas burn- 
ing outfit, or there may be emergencies when the burning outfit 


WORK ON THE BATTERY 245 


is out of commission and it is necessary to burn in a few joints 
without delay. For these conditions this chapter is given. 


Necessary Equipment: 

Two soldering irons, weighing 3 pounds each, the ends heated 
and hammered to long points so that there will be no. difficulty 
in touching tops of posts when connecting straps are on. 

One large piece of sal ammoniac. Wire solder. Stick solder 
will answer the purpose if wire solder is not available. 

A plumber’s candle for flux. 

One quart soldering acid in a two-quart’ earthen jar; this is 
for cleaning the iron after tinning it, and not under any circum- 
stances to be used as a flux with lead. 

One good sized bastard file to keep the scale filed off of solder- 
ing iron and for filing tops-of straps before soldering. 

One good pocket knife with strong small blade for cutting and 
cleaning holes in connecting straps and terminal connectors. 

Some good apparatus for heating irons, either natural gas burn- 
ers, gasoline burners, or tinners’ furnace. 

The four essential conditions for a perfect job are: 

1. Large heavy irons, properly shaped and red hot. 

2. Perfectly tinned irons for each joint. 

3. The surfaces to be united perfectly cleaned. 

4, A tallow candle for flux. 

With these four conditions fulfilled, any man of ordinary ability 
can, if he follows directions, do a first-class job. 

With the necessary equipment on hand, put your irons in a hot 
fire. Put your connecting straps and terminal connectors in a two- 
quart granite stewpan; barely cover with water; sprinkle a heap- 
ing tablespoonful of soda in water, and place on fire and boil. 
This cleans every atom of acid from them. Remove stewpan from 
fire and pour soda water on some acid spot on floor. Then rinse 
the terminals well and place in pile on hot plate and light fire 
under them and let burn 5 to 10 seconds only to dry (never go 
away and leave them with fire under them) ; then turn fire out, 
clean all straps and connectors thoroughly, either with hand wire 
brush or circular wire brush run by power. The surfaces to be 
fused together must be perfectly clean and bright. 


246 THE AUTOMOBILE STORAGE BATTERY 


Now take your 34 inch drill bit in brace and bore a thin shav- 
ing off the post,—just enough to bright and clean the top of post. 
Use your pocket knife or chisel to cut off dirty, ragged edges of 
post. Blow off all loose dirt on top of posts. Take candle and 
rub top of posts. Now take the hottest iron, and with coarse 
file, clean the four sides of taper point; then tin thoroughly on 
the sal ammoniac. Dip point of iron in the soldering acid to 
clean. Now hold the point of the iron on the top of the post, and 
at the same time melt some solder on the point of the iron so it 
will run down off the point of iron and fuse with the melted lead 
on top of post. Twist the iron back and forth while holding it in 
a vertical position, so as to mix the melted lead with the melted 
solder. Repeat this operation on the top of each post, and you 
have the foundation for a good job of soldering in. 

Now place the connecting straps in proper position and level 
the upper surfaces by gently tapping them with a hammer whose 
face has been rubbed on sandpaper to clean it. Also put the ter- 
minals on exactly as they came off and you are ready to solder in. 
Rub a little tallow around holes with plumber’s candle. Take a 
cherry hot.iron, file the four taper surfaces clean, then tin on 
block of sal ammoniac, and dip tinned point in acid. Holding the 
iron perpendicular, place it on top of post and see that it melts the 
top of post; then as fast as you can, melt solder into hole, turning 
your iron back and forth so as to have the corners of iron come 
in contact with surface of inside of hole and melt it, so the solder 
will fuse with it. When the hole is full of melted solder, draw the 
iron out, and with flat surface of iron, level the top of post care- . 
fully by melting solder so it will flow smoothly, all over top, fus- 
ing with the lead. If you have done your work right, you have a 
perfect joint, notwithstanding the belief that tin will be affected 
by sulphuric acid. 


Cleaning and Painting the Case. 


The next operation is to thoroughly clean the case; scrape off 
all compound that has been spilled on it, and also any grease or 
dirt. If any grease is on the case, wipe off with rag soaked in 
gasoline. Unless the case is clean, the paint will not dry. Brush 


_WORK ON THE BATTERY 247 


the sides and end with wire brush; also brush bright the name 
plate. Then coat the case with good asphaltum paint. Any good 
turpentine asphaltum is excellent for this purpose. If it is too 
thick, thin it with turpentine, but be sure to mix well before 
using, as it does not mix readily. Use a 1% inch, rather narrow 
brush, but of good quality. -Paint all around thé upper edge, first 
drawing the brush straight along the edges, just to the outer 
edges of rubber tops. Now paint the sides, ends and handles, but 
be careful to go around name plate without smearing any paint 
on it. To finish, put a second, and thick coat all around top edge 
to protect edge of case. Paint will soak in around the edge on 
top of an old case more easily than on the body of the case as it is 
more porous. 


Charging the Rebuilt Battery. 


With the battery completely assembled, the next step is to 
charge it at about one-third of the starting or normal charge rate. 
For batteries having a capacity of 80 ampere hours or more, use 
a current of 5 amperes. Do not start the charge until at least 12 
hours after fillmg with electrolyte. This allows the electrolyte 
to cool. 

Continue the charge until the specific gravity and voltage do 
not rise during the last 5 hours of the charge. If you have put 
in new elements or new plates charge for at least. 72 hours. 

New battery plates as received from the factory are generally 
somewhat sulphated, particularly the negatives. When you assem- 
ble an element, place it in a jar, and cover with electrolyte, the 
amount of sulphate increases on both positives and negatives. 
This action is shown by a drop in voltage caused by extraction 
of the acid from the electrolyte. The charge should be begun 
about twelve to fifteen hours after you cover them with electro- 
lyte. It is better to charge the new plates at a low rate, say 5 
amperes, and keep the temperature of the electrolyte below 
105°F. 

Measure the temperature of the electrolyte occasionally, and if 
it should go above 105°F, either cut down the charging current, 
or take the battery off charge long enough to allow the electrolyte 
to cool below 90°F. 


248 THE AUTOMOBILE STORAGE BATTERY 
Adjusting the Electrolyte. 


If the specific gravity of the electrolyte is from 1.270-1300 at 
the end of the charge, the battery is ready for testing. If the 
specific gravity is below 1.270 or above 1.300, draw off as much 
electrolyte as you can with the hydrometer. If the specific grav- 
ity was below 1.270, add enough 1.400 specific gravity electrolyte 
with the hydrometer to bring the level up to the correct height 
(about 4% inch above tops of plates). If the specific gravity was 
above 1.300, add a similar amount of distilled water. If the 
specific gravity is 15 points (.015) too low or too high, adjust as 
directed above. If the variation is greater than this, pour out all 
the electrolyte and add fresh 1.270-1.300 specific gravity elec- 
trolyte. 

After adjusting the electrolyte, charge until the gravity of all 
cells is 1.280-1.300, and there is no further change in gravity for 
at least two hours. Then take the battery off charge and make a 
final measurement of the specific gravity. Measure the tempera- 
ture at the same time, and if it varies more than 10° above or 
below 70°, correct the hydrometer readings by adding one point 
(.001 sp. gr.) for each 3’degrees above 70°, and subtracting one 
point (.001 sp. gr.) for each 3 degrees below 70°. Be sure to wipe 
off any electrolyte which you spilled on the battery in adjusting 
the electrolyte or measuring the specific gravity. Use a rag 
dipped in ammonia, or soda solution. 


Discharging and Testing. 


At this point, many batterymen send batteries out, but it is bet- 
ter, if you have time, to discharge the battery and calculate the 
number of ampere hours the battery will deliver by multiplying 
the discharge current by the time required for the voltage of each 
cell to drop to 1.8. 

Discharge the battery at a current approximately equal to its 
ampere hour capacity, using this current for about 10 minutes. 
For batteries of 80 ampere hours or less, use the discharge board 
shown in figure 74. For batteries of 100 ampere hours or more, 
use the coil of Nichrome wire shown at the left, in figure 73. 


- WORK ON THE BATTERY > 249 


With the battery discharging, measure the voltage of each cell. 
If no cell shows a voltage below 1.8 at the end of 10 minutes, the 
battery is normal. In this ease, discharge the battery at 14 to 
1/5 of its ampere hour capacity until the specific gravity in each 
cell is 1.150. Then charge at the normal rate until the battery 
tests 2.5 volts per cell, and the specific gravity is 1.280-1.300, and 
adjust the electrolyte to 1.280. 

If the voltage of any cell drops below 1.8 at the end of 10 min- 
utes, discharge the battery at the rate given on the name plate 
until the specific gravity is 1.150. Then charge the battery again 
at the normal rate, and see if the cell will come to 2.5 volts while 
charging. If not, make a cadmium test, as described on page 266, 
and determine whether the positives or negatives are at fault. If 
either shows a considerable loss of capacity, the battery will not 
give a long service. 

The charging and discharging of the battery puts the active 
material in good condition, because the active materials must have 
exercise, Just as a man must, in order to be in the best of health. 
By charging and discharging, you exercise the pastes and make 
them as active as possible. Were it not for the time and expense 
of charging and discharging, it would be better to put the battery 
through four or five charges and discharges. 


CHAPTER 17. 
SPECIAL INSTRUCTIONS. 
Willard Type 8 Storage Batteries. 


The Willard Type S Storage Battery is a very difficult one to 
take down and rebuild, and great care must be taken to perform 
each operation thoroughly, in order to do a good job. 


Opening the Battery. 


Have the plugs in. With a 7/16 inch drill, bore three holes in 
a row in each connector, 4 to % inch deep, directly over the post, 
figure 161. Then hold the drill 
at an angle and run it along 
the slot made by the three holes 
so as to cut away the edges left 
1 where the holes meet, figure 
162. This will give you a slot 
} a little wider than the post. 

Sweep all lead drillings in a 
box with a whisk broom. Re- 
move all the plugs and blow 
2 out the gas. Heat the connec- 
tors by running a flame over 
Fig. 763 hard “Tyne S Better f the drilled slot. You can then 

; pry off the connectors with a 

screw driver, using an angle iron to protect the top of the case, 
figure 163. | 

Heat the sealing compound with the flame, and with a medium 
wide screw driver, cut out the compound flush with the tops of 
the Jars. . 

Heat up the compound again with flame, and clean out the 

250 


SPECIAL INSTRUCTIONS 251 


Fig. 162. Widening the Slot 


Fig. 163. Removing Top Connectors with Screwdriver. Note Angle Iron Held on 
Edge of Case to Prevent Damaging Case. Willard Type S Battery 


Fig. 164. Removing Pitch with a  %-inch Chisel from V-shaped Slot Around 
Covers on Willard Type S Battery 


252 THE AUTOMOBILE STORAGE BATTERY 


Fig. 165. Lifting Elements Out of Jars, and Resting on Edge of Case to Dralt 
Willard Type 8 Battery 


Fig. 166. Removing Covers from Willard Type S Battery 


SPECIAL INSTRUCTIONS 253 


V-shaped cracks with a 1% inch chisel, figure 164. Apply a little 
more heat, place battery on floor, and pull out the elements and 
drain, figure 165, using two gas pliers or pincers to grasp the 
posts in lifting. 

Grasp each cover in both hands, work it back and forth, 
and lift off or remove as in figure 166. Place an element on 
block as in figure 113. Examine plates, and proceed as directed 
on pages 198 to 230. After charging, pressing negative plates, 
and making any repairs necessary, assemble the elements, put in 
the rubber separators, and place elements in jars. Add new 
electrolyte, of 1.400 gravity. 


Fig. 167. Extending Post on Willard Type S Battery. Note Asbestos Fitted Around 
Posts to Prevent Lead from Running Down Into Cell 

With the elements all firmly in place, and properly arranged 
for connecting, the next step is to lengthen the posts by about 
3g inch. Take a piece of 1% inch thick asbestos paper, and cut 
holes in it exactly the size of the post. Push this down around 
the post, figure 167. Get some 1/32 inch thick sheet iron, 114 
inches wide, and 3 inches long, and bend a piece exactly the 
same size as the post to serve as a mold. Slip this over the 
post, figure 167, and fill all around the inside of the mold, which 
will make the top of the post of the proper size. The lower part of 
the post is "larger than the top. If the mold does not fit at the 
lower edge, calk it with asbestos packing. 

With a small hissing flame melt the top of the post in the 
mold, figure 167. Then melt in lead as fast as you can until you 
have built up the post 7/16 inch above the old top. Let the post 


254 THE AUTOMOBILE STORAGE BATTERY 


cool, and then work out the asbestos from the mold with a knife. 
Pry off the mold, and in a similar way build up the other posts. 
Should the lead ever show a tendency to stick to the mold, rub 
a little graphite mixed with oil over it. 

The next step is to clean the covers thoroughly. Also clean 
the compound out of the wells around the posts with a hot % 
inch chisel. A good way to clean the covers is to scrub them 
with a brush soaked in gasoline, and wipe them dry. Clean out 
the very bottoms of the wells into which the petticoats of the 
straps fit, and wipe perfectly dry. 

Clean out the inside of the jars near the top, and play the 
flame on the tops of the jars, and around the edge of the case. 
Use a ¥% inch hot chisel to clean out all compound. Use a hot 


te 


Fig. 168. Putting Asbestos Packing Around Post in Willard Type S Battery, to 
Prevent Compound from Running Down Into Cell When Burning In 


sealing iron to dry out the cracks, being careful not to burn 
the jars. 

Now place on the covers, and make sure that the upper edges 
are straight and square. See page 230. If there are any cracks 
around the lower edge next to the jars, ealk them with 1% inch 
strands of asbestos. Force this in tightly all around the edge of 
the jars. 

Now put just enough pitch in a two-quart granite stewpan to 
seal this one battery, and not more. The pitch is liable to burn 
if heated more than once, and it will not become as thin when 
heated the second time as when heated only once. Put the pitch 
over a rather slow fire so that it will be ‘heated sufficiently 
just at the time you need it. The pitch must be hot, and very 
thin to do a good job, yet you must be careful not to burn it, for 


SPECIAL INSTRUCTIONS 255 


when it burns at the bottom, it is not thin enough to run into 
the small cracks, and is therefore not suitable for the first pour- 
ing. 

While the pitch is heating; straighten the posts so that they 
are exactly in the center of the holes in the covers. After warm- 
ing them slightly, calk around them with 1% inch strands of 
asbestos, figure 168, A small screw driver is about the best tool 
to use in calking. When you have calked around all the posts, 
the pitch will probably be hot enough to pour. Shake the pitch 
around in the pan, and if it is quite thin, and pours very easily, 
it is ready for use. 


Fig. 169. Pouring Special No. 4 Compound Into Wells Around Posts. Willard 
Type S Battery 

Now pour the pitch in the spaces between the case, jars, and 
covers until these are full. It is well to tamp the sealing com- 
pound in the slots with a hot sealing iron. This is made of a 
block of copper with a narrow iron blade—to go in the slots—_ 
attached to the copper. When using this iron, pour the pitch 
around only one cover at a time. Then hold the hot iron in a 
vertical position, insert it between the cover and the jar, and 
quickly move it up and down, thus forcing the compound clear 
to the bottom of the slot. Move the iron forward about 14 inch 
after each downward stroke. In this way tamp in the compound 


256 THE AUTOMOBILE STORAGE BATTERY 


all around the cover. Do the same for all the cells. If you have 
an electric fan, turn it on the battery to cool the pitch. If the 
pitch was thin and hot, the edges of the jars clean, the covers 
clean, and tight around the insides of the jars, the edge of case 
properly cleaned and dried, the pitch will stick, and as it cools, 
it will sink down in the middle of the cracks. When it has 
cooled, pour in some more pitch until it is slightly higher than 
the top of the case and covers. When the pitch of the second 
pouring has cooled, scrape off the excess with a warm putty knife. 

Place the connecting straps in a pan of soda solution, and boil 


Fig. 170. Meating Top Connectors trom, Willard Type Battery before Placing 
‘on Post 


them. Then dry them, and brush and clean them. File out the 
oblong holes in the straps with a rat-tailed or coarse flat bastard 
file. The straps may be held in a vise, if they are carefully 
handled. Also file the tops of the straps clean around the holes. 
After the filing, the straps will slip over the posts so that they fit 
snugly and will easily unite with the extended post. The surfaces 
of the post and strap must be absolutely clean, or else they cannot 
be burned together. When you have the straps cleaned up, and 
tried on, so you are sure that they will fit well, put some Willard 
special No. 4 compound over the fire. Use about a tablespoon 
for each post. This compound contains a considerable percentage 


SPECIAL INSTRUCTIONS 257 


of rubber, and will melt very thin and make a good seal if prop- 
erly used. 

When the compound is hot and thin, quickly dry out the wells 
around the post with the hydrogen flame. Also run the flame 
over the compound which you have already poured in, so as to 
put the finishing touches to it. With the connecting straps re- 
moved, pour the compound into the wells around the posts until 
it comes up almost to the top of the edge of the well next to the 
post, figure 169. Fill all the wells to the same height. 


Fig. 171. Pressing Down Hot Top Connector Into No, 4 Compound. Willard 
‘Type 8 Battery 


Now put one connecting strap, and one terminal connector on an 
asbestos pad, and with a blow torch or strong hydrogen flame 
with little air, heat them, figure 170. Be careful to keep the 
flame moving constantly, or you will melt them. When hot, put 
them in position on the posts with pliers, placing the positive 
terminal near positive mark on case. Pound them in place with 
a block of wood, figure 171, until they fit tight, and are close to 
the covers. Put on the other terminal and strap in the same way, 
and the battery is ready for burning. 


258 THE AUTOMOBILE STORAGE BATTERY 


In burning these terminals and connectors, several steps must 
be taken: 

1. You must protect the upper edge of cover all around the 
connecting straps and terminals with asbestos paper or transite 
board, figure 172. 

2. I£ the built up posts extend more than 1% inch above the 
top of the straps, cut them down to this height. 

8. You must do the burning quickly, or the compound will 
boil and run out. If the compeund becomes so hot that it begins 
to run out, stop working on that post, and start on another while 
the first one cools. 


Fig. 172. Transite Board Around Cover to Protect It When Burning In Connectors 


4. You must have a rather small, hot hissing flame to start 
with, and must do the rough burning as quickly as possible. 

5. When all the posts are roughly burned, brush off the tops 
and finish with a rather soft, small flame, with just a faint hiss 
to it. 

6. Mark and paint the battery. See page 246. 

If you perform each step carefully, it will take five hours or 
more to do a first-class job. 


Special Instructions for Exide Batteries. 
Exide batteries all use a removable nut to make a tight joint 


between the posts and the cover. With reference to other fea- 
tures, these batteries may be divided into several classes. 


SPECIAL INSTRUCTIONS 259 


Fig. 173. Exide Battery, Type 3-XC-13-1, Showing Parts and Construction 


1, Batteries having burned-in connecting straps, with a single 
flange cover, figure 173. 

2. Batteries having burned-in connecting straps, with double 
flange cover, figure 175. 

3. Batteries having bolted connecting straps, with double 
flange cover. These never use the single flange cover. 

(a) Batteries with burned-in connectors—types XA, XC, LX, 
SX, ZA, JX, PHA, MHA. Remove these as described on pages 187 
to 191. 

(b) Batteries with bolted 
connectors,—types X, PH, 
PHB, MH, ZB. The nuts 
should be removed with a 
socket wrench of the proper 
size, figure 174. Then re- 

Fig. 174. Socket Wrench move the connectors and 

washers carefully, and put 

in one of the labeled boxes previously mentioned. There are 

two top nuts and straps for each complete strap, and three wash- 
ers over each post, as shown in figure 176. 


THE AUTOMOBILE STORAGE BATTERY 


260 


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Fig. 175. Section of Exide Battery with Burned-In Connections, and Single Flange 


Cover 


SPECIAL INSTRUCTIONS 261 
Removing Covers. 


Batteries, types X, XA, PH, _— 
and MH have tie bolts which 
run through the case from side — 
to side, between the jars. The 
jars are spaced properly by 
horizontal, wooden strips, be- 
tween which are the tie bolts. 
Unserew these bolts several 
turns to release the jars. 

The next step is to remove 
the sealing nuts. For this pur- 
pose you need a special Exide 
Sealing nut wrench, figure 177. 

Never use any other tool for 

this purpose. Heat the tops of yi. 477, uxide Sealing Nut Wrench 
the cells a little, and with two 
crooked nosed pliers, raise the complete cell an inch or two. 

Next remove the sealing compound. The single flange cover 
(used on types XC, LX, SX, and JX) rests on rubber gaskets 
placed on top of the posts, and is level with the top of the jar, 
leaving a V-shaped slot all around the inner edge of the jar which 
is filled with pitch. The pitch may be softened as previously 
deseribed (page 191), or a hot screw driver may be run through 
it in order to remove it. 

The double flange cover (used on types X, XA, PH, MH, ZB, 
and ZA) laps over both the inner and outer edge of the jar. There 
are two flanges, one on the outside, and the other on the inside of 
the jar, forming a slot which fits over the top of the jar, and also 
holds the pitch. To remove the pitch, run the flame all around the 
edge of the cover, but be extremely careful not to burn the cover. 
After the outer flange is thoroughly warmed, the cover will lift off 
slowly. Support the cell on two blocks, the lower edge of the 
outer flange resting on the top of the block, and the bottom of the 
jar raised slightly above the bench. Press down on the posts, and 
the cell will drop free of the cover, figure 178. 

Inspection of plates, ete. This has already been described fully, 


£5.B, 00.907 
Fig. 176. Parts for Bolted Connections 


262 TIIE AUTOMOBILE STORAGE BATTERY 


pages 198 to 222. The only special instructions needed refer to the 
perforated rubber separators used in types PH and MH. These are 
nearly always in such a condi- 

tion that they can be used again, 

unless they have been broken in 

handling, or worn through. 

Better have some of: these on 

hand in case you break some. 


Reassembling. 


Put the positive and negative 
groups together without separat- 
ors, place the rubber washers on 
the posts, and put on the cover. 
Put on the sealing nuts, and 
tighten them slightly with your 
fingers. If the nuts turn on hard, 
spread a little graphite—which 
has been mixed to a paste with 
water—on the threads, Never 
use vaseline or grease for this purpose. Now put in the separators. 
(See page 224.) Tighten the sealing nuts with the wrench shown 
in figure 177. 

Next lock the sealing nuts. On batteries using burned-in con- 
nectors, the thread on the post extends above the top of the nut. 
Hold the point of a center punch (or nail) on the thread at the 
top of the nut and strike a sharp blow with a hammer, figure 179. 
This will damage the thread and prevent the nut from turning loose. 
Do this at several points around the post. 

On the batteries having bolted connections, the washers, straps 
and top nut will hold the sealing nut firmly in place. 


Fig. 178. Removing Double Flange Cover 


Sealing. 


Remove all old compound from covers and jars and wipe with 
a cloth dipped in ammonia or soda solution. In sealing batteries 
that use the single flange cover, melt the compound and pour it into 


SPECIAL INSTRUCTIONS 263 


the V-shaped groove, finishing as usual. In sealing batteries using 
the double flange cover, clean the groove thoroughly and pour one- 
half full of hot pitch. Place 

cover on top of jar and press 

down evenly all around. Anoth- 

er way is to roll out between two 

boards some of the special Exide 

compound, made for this type 

of cover, until it is about 3-16 

inch in diameter. Lay this com- 

pound in the groove while the 

element is upside down, figure 

180. Then put element in jar, 

and press down evenly so that 

the top of the jar presses up 

against the compound at all 

points, Run a flame around the 

outside of the flange until the 

compound melts evenly. Press 

down the cover carefully. Re- 

move any compound which is 

foreed down out of the groove 

with a hot putty knife or screw Fis: 170, Yocking Bealtag Nos 
driver. 


Putting Cells in Case. 

When all the cells have been sealed, put the elements in the 
cases, taking care to have the positive and negative posts placed 
correctly for putting on the connectors, In types X, XA, PH, and 
MH, be sure to put in the wooden spacers between cells, and 
tighten the tie bolts to hold the jars firmly in place. If the bat- 
tery has no tie bolts, wedge the jars in place with strips of wood 
if they do not fit snugly. 


Putting on Connecting Straps, 

Directions for the burned-in connectors have already been 
given (pages 239 to 246). In placing the bolted connectors, spread 
vaseline over the studs. Put the connectors and washers on in 


264 THE AUTOMOBILE STORAGE BATTERY 


the following order,—one connector link, one washer, second 
connector link, second washer, top nut. Tighten the top nut with 
socket wrench, figure 175. 

The remaining steps consist of 
charging, and balancing the 
electrolyte, consult pages 247 
and 248, 

In addition to the three types 
of Exide batteries described 
above, there are several other 
types which use no sealing com- 
pound at all, and therefore re- 
quire no special instructions. 
An old type has two covers, the 
lower of which is somewhat sim- 
ilar to the single flange cover 
described above. The upper 
cover fits over the outside of the 
jar. 


Fig. 180. Sealing Double Flange Cover 


Special Instructions for Prestolite and U.8.L. 


The Prestolite and U.S.L. Companies make a new type of bat- 
tery which resemble each other in a number of respects. The tops 
are like U.S.L. described on page 98. Take great care in bring- 
ing a flame near these batteries, as gas may be pocketed under 
the covers and cause an explosion. There is only a small vent 
hole through which gas can escape, as the wells extend down into 
the electrolyte when the cells are properly filled. 

When you work on these batteries, draw out enough electro- 
lyte so that it is below the bottom of the well. Then thoroughly 
blow out any gas which may have become pocketed under the 
cover. . 

Another unique feature of construction is the post and lead 
sealing shell fitting over it. After this shell has been screwed 
into the cover from below against a soft rubber gasket, the tops 
of the shell and post are burned together. This makes a perfectly 
tight seal, provided the shells have been screwed up tightly. The 


SPECIAL INSTRUCTIONS 265 


Sealing arrangement around the edge of the jar is similar to that 
in the single flange Exide cover, figure 173. 

Be very careful in sealing this type of battery. Ordinary com- 
pounds will not hold. Use pitch, or a high grade and very sticky 


Fig. 181. Prest-O-Lite Battery, Showing Parts and Construction 


» compound. Never use compound or pitch a second time for this 


battery. 
Figure 181 shows a Prest-O-Lite Battery. Directions already 


given apply to this type also. 


CHAPTER 18. 
CADMIUM TEST. STORING BATTERIES. 
Cadmium Test for Storage Batteries. 


Tests of the specific gravity of batteries and tests of voltage 
of the cells give indications that are quite reliable, but unfor- 
tunately either the voltage or gravity or both voltage and gravity 


1 DISCHARGEO CHARGED 
pe 


< 
oe 
rc 
in 
> 
en 


cd 


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pe arive 


= 


amr ER 


Fig. 182 


may be satisfactory and yet the battery capacity may be very low. 

This is true because either the positive or negative plates may 

not be charging or discharging properly and if either set does 

not completely charge and discharge, then the capacity of the 
266 


CADMIUM TEST. STORING BATTERIES 267 


cell can only be equal to the capacity of the faulty set of plates. 
Should such a condition exist, the voltage will fall rapidly during 
discharge and the capacity of the battery will be greatly reduced. 

The change in voltage of the positive and negative plates, be- 
tween the discharged and the charged condition is graphically 
shown in figure 182. The horizontal lines represent the change 
in voltage starting from the heavy line marked ‘‘O”’ and increas- 
ing above the line for positive polarity and below the line for neg- 
ative polarity. | 

The positjon of the negative plates of a discharged cell as to 
voltage is represented by the heavy line marked ‘‘Negative’’ in 
the column headed ‘‘Discharged.’’ The position of the positive 
plate at this time is indicated by a heavy line marked ‘‘Positive’’ 
and in this same column. The voltage of the negative plate with 
relation to the ‘‘O”’ line is 0.25 and the voltage of the positive 
plate with reference to this same ‘‘O”’’ line is 2.05. It will be 
seen that the total difference in voltage between the positive 
and negative plates is therefore 1.8, or 2.05 minus 0.25, and it 
will be recognized that this voltage (1.8) is the voltage of a dis- 
charged storage cell. 

The relative voltages of the positive and negative plates in 
a fully charged cell are indicated by the heavy lines in the column 
marked ‘‘Charged’’ and it will be seen that the voltage of the 
positive plate has become 2.3 above ‘‘O’’ while that of the neg- 
ative has become 0.2 below the ‘‘O”’ line. The total difference 
in voltage between the positive and negative plates is now 2.5, or 
2.3 plus 0.2. It will be recognized that this voltage (2.5) is the 
voltage of a storage cell when fully charged. 

The voltage of the positive plates has changed 0.25 of a volt, 
that is from 2.05 to 2.3. The voltage of the negative plates has 
ehanged 0.45 of one volt, that is from 0.25 above the ‘‘O”’’ line 
to 0.2 below the ‘‘O’’ line. Therefore, in order that a discharged 
cell may become fully charged, it is necessary that the voltage 
of the positive plates change 0.25 of a volt and the voltage of the 
negatives must change 0.45 of a volt. 

If for any reason the positive plates should get into such a 
condition that their voltage does not change over this range, the 
battery cannot have full capacity or full voltage on discharge. 


268 THE AUTOMOBILE STORAGE BATTERY 


The same is true of the negative plates, their voltage should 
change over the entire normal range. 

It will be seen by examining the diagram in Figure 182 that it 
would be quite possible for the cell voltage to be normal and yet 
have an incorrect relation between either the positive or negative 
plates and the ‘‘O”’ point. For instance with a fully charged bat- 
tery, should the voltage of the positive plate be found consider- 
ably below the normal point, it would indicate that the lead sul- 
phate had not been completely reduced and replaced by peroxide 


WooD TEST ROD N21. 


Fig. 183. Making a Cadmium Test 


of lead. Should it be found that with a charged battery the 
voltage of the negative plates remains above or on the positive 
side of the ‘‘O”’ line or if it does not drop to the proper point 
on the negative side below the ‘‘O’’ line, it would indicate that 
the lead sulphate on the negative plates had not been completely 
reduced and replaced by sponge lead. In either case the remedy 
would be to.give the battery a long continued charge at a low 
rate, that is, at the twenty-four hour rate. 

The voltage of the separate sets of plates is méasured by attach- 
ing one side of a voltmeter to the terminal of the set of plates 
that is to be tested and attaching the other side of the voltmeter 


CADMIUM TEST. STORING BATTERIES 269 


to a rod of the metal cadmium, which is then inserted into the elec- 
trolyte of the cell. The voltmeter will then indicate the volt- 
age between the cadmium and the plates being tested. The cad- 
mium remains inert and is represented by the ‘‘O”’ line on the 
diagram. With the voltmeter connected between the cadmium, 
which represents ‘‘O,’’ and either set of plates, the plate voltage 
may be found. 

The cadmium rod should be from 3-16 to 8% of an inch in 
diameter, and from 3 to 4 inches long.. Solder it to the side of a 
rod of copper or bronze, as shown at No. 1 in Figure 183. You 
will need a second test rod, as shown at No. 2 in Figure 183. 

The voltmeter for this test should have a scale reading up to 
2.5 volts, and should preferably have the ‘‘O”’’ in the center. If 
the ‘‘O’’ is at the left end of the scale, the wires attached to the 
test rod should be connected to the meter terminals so that the 
needle swings toward the right. If the pointer should swing to 
the left in this meter, reverse the wires at the meter terminals 
so that it will swing to the right. 

If you use Ambu in making the cadmium test, connect the wires 
which are fastened to the test rods to the ‘‘—’’ and ‘‘2.5’’ posts. 
Set lever ‘‘C’’ so that the ‘‘O”’ line on the ‘‘ VOLT AND AMPERE 
SCALB’’ is under the pointer, and turn the button switch so that 
the arrow points to ‘‘V.’’ Do not move the ‘‘C’’ lever again 
during the test. . 

The cadmium should be covered with a rubber tube which has 
holes cut in it. No part of the rod should touch the plates. In 
testing the positive plates, test rod No. 2 is held on the positive 
post of the cell, and the cadmium rod is inserted in the vent hole. 
In testing the negative plates, test rod No. 2 is held on the negative 
post of the cell, and the cadmium rod is inserted in the vent hole. 
The acid must cover the lower part of the cadmium. 

When about to proceed with the work the cadmium which has 
been covered with rubber should be inserted in the electrolyte and 
allowed to remain so that its surface may reach a condition that 
will not change with further action of the acid. The surface of 
the cadmium should never be scraped or polished as this will pre- 
vent uniform readings from being secured under various con- 
ditions and with varying intervals of time. 


270 THE AUTOMOBILE STORAGE BATTERY 


The methods of inserting the cadmium pencil into the cell and 
of connecting the cadmium and cell terminal with the voltmeter 
are shown in Figure 183. 

Charged battery. Test the negative and positive plates as di- 
rected above. Test the positive plates first. Then test the nega- 
tive plates. If you are using a voltmeter with the ‘‘O’’ at the left 
end of the scale, the pointer should swing ‘‘backwards’’ when 
you test the negatives, and the wires connected to the meter should 
be reversed, and the test repeated. If you are using Ambu, the 
pointer should swing to the opposite side of the ‘‘O’’ line when 
testing the negatives that it did in testing the positives. The 
charging current should be passing into the battery when the tests 
are made on each cell. The voltage reading between the cadmium 
and positives should be between 2.35 and 2.45. 

The voltage reading between the cadmium and the negatives 
should be between 0.1 and 0.2. If the pointer is near the ‘‘O’’ 
line in testing the negatives, or swings to the same side of the ‘‘O”’ 
line as it does in testing the positives, the negatives are defective. 
The farther the pointer goes to the other side of the ‘‘O”’ line, the 
better the condition of the negatives. 

If the voltage reading obtained in testing the positives is less 
than 2.35 volts, and the negative plates give a normal reading of 
0.1 to 0.2 volts, the positive plates are defective. The causes may 
be sulphated plates, leak of current between plates, natural age- 
ing of the battery, or lack of charge. In this case, discharge the 
battery to 1.8 volts per cell, (see page 248), and then charge it 
again. Repeat this several times. 

Discharged battery. Test the positive plates as directed above. 
Then test the negatives, the pointer should swing to the same side 
of the ‘‘O’’ line in each ease, without reversing the wires attached 
to the meter. With a battery having a voltage of 1.8 per cell, the 
reading obtained when you test the positive plates should be about 
2.05 volts. The reading obtained when testing the negatives 
should be about 0.25. The readings should be taken while the — 
battery is discharging at the normal rate. | 

In some cases, readings obtained in both tests for positive and 
negative plates are nearly zero. This indicates a short circuit, and 
the battery should be opened. See page 187. 


CADMIUM TEST. STORING BATTERIES 271 
Storing Batteries Dry. 


Taking a battery out of commission for dry storage of six weeks 
or longer (six years, if necessary) consists in putting each cell 
in condition to charge normally; then charge it until the gravity 
will not rise any more, the electrolyte is clear, and the plates all 
of the proper color; at this stage the charging has excluded all 
impurities possible from the plates and the pores contracted to 
their limit. Pour out the electrolyte, separate the groups, remove 
the separators, and press the negative plates as follows: 

Put a smooth straight board or transite board, the thickness of 
the positive plate plus two separators, (which in the ordinary 
automobile battery is just a trifle over one-fourth of an inch) in 
each space between the negative plates of that group, then place 
a piece of 2’x6”x7” long board on each side of group, put group 
in vise or plate press, draw up slowly till tight. Leave for a few 
moments; then remove from vise or press and remove boards, and 
rinse group in clear water. Treat each negative group in similar 
manner and then put in jars and cover with distilled water for ten 
or twelve hours. Then remove and dry; but if they begin to heat, 
dip in water and dry; repeat the dipping if they heat the second 
time. Continue dipping the group after drying as long as the 
plates heat up. When the plates are thoroughly dry, immerse 
them in clean, new electrolyte (of about 1.275 specific gravity) 
and allow to soak for three or four hours. The jars may be used 
for this purpose. After rinsing and drying they are ready to put 
away. 

The positive plates should not be washed but may be dipped in 
the above acid several times to clean them. They should be 
straightened as much as possible immediately upon removing from 
jars. Sometimes this may be done (if not too hard) by placing ~ 
boards between them as with the negatives and pressing in vise 
or plate press. Do not apply much pressure. Press the group 
about 10 or 15 minutes, and then use flat nosed pliers to completely 
straighten the edges if they are still warped. Plates can gener- 
ally be straightened fairly well, but care must be used not to 
erack them. If plates are cracked, or buckled badly, replace with 
new ones without hesitation. The positive plates must not be left 


272 THE AUTOMOBILE STORAGE BATTERY 


exposed to the light. Throw away the old separators. Clean the 
covers and terminals, as directed elsewhere, wash out the jars and 


put a positive group in each jar. Nest two negative groups and | 
with covers and terminals put in labeled box as described else- — 


where. 

Store the case and box in a dark place until called for. You 
should tell the owner when arrangements are made for storing 
that he must give you ten days’ notice to put battery back into 
commission. When a battery is dry stored as above, to put it 


into commission, use about 1.360 gravity acid, fully charge and 


discharge, making two complete cycles, and balance to 1.280. 
With this treatment the pastes become active and put the battery 
into first-class condition. 


Finished Work. 


Perform every detail, from boring off connecting straps, to 
the final charge with the utmost care. Make it an iron-clad rule 


that every battery which you rebuild must be rebuilt as nearly | 


perfect as you can; that every battery you turn out of your shop 
will deliver from 80% to 90% of its rated capacity; that every 
such battery will stand up under the service required of it. 

See that every job you turn out is done as well as you ean do 
it. Make each job a little better than the previous one. Treat 
each customer courteously, and never promise anything unless 
you know absolutely that you can keep that promise. Put your- 
self in your customer’s position, and be as careful of his money 
as if it were yours, and you were paying a repairman to put your 
battery in shape. 

Do not grow careless and do sloppy work. Be conscientious, 
and do everything right. If you do not know the right way, make 

up your mind to learn the right way. You must know what you 
are doing, and must not grope around on a job. If you make a 
guess as to what should be done, and adopt the cut-and-dry 
method, you will ‘‘fall down on the job’’ nine times out of ten. 

The battery owner may pay the bill once, for a poor job, but he 
will never come back. The public is just as intelligent as you 


CADMIUM TEST. STORING BATTERIES 273 


Fig. 184. Upper Sido of a Very Poorly Burned-In Connector 


Fig. 185. Under Side of Link Shown In Previous Figure. Note that Holes were 
Bored with a Wood-Bit 


Fig. 186, Trouble Breeders. Failures in Making Connections and Burning In 


274 THE AUTOMOBILE STORAGE BATTERY 


are, and knows when it is being ‘‘soaked.’’ Car owners soon learn 
to go to the man who knows what he is doing, and who does it 
in the right way. 

Inferior work, such as the burning shown in figures 184, 185, 
and 186, will soon put you out of business. Your reputation is 
at stake every time you rebuild a battery. It is in your power to 
build up a reputation for good work that will make you the 
busiest battery man in your vicinity. 

You should go a step beyond repairing the battery. You should 


know, when a car leaves your shop, that there are no grounds or | 
short circuits in the wiring which will cause the battery to run 


down, and that the generator is charging at the proper rate. The 
best way to do this is to have an AMBU ELECTRICAL TROUBLE 
SHOOTER, which gives the proper charging rates for all types 


and makes of dynamos which have been used as standard equip- | 
ment since 1911, and which furthermore quickly locates and tells | 


how to cure any troubles which may exist in the starting or light- 
ing system. If you find any repair troubles outside of the battery, 
you will earn more money, and you will have car owners coming 
to your shop from near and far. : 


rr 


\ 


INDEX 


A 
Page 
Adding water to replace evaporation. ...........ccccceccccccaces 73 to 78 . 
Adjusting the electrolyte after rebuilding...................0 cc eeeees 248 
Analysis of the condition of the battery...................--0 00s 162 to 172 
Assembling and finishing elements during manufacture...............64- 100 
B 
Batteries in general...... 0.2... ce ccc ce ee tte ee ce ee eee e ee eneeeee 5 
Battery case rotted. Causes and remedies.............. ccc eee eee eee 177 
Battery discharges rapidly. Causes and remedies..................-000- 178 
Battery trouble charts......... 0.0... cece cc eect ce eee eee ee eee 172 to 178 
Battery will not take charge. .... 0.0... ce ee weet een eees 176 
Boring off connecting strapsS..... 0.0... cece ccc ee ee ce eee eee ee eee 189: 
Buckling of plates... ...... 0c ccc ccc ee ce ee ee eet eee eee eeee 58 
Burning lead mold........ cece cece eee eee eet ee teen cent weenie 146 
Burning on connecting straps with Oxy-Hydrogen flame................. 239 
Burning on connecting straps with soldering irons..................08.. 244 
Burning on new plates.......... 0 eee ee eee eee ee ence eee ees 218 
C 
Cadmium test for storage batteries.............. cece ee eee ee eeee 266 
Capacity of storage batteries ...... 0... cece tee eens 40 
Capacity, causes for loss Of... 2... ce cece ce eee eee eee eee ee ence 54 
Capacity, effect of age On.... 6.6... cece ce cee eee cence A6 
Capacity, effect of circulation of eloctrolyte on............ Lecce eu euaes 43 
Capacity, effect of plate surface area On... ..... cece teenies 41 
Capacity, effect of quantity, arrangement and porosity of active material on 41 
Capacity, effect of quantity and strength of electrolyte on..............4. 41 
Capacity, effect of rate of discharge on...............-. re 43 
Capacity, effect of temperature On.... 0.6... eee eee eee te ete e ees 45 
Care of battery when not in service.......... eee eee ee eet tee eee 88 
Case, care of battery... ....... eee eee eee eee Leet ee ees 72 
Case, cleaning and painting the............6- ese e eee eee eee eee eee 246 
Case, manufacture of........ bee cece tee en te tee eee eee eee eee sree enene 99 
Case, repairing the....... 6.50 cece ccc e eer ee ee eet eee teen nee eens 225 


2718 INDEX 

Page 
Case, rotted... .cccccccc secre cect eee c et tanec eee eee eeee est estseeeres liz 
Cell, elementary... .. cc. cece ce cece ee eee tenets eeeeeeees 5 
Cell, things required in storage.......... 0... . eee cece eee eee eee eeeee 7 
Cells, primary and secondary..............00c cece cence ee eee eee eeeees 6 
Charge, battery will not hold........-.... ccc eee eee te eee tenes 178 
Charge, battery will not take............ 0c eee cc ce ee ee eee .176 
Charge, changes at negative plates during.......... 2... 0c cess eee wees . 38 
Charge, changes at positive plates during............. 0.2... cece ee ee eee 39 
Charge, change in density of electrolyte during................. 0500 eee 38 
Charge, chemical actions of ............ ccc cece ee ce ee eee eee eeeeee 15 
Charge, final products of ............. eee cece ce ee ee ee eee eens 12, 14 
Charge for sulphated battery.......... 0. ce cece cee nee eee e eee 184 
Charge, freshening......... 0... ccc eect ee eee een eee tees ee eeeeee T2 
Charge, gassing during............. 00. cece e eee eee eens Dette e eee eee 184 
Charge, ions Guring..... 2... cece ccc ee eee eee eee teeta eee 18, 22 
Charge, loss of in an idle battery. ... 2.0... ... cc cece eee eee eee 26 
Charge, normal... ... ccc cece cece cece eet eee eee et eee e eens 184 
Charge phenomena........... 0. cece ce ce cee cee teen eee eee ee eees 37 
Charge, specific gravity does not rise during.............. 00. ee ee ee eee 186 
Charge, specific gravity rises above 1.300 during.............. 2.0. ee eee 186 
Charge, starting rate Of... ... 6. ccc cee ce cc cee ee eet eee te ee tenets 184 
Charge, voltage changes during.......... 0... 0. cece eee eens 37 
Charging oattery before rebuilding. ........-... 0.0... cece ee eee eee eee 182 
Charging battery off the car... .... cee cee ce ee eee tenes 183 
Charging battery on the car........ ee ce eee ee eee ees 182 
Charging bench... ....... cee cc eee cee eee ee eee eee eee ee ee eens 114 
Charging equipment...... 0... cc eee ee eee eee eee tence eee 113 
Charging methods.......... cece eee cece ce ee eee rete eee eee tenes 110 
Charging the rebuilt battery........ 0... 0. cee cc eee eee eee ce eee 247 
Chemical actions, substances which enter into the........... cee cece eee 12 
Chemical actions which produce electricity.................. cece eee eee 11 
Cleaning and painting the case..... 2... .. cc ee eee ee eee eee 246 
Condition of battery. Analysis of........ 0... ccc cece ee eee eee 162 to 172 
Conditions of operation, engine idle. ... 2.0.2... ce eee cee ee ee ens 62 
Conditions of operation, engine running....-........ cece eee ce ee ween 63 
Connecting straps, burning on, with Oxy-Ilydrogen flame................ 239 
Connecting straps, burning on with soldering irons...................... 244 
Connecting strapS, TEMOVINE...... cece cee ce ee eee te eee eee t eee e ene .189 
Connection of battery to Car... .... cee eee cee tee te eee eee eet 71 
Cold weather efficiency of storage batteries... 0.0.2.0... 0 ce eee ee ee eet 66 
Corroded terminals. Causes and remedies............0cc cee ee tees cc cce .177 
Course of operation of starting and lighting systems.................... 61 
Covers, putting on the... ... ccc ect cee cree rete e eee e ete e ee eees 230 
Covers, various designs for... .. 20... ccc ccc ccc ee cee eee e nese eeecees 96 


Page 

Cutout adjustment... 0... ccc cece cee ee cee een e ee teaeneeees 169 
Cutout, operation of electromagnetic.............. 0. ce cece eee eens 65 
Cutout, operation of manual... .......... eee cence teen eee 63 
Cutout, operation of mechanical.............. 0c cece eee ee eee cence 64 

D 
Discharge board...... cc cece ee eee cece ee et ee eee tect e ee eeees 133 
Discharge, changes at negative plates during........... cc. eee seen ewes 34 
Discharge, changes at positive plates during................. 0. eee eee 35 
Discharge, expansion of negative active material during........ seen ees 35 
Discharge, chemical actions of........... cece ce eee eee t cece eee 15 
Discharge, factors limiting extent of........... 0... ccc eee eee 31, 34, 42 
Discharge, final products of ........... cece eee eee cet ee eee ees 12, 14 
Discharge, ions during......... 2... ccc ete ee etree ee eens 22, 24 
Discharge phenomena.......... cree cece ce cece ce eee eee ce eee e wees 29 
Discharge, voltage changes during............ 0c. cece eee eee e eee neces 30 
Discharging and testing batteries after rebuilding....................... 248 
Discharging battery after charge............ ccc eccee cence eeeeeenes 186 
Diseases of storage batteries. ... 0.0... tcc eee ee eee eee eens 51 
Dry storage of batteries... ..... 0. cc ee eee eee eect ee enes 271 
E 

Early history of storage battery.................048. see cece e eee ee eees 11 
Efficiency of battery in cold and warm weather................. cece eeee 66 
Electric arc, lead burning with............ cece cee eee eee nes 152 
Electricity not generated by battery......... 0... ec cee ee ee eee nee 22 
Electricity, sources of, ON CAV... .. kk ee eee ee teenies 3 
Electrolyte, adjusting after rebuilding.................. eee eee ee eee 248 
Electrolyte, causes of leakage of, at top of battery....................6. 176 
Electrolyte, causes of low level of...... 0.0... cece ce cee eee e eee eee 175 
Electrolyte, changes in density of, during charge................0.00000- 38 
Klectrolyte, changes in density of, during discharge.................... 32 
Electrolyte, densities of, for best operation............... cece eee eee 36 
Electrolyte, filling jars with.................. eben eee te eect ee eeee 16.228 
Flectrolyte, freezing points Of... 0.0.0... . cece cence tenes 87 
Flectrolyte, height of......... ccc ccc ce eee eee eee enna eanes 73 
Electrolyte, mixing... ...... 0... ccc cece ce eet eee ete nett teen eens 158 
Electrolyte, proportions of water and acid in mixing.................... 160 
Electrolyte not decomposed in an idle battery............ ce. eee eee eeee. 27 
Electrolytic rectifier........ 00. c eee eee ee ee te eee ee nent e eens 128 
Elementary cella... 0... . cece ce cee ee eee eee teen tte e eens 5 


Julements, reassembling the........--. cece cece cee ree cece eee e ee cees 222 


280 INDEX 


Page 
[Examining plates in rebuilding batteries................. 0.0. cc ccceee: 200 
Excessive temperature on charge........... 0. ccc cece eee e nce e ee nees 186 
Exide batteries... .. cc ccc ccc cc cee eect e ce teen eee e ete eteeseees 258 
EXid@€ COVETB. 0... cece cee ce eee eee tee eee ee eee eens ete eee eee 98 
F 
Filling jars with electrolyte............ cece cee cece reece eee ees 228 
Find the cause of every trouble..... 0.0... 0. cece ce ec tenes 211 
Finished work. ...... 0.2... cece cece ee eee ne eee eee eee eee e eee eeee 272 
Finishing charge rate... .... 0.0... cece ee ccc tee eee e ee eee teenies 184 
Forming plates... ... 0... ccc ccc cece eee eee ee teen eee eee e teas 92 
Four compartment heater............ 0 ccc cee eee cee cee ete eee ee eee 192 
Freeing Shorts... ... 0. ccc cc ce ce cet ce eee eee ee een ee ee eee eenes 211 
Freshening charge......... 0... cece cece eee cere eee eee eee ee eecees 22 
Freezing, causes and remedieS... 1.0... 00... cee cee cee teen e ee eens 178 
Freezing points of electrolyte of various specific gravities................ 87 
G 
Gassing during charge........ 0... cc cece cece eee eee eee teen ee eeees 184 
H 
Hardening of negatives... ...... cece cece eee eee cee eee cence ences 59 
Height of electrolyte... 0.0... cece ccc cece teen eee e ene eees 73 
High gravity, causes and results Of.......... 0.6. cece eee c cece e ee ee 174 
History of storage battery... ........ ccc ce cee eee ee eee eee eens 11 
How chemical actions produce electricity....... 0.0... . cece ee eens 17 
How to take care of battery on the car........... cece ee ees 68 
I 
Idle battery, causes of loss of charge in......... eee e eee eee nee 26 to 28 
Idle battery, electrolyte not decomposed in........... ee cece eee eee ee 27 
Idle battery, formation of sulphate im........ cc ce eee ee eee 26 
Idie battery, loss of charge in, caused by impurities..................... 28 
Idle battery, loss of charge in, caused by leakage....................08. 28 
Installation of battery On Car... eee ce eee ee eee eee teen eees 69 
Internal resistance, effect of active materials On.......... 20. cee ee ween 49 
Internal resistance, effect of electrolyte on... 0.1... 0... cee ce ee ee ees 49 
Internal resistance, effect of grids OM.......... cece ee ee ee ee ee nes 48 
Ions during charge......... Cee eee eee eee e eee tee tee ee ene 18 to 22 


Tons during discharge... ......... cece cece ec cece ee cece ee ee ee eeees 22 to 24 


J 
Page 
Jars, putting in new......... ccc ccc cece cece cece tenes eens 2226 
Jars, how to determine if cracked. .......... cc cc cece e cece ccc cece wenees 167 
L 
Lamps, do not use larger than those supplied with car..............006- 63 
Layout for a small shop........... ccc cee ee cece ce tee tet eee eens 104 
Lead burning with electric arc............. 0. e eee cee nee eee dee eeeee 152 
Lead burning with gas flame..... 1.0.0... cece eee ee eee ence ences 152 
Lead burning with oxygen-hydrogen flame........... ence nec ee nees 239 
Lead burning with soldering irons................. 0.0. cece eee eee eee 244 
Leakage of electrolyte at top of battery............... ee eee teen eens 176 
Light in the shop..... Coe ee ee ee te eee ee eee eee te eee eee e ener n eens 109 
Lights, causes of dim... ... cc eee ce ee tee e teen ee ee ete nees 178 
Loss of charge in an idle battery......... 0... ce ee cece cee eee ee eee 26 
Low gravity, causes Of........ cc eee te eee tence tee teens 172 
Low level of electrolyte, causes and results of............ 0. cee ee ee eee 175 
Low voltage, causeS Of... .... ccc eee ee ce ce eee eee ee teen ee eees 172 
M 
Manufacture of storage batteries... ...... 0... cee ce cece eee eee eens 89 
Mercury arc rectifier... . 0... cele ce eee eee ee eee teens 123 
Methods of heating sealing compounds..... Dee e eee eee eee cence eens 191 
Methods of producing electricity..... 0.0... 0. ccc ccc ee ee eens 5 
Mold for preparing burning lead........... cc cece cee eee nee 146 
Molding grids for plates......-.. ccc ce cc cece teen eee eens 89 
Motor generator setS...... 0. cece cece tee eee e eee eee eee enna 123 
N 
Negative plates, changes at during charge........... 6.0 c eee eee e ee eees 38 
Negative plates, changes at during discharge...........--.. 0. - eee ee eee 34 
Negative plates, expansion of during discharge. ................0 eee eeee 35 
Negative plates, hardening Of ......... cece eect ee cee ete eee n ence 59 
Negative plates, pressing......ceeee sce c crete eet e rete ett teen eee e teas 215 
Normal charge.......- eee ce eect eee eet tee eee tee ene en ees 184 
0 
Open circuit voltage not a reliable test. 0... 0.0 cc eee et et tee tet e en eees 32 
Opening a battery... ... cece ee ee eee tee eee nett eee eens 187 


Opening, when necessary... --- ++ cere eee e teeter ett teen teen tenes 181 


282 . INDEX 


Page 
Upening, when unnecessary... ....... cece cece e cece ee ce renee ee eeeeees 180 
Operating conditions governing action of battery.................... -: 65 
Operating temperatures... ... 0.0... eee cece ee ee teen cence eees 85 
Operation, conditions of........ ee ete ee eee eee e ene eee eeeneeee 61 
Operation, conditions of with engine idle................ 0s cece eee e eens 62 
Operation, conditions of with engine running..................0ceeeeees 63 
Operation, course of, in a starting and lighting system................. 61 
Overcharge, monthly........ 0... cece eee ccc eect e eee eee eeeee 186 
Overheating, causes and results of. ....... 0. e eee eee eee ee eens 175 

P 
Pastes, applying to gridS.... 0... cece ccc cence ence ee eeeeeees 91 
Pastes, formulas for............ cece ccc ee eee eee ce eee eet e een eeeees 91 
Plate Press... . eee eee cee teen ee ee nent sent eeeeee 142 
Plates, buckling of ......... 0... cece ect ce eee ene eee eee en eees 58 
Plates, burning on new.......... 2. ccc eee eee cece eee tenet e cease 239 
Plates, examination of, in rebuilding............. 0... 0c cc cece eee eee 200 
Plates, forming Of......... 0... cece cee ccc eee tenet teen teens 92 
Plates, manufacture Of.......... ccc ccc cee cette eee e es neees 89 
Plates, Planté and Faure...... 0... 0. cece eee eee ee eee eeeee 11 
Plates, washing and pressing......... 0.0... cece eee ce eee eee eeee 215 
Plates, what to do if some must be discarded.............. 0... cece cee: 199 
Plates, when old may be used again............ 0... cece cee ee cee e ees 208 
Plates, when to put in neW.......... ce cece eee eee e eee eens 201 
Plugs filling, must be removed during charge................ cece eeueee: 184 
Positive plates, buckling of, when exposed to light...................... 60 
Positive plates, changes at during charge............. 2. cece eee eee 39 
Positive plates, changes at during discharge.............. 0.2 cece ee nees 35 
Positive plates, greater activity at, than at negative.................... 35 
Precautions to be taken by repairman..............-. cece ee ecw eces 150 
Preliminary charge in rebuilding batteries............... 0.0 cece ee eeeee 213 
Preparing battery for US€........ ce cece eee eee ee eee ee ee eee nes 69 
Prestolite batteries... eee ccc ec eee ete tee e eee eens 264 
Primary and secondary cells..... 0... 0. cece ce cee ee eee ee ee eee neces 6 
Producing electricity, methods of....... 0.0... cece ect eee eee eee ee 5 
Proportions of water and acid in mixing electrolyte................. ...- 160 
Putting elements im jars....... 0. cee ccc eee eee ee eee ee eee anes 227 
Putting in NeW Jars... . 6... eee ee ee ee en ee ee ee eee enna: 226 
Putting on the CoverS.......... ccc cect eee ee eee eee eeres 230 
R 

Reassembling the elements.......... 0... ccc cece eee cence eeeencs 1. 222 


“abuilding batteries... 0... cc cee ccc tne cence eeee seen: 187 


Page 
Rectifier, electrolytic... ...... 0... cece ce cee eect eee teen ee teteeenes 128 
Rectifier, Mercury ATC... 6c ec ce ce eee eee eee eee eee eee 123 
Removing sealing compound.............. ccc cee cece eee ee eees eee eee 191 
Repairing the case........... 00 cece eee eee eee eee eee eee eee eee eeeee 225 

S 
Saving the sediment... 0.0... 0... cece ccc ee cence ete eee e anes 157 
Sealing compound, methods of heating.............. cece eee eee 191 
Sealing compound, Tremoving............... cece eee cee eee eee eee 191 
Sealing compounds. ...... 0... . cece cee eee eee eee eee ete eee ee eens 231 
Sealing the battery.... 00.0... ccc eee teen ee eee ete neees 233 
Separators, manufacture of........... 0. cece eee eee eee tenes 95 
Separators, storing 2.0... 0... ce eee eee eee eee eee eens 210 
Separators, work on, in rebuilding batteries..................00000420 209 
Shelving ............ ee eee ee eee eee teen tee tee tence eee eens 109 
Shop equipment... 0.0.0... cece eee eee eee tence teen eee eee 103 
Shop, layout for small... ..... 0... cee ee ce eee eee ee eens 104 
Shop, light in the....... 0... ccc cece ee eee eee eee eee ete eens 109 
Shorts, freeing... 0... 6 ee ee ete eet ee eee e eee eens 211 
Soldering irons, lead burning with...............0.0.- ne 244 
Sources of electricity on the car...... 02... . cece ce ee ee eee eee 3 
Specific gravity as affected by temperature............... eee ee eee eee 85 
Specifie gravity, causes of loW........ eee eee eee ene nees 172 
Specific gravity does not rise on charge............. 0. cee eee eee 176 to 186 
Specific gravity, MeaSurINg......... cee cee eee ee eee e eee eees 79 
Specific gravity rises above 1.300 on charge...............00--- Ore eees 186 
Specific gravity, why 1.300 is used.......... cece cece e een eee e eee eeee 42 
Standard method of procedure in handling plates................0.0000- 199 
Starting charge rate... ... cee ce cee cee tee eee e eee e eee e ee eeees 184 
Starting motor should be used as little as possible..........--....eee0e- 65 
Steamer, battery... .. ccc cece ccc cece eee tee eee teen teeta ea tes 140 
Steps in the application of electricity to the gasoline automobile........ 1 
Storage battery does not generate electricity......... 0.0... ee ee cee eee 22 
Storage battery, what it consists of .......... 0.6. c eee eee eens 89 
Storing batteries while dry......... 0. cee cee ete cee eee teen anes 271 
Sulphate, formation of, in an idle battery............ cece eee e eee eee 26 
Sulphated battery, charging... ..... 0... ce eee eee eee eee teen ees 184 
Rulphation oo... cece ce ee eee eee ee eee et ete tenes 51 
T 

Tagging batteries... 6... kee te ence ee eee e een ener eees 147 


Temperature during charge... 2.2... e cee ee eee eee nent nee enees 185 


284 INDEX 


Page 
Temperature, operating... .......... 0 ccc cece ee tee eee nse teen enc ee eee 85 
Tools and equipment........-.- 0... cece cece eee ee cece eee eee eee 135 
Trouble charts. ......... 0... cc ee cece eee nee eee e tees 172 to 178 
Turntable for batteries. ... 0... 0... eee cece eee ee ee tee eet eee nee 144 
U 
U. S. L. batteries... ie ccc cee ce ee eee e eect eee eeenns 264 
U. S. DL. Covers... ec ee cee eee eee eee ence e eect enee 98 
V 
Voltage, causes Of LOW... ... ee ccc cee cece ee ee te eee eee eee eee sees 172 
Voltage changes during charge............. 0.02 c ccc cece eee tee teens 37 | 
Voltage changes during discharge.......... Le eee cette eee e eee neen 30 | 
Voltage independent of plate surface area........... 20.0... cc eee ee eee ee 32 
Voltage on open circuit not reliable test.................. eet eee wees 32 
, \ 
Ww 
Warm weather efficiency of storage batteries............... 0. cee ee eee 66 
Washing and pressing plates............ ccc eee eee e eee ee tee eee e ees 215 | 
What must be done with opened battery.................. cee eee eee 198 
What to do if some plates are to be discarded...................0.00000. 199 | 
When a battery may be left on the car........ 0... eee eee nee 179 
When a battery must be opened...........,. 20 cece eee eee cette eee eens 181 
When a battery should be removed from car................00eeee ee eee 179 | 
When it is unnecessary to open a battery............ sees eee ee eee 180 | 
When the old plates may be used agaim.........-.-... cece eee cece eee 208 : 
When to put in new plates........ 0... cee cece eee ee teen e ee 2... 201 | 
Why specific gravity of 1.300 is used...........-e cece renee ee eee 42 
Willard type S battery... .. 0.0... cece cee eee e ee eens . 250 
Work bench, special... . 0.6... cee ce ee eee ete eee eee eee nee 105 
Work on the battery................0 005: eee ee ee ee eee eee ees 182 
A100) s¢-) 1X0) | 102